Lignin-based resins for kraft paper applications

TAPPI Journal ◽  
2019 ◽  
Vol 18 (11) ◽  
pp. 666-675 ◽  
Author(s):  
PRAJAKTA DONGRE ◽  
BILJANA BUJANOVIC

We investigated miscanthus (MS) and willow (W) lignin-furfural based resins as potential reinforcement agents on softwood and hardwood kraft paper. These resins might be sustainable alternatives to the commercial phenol-formaldehyde (PF) resins. Phenol is a petrochemical product and formaldehyde has been classified as a carcinogen by the U.S. Environmental Protection Agency. The lignin used in this study was derived from hot water extraction (160ºC, 2 h) of MS and W biomass, and may be considered sulfur-free. These biorefinery lignins were characterized for their chemical composition and inherent properties via wet chemistry and instrumental techniques. The resin blends (MS-resin and W-resin) were characterized for their molecular weight, thermal behavior, and mechanical properties. Mechanical properties were measured by the resin’s ability to reinforce softwood and hardwood kraft papers. The effect of adding hexamethylenetetramine (HMTA), a curing agent, to the resin was also examined. Mixtures of PF and lignin-based resins were investigated to further explore ways to reduce use of nonrenewables, phenol, and carcinogenic formaldehyde. The results show that lignin-based resins have the potential to replace PF resins in kraft paper applications. For softwood paper, the highest strength was achieved using W-resin, without HMTA (2.5 times greater than PF with HMTA). For hardwood paper, MS-resin with HMTA gave the highest strength (2.3 times higher than PF with HMTA). The lignin-based resins, without HMTA, also yielded mechanical properties comparable to PF with HMTA.

2017 ◽  
Vol 7 (1) ◽  
pp. 23
Author(s):  
Jack Fuller ◽  
Yang Guo

According to the U.S, Environmental Protection Agency (EPA), the number of boilers in the U.S. devoted to the production of steam, electricity, and heat is approximately 1.5 million. This study analyzes boilers burning natural gas, coal, wood, oil, or other fuels to recover thermal energy in the form of steam or hot water to produce electricity or heat. The focus of this research paper will be to assess the compliance status of the boilers which were in the original EPA major source Boiler MACT group to provide insight into the current operating status of these boiler units.


Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3175
Author(s):  
Ravindra Prajapati ◽  
Kirtika Kohli ◽  
Samir K. Maity ◽  
Brajendra K. Sharma

Plastic is referred to as a “material of every application”. From the packaging and automotive industries to the medical apparatus and computer electronics sectors, plastic materials are fulfilling demands efficiently. These plastics usually end up in landfills and incinerators, creating plastic waste pollution. According to the Environmental Protection Agency (EPA), in 2015, 9.1% of the plastic materials generated in the U.S. municipal solid waste stream was recycled, 15.5% was combusted for energy, and 75.4% was sent to landfills. If we can produce high-value chemicals from plastic wastes, a range of various product portfolios can be created. This will help to transform chemical industries, especially the petrochemical and plastic sectors. In turn, we can manage plastic waste pollution, reduce the consumption of virgin petroleum, and protect human health and the environment. This review provides a description of chemicals that can be produced from different plastic wastes and the research challenges involved in plastic waste to chemical production. This review also provides a brief overview of the state-of-the-art processes to help future system designers in the plastic waste to chemicals area.


1999 ◽  
Vol 01 (03) ◽  
pp. 329-347 ◽  
Author(s):  
REBECCA A. EFROYMSON

The Toxic Substances Control Act (TSCA) is the legislation used by the U.S. Environmental Protection Agency to regulate releases of genetically engineered microorganisms. The rule defining the scope of the notification requirements for releases of microbial products of biotechnology was published in April 1997. The Environmental Protection Agency (EPA) had some latitude regarding the extent to which various categories of microorganisms would be regulated, but the agency was constrained by requirements of TSCA and an interagency agreement about how to regulate products of biotechnology. This paper investigates the extent to which the scope of oversight is based on risk. A risk-based rule is defined as one where the reporting requirements are based on potential for exposure or expected adverse effects. The evolution of the rule is described, and risk-based components are discussed. In conclusion, the scope of oversight of microbial releases is determined to be based on risk to the extent that legislation and institutional constraints permit.


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