scholarly journals Rheological Behavior Models of Polymers

2021 ◽  
Vol 12 (1) ◽  
pp. 1263-1272

We studied and investigated the various viscosimetric and rheological polymers' behaviors during this comprehensive review. The viscosities relate to the investigation of the flux, the deformation, and the polymers' elasticity; we have employed the viscosity since this plays a primordial role in the phenomena flux and implementation of the polymer. The rheology behaviors were investigated for the determination of the physical properties of polymers. The rheological properties are mostly employed for improving polymers implementation. Further, three rheological behaviors models such as Newtonian, pseudo-plastic (Power Law, Law of Tile and Cross Law) and heat-dependent pseudo-plastic (Williams-Landel-Ferry Law (WLF), Law of Tile-Yasuda and Arrhenius law) were studied.

10.14311/892 ◽  
2006 ◽  
Vol 46 (6) ◽  
Author(s):  
F. Rieger

Knowledge about rheological behavior is necessary in engineering calculations for equipment used for processing concentrated suspensions and polymers. Power-law and Bingham models are often used for evaluating the experimental data. This paper proposes the reference radius to which experimental results obtained by measurements on a rotational viscometer with coaxial cylinders should be related. 


2007 ◽  
Vol 40 (2) ◽  
pp. 690
Author(s):  
G. E. Christidis

The new method of Christidis and E beri (2003), which determines the layer charge and charge distribution of dioctahedral smectites in bentonites is presented and is compared to the existing methods for determination of layer charge and charge distribution, namely the structural formula method and the alkylammonium method. The new method is based on the comparison ofXRD traces of K-saturated, ethyleneglycol solvated smectites with simulated XRD-traces calculated for three-component interlayering. Applications of the method include modeling of the evolution of smectite layers towards illite during diagenesis, and study of the influence of layer charge and charge distribution of smectites on important physical properties of bentonites such as rheological properties (viscosity, gel strength, yield point and thixotropy) and swelling. Smectites with layer charge between -0.425 and-0.47 to - 0.48 equivalents phfu affect rheological properties in a different way compared to smectites with higher or lower layer charge than this layer charge interval. Based on these observations a new classification scheme for smectites has been proposed according to their layer charge. In this classification scheme the term smectites with intermediate layer charge has been introduced.


2015 ◽  
Vol 49 ◽  
pp. 24-34 ◽  
Author(s):  
Mahdi Ghajari Shamooshaki ◽  
Alireza Sadeghi Mahounak ◽  
Mohammad Ghorbani ◽  
Yaya Maghsouldloo ◽  
Aman Mohammad Ziaeifar

The milk along with xanthan at levels 0, 1.9, 3.9, 5.9, 7.9, 9.9 and 0.1 and 0.2 % (No 1 (control) to 11 respectively) as egg replacement were used for preparation of mayonnaise. Creaming index, heat stability, physical stability and rheological properties of samples over a were investigated. Also flow behavior of samples were fitted to Power law, Herschel-Bulkley and Casson models. It was found that addition milk along with xanthan to mayonnaise protected from phase separation in comparison to control sample. All the samples had stability higher than 99% except samples 1, 4, 5 and 6. The highest stability was recorded for sample No 11 (99.98%) and the lowest for 5 (74.95%) that compared with control sample had significant differences (p> 0.05). All the samples except No 1 and 5 showed heat stability higher than 99 % and the highest stability recorded for No 11 ( 99.72%) and the lowest for No 5 (67.42 %) and in comparison with control were significantly different (p> 0.05). Apparent viscosity decreased with increase the egg replacement from 40% to 80%, as the highest and lowest viscosity observed in samples contain 100% and 80% replacement respectively. All samples showed shear-thinning behavior and the high coefficients of determination for Power law and Herschel-Bulkley models (0.99) revealed the adequacy of these rheological models to describe flow behavior of mayonnaise.


Author(s):  
Lia Yunita

<p class="Default">Lumpur pemboran merupakan salah satu penunjang yang penting dalam suatu operasi pemboran minyak, gas dan panas bumi. Fungsi Lumpur pemboran  ditentukan oleh komposisi kimia dan sifat fisik lumpur.  Kesalahan dalam mengontrol sifat-sifat fisik lumpur akan menyebabkan kegagalan yang dapat menimbulkan hambatan pemboran (<em>hole problem</em>) dan akhirnya mengakibatkan kerugian yang sangat besar. Viskositas merupakan bagian yang pokok dalam sifat-sifat rheologi fluida pemboran. Pengukuran sifat-sifat rheologi fluida pemboran penting mengingat efektivitas pengangkatan <em>cutting</em> merupakan fungsi langsung dari viskositas. Di laborotorium teknik perminyakan penentuan viskositas lumpur pemboran biasa dilakukan dengan menggunakan Marsh Funnel.Penelitian bertujuan membandingkan hasil penentuan viskositas menggunakan marsh funnel dan viscosimeter berbasis video berbantuan <em>software tracker</em>.  Sampel dalam penelitian adalah  lumpur pemboran berbahan dasar aquadest dan bentonite dengan tambahan additive. Percobaan dilakukan sebanyak lima kali dengan komposisi lumpur pemboran yang berbeda. Sampel I berbahan dasar bentonite ditambah aditive spersene 0,5 gram. Sampel II  berbahan dasar bentonite ditambah aditive spersene 1 gram, Sampel III  berbahan dasar bentonite ditambah aditive CMC 0,5 gram. Sampel IV berbahan dasar berbahan dasar bentonite ditambah aditive CMC 1 gram dan sampel V berbahan dasar bentonite tanpa aditiveHasil analisa menggunakan Marsh Funnel dalam penentuan viskositas lumpur pemboran dimana dari hasil analisa laboratorium apabila lumpur dasar ditambahkan  spersene  maka viskositas kinematik akan berkurang dari 29,3 detik menjadi 28,3 detik dan apabila lumpur dasar ditambahkan CMC maka viskositas kinematik akan bertambah dari 36,5 detik menjadi 38,3 detikPenggunaan viscosimeter berbasis video berbantuan software tracker dalam penentuan viskositas lumper pemboran dengan penambahan spersene 0,5 gram diperoleh nilai viskositas 0,065 ±0.02 poise, penambahan spersene 1 gram diperoleh nilai viskositas 0,052 ±0.02 poise, penambahan CMC 0,5 gram diperoleh nilai viskositas 0,087 ±0.01 poise, penambahan CMC 1  gram diperoleh nilai viskositas 0,092 ±0.03 poise. </p><p class="Default"><em>Drilling mud is one of the important supports in an oil, gas and geothermal drilling operation. The function of drilling mud is determined by the chemical composition and physical properties of the mud. Errors in controlling the physical properties of mud will cause failure which can lead to drilling problems (hole problems) and ultimately result in huge losses. Viscosity is an essential part of the rheological properties of drilling fluids. Measurement of the rheological properties of drilling fluids is important considering the effectiveness of cutting removal is a direct function of viscosity. In the petroleum engineering laboratory the determination of viscosity of drilling mud is usually done using Marsh Funnel. The research aims to compare the results of the determination of viscosity using marsh funnel and video-based viscosimeter assisted by software tracker. The sample in this study was drilling mud made from aquadest and bentonite with additives added. The experiment was carried out five times with different drilling mud compositions. Sample I made from bentonite plus 0.5 gram additive spersene. Sample II made from bentonite plus spersene aditive 1 gram, Sample III made from bentonite plus aditive CMC 0.5 gram. Sample IV made from bentonite based added CMC aditive 1 gram and sample V made from bentonite without additive The results of analysis using Marsh Funnel in determining the viscosity of drilling mud where from the results of laboratory analysis if base mud was added with spersene the kinematic viscosity would decrease from 29.3 seconds to 28.3 seconds and if the base mud is added CMC then kinematic viscosity will increase from 36.5 seconds to 38.3 seconds. The use of video-based viscosimeter assisted by tracker software in determining the viscosity of drilling jumpers by adding 0.5 grams of spersene obtained a viscosity value of 0.065 ± 0.02 poise , the addition of 1 gram of spersene obtained a viscosity value of 0.052 ± 0.02 poise, the addition of 0.5 gram CMC obtained a viscosity value of 0.087 ± 0.01 poise, the addition of 1 gram CMC obtained a viscosity value of 0.092 ± 0.03 poise.</em></p>


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