scholarly journals Mineral Additives to Enhance Early-Age Crack Resistance of Concrete under a Large-Temperature-Difference Environment

2021 ◽  
Vol 11 (19) ◽  
pp. 9338
Author(s):  
Jinjun Guo ◽  
Liyan Cui ◽  
Jingjiang Wu ◽  
Hongyin Xu ◽  
Zheng Zhang ◽  
...  

The large temperature difference condition in Northwest China threatens a myriad of concrete structures during construction, with the daily temperature varying by around 40 °C. To investigate the macro-mechanical properties and microstructural characteristics of concrete containing different amounts of mineral admixtures under such harsh conditions, this investigation used an environmental chamber to simulate a saline soil erosion environment with a large temperature difference. Four types of concrete containing different proportions of fly ash and slag were prepared and exposed in the environmental chamber with a daily temperature change of −5~40 °C to investigate their compressive strength, flexural strength, and fracture properties. Moreover, the X-ray diffraction (XRD) characteristics, microscopic morphological characteristics, pore structure characteristics, and post-erosion chloride ion distribution characteristics were also observed and recorded. Results showed that the mineral admixture could improve the early strength development of the concrete and effectively improve the fracture performance of the concrete. The average compressive strength growth rate of concrete from day 3 to day 14 was 83.25% higher than that of ordinary concrete (OC) when 15% fly ash and 15% slag were added. In addition, the fracture energy of the concrete was maximized when 15% fly ash and 20% slag were added, which was 50.67% higher than that of OC; furthermore, the internal compactness and pore structure were optimized, and the resistance to saline soil erosion was strong. This provides a basis for the practical application of compounded mineral admixture-modified concrete in an arid environment with a large temperature difference and saline soil erosion.

2016 ◽  
Vol 847 ◽  
pp. 479-484 ◽  
Author(s):  
Ya Lu ◽  
Ming Li ◽  
Zi Han Guo ◽  
Xiao Yang Guo

In view of the common polymer retarder of AMPS has poor sedimentation stability for slurry in high temperature, and thickening curve for unusual problems, a new terpolymers retarder PSIH which can solve the problem for the large temperature difference was synthesized by free radical aqueous solution copolymerization using styrene sulfonate (SSS), Itaconic acid (IA) and unsaturated hydroxyl ester monomers X . The structure and thermal stability of the copolymer was characterized with gel permeation chromatography (GPC), infrared spectroscopy (IR), and thermal gravimetric analysis (TG). The application performance of the retarder was assessed. The results demonstrated as follows. 1) The preferred synthesis conditions of the retarder is: the mass ratio of SSS/IA/X=9: 3: 1, temperature=60°C, initiator concentration =2%, the reaction time=5h, pH value was controlled in the neutral bias acidity. 2) Synthetic copolymer is the target product with appropriate molecular weight and has good thermal stability with thermal decomposition temperature of the main chain up to 375°C. 3) Compared with ordinary retarder the PSIH has merits as follows: excellent thermal resistant ability and sedimentation stability in high temperature; the rapid development of compressive strength in low temperature, and a big temperature span (30 °C~150 °C). The thickening time of the slurry with 1.0% PSIH is 245 min at 150°C; the compressive strength of cement with the same dosage can get up to 4.7MPa at 30 °C. In short, PSIH has excellent ability to cope with large temperature difference, providing a strong technical support for complex deep well cementing.


2011 ◽  
Vol 675-677 ◽  
pp. 1073-1076
Author(s):  
Zu Quan Jin ◽  
Peng Zhang ◽  
Tie Jun Zhao ◽  
Bao Rong Hou

In this paper, preparation, property study of ultra-strength mortars with mineral admixture and clear river sand was carried out. The mineral admixture include fly ash, ultra-fine GGBS and silica fume. The experimental results show that the compressive strength of mortar improves with increasing amount of silica fume or ultra-fine GGBS. When the content of silica fume or ultra-fine GGBS is 30~35%, the compressive strength and flexural strength of mortar in curing age of 7 days are 100 MPa and 20MPa, respectively. But strength of mortar decreases with the increase replacement rate of fly ash. When the mortar mixes with combined of silica fume and ultra-fine GGBS, the optimum proportion of siliaca fume to ultra-fine GGBS is 2:3. And the compressive strength of mortar in curing age of 7 days is 75~100MPa when the mixed mineral admixture is 40~60%. The compressive strength of mortar is about 90MPa as it mix 60% of cement, 15% of silica fume, 15% of GGBS and 10% of fly ash. Moreover, the ultra strength mortar refines its pore structure and its capiliary pore (≥100nm) amount reduces by 78% compared to ordinary mortar.


2020 ◽  
Vol 44 (9) ◽  
pp. 3771-3776
Author(s):  
Zhigang Peng ◽  
Chen Chen ◽  
Qian Feng ◽  
Yong Zheng ◽  
Huan Liu ◽  
...  

We synthesized a retarder, which has excellent thickening performance in the temperature range of 90–150 °C.


2011 ◽  
Vol 295-297 ◽  
pp. 165-169
Author(s):  
Guan Guo Liu ◽  
Jing Ming ◽  
Xiong Wen Zhang ◽  
Ai Bin Ma

Sulfate attack is one of several chemical and physical mechanisms of concrete deterioration. In actual situation, concrete structures always suffer from the coupled effects of multifactor such as wet-dry cycle and sulfate attack when exposed to tidal area or groundwater level change environment. Partial replacement of cement with mineral admixture is one of the efficient methods for improving concrete resistance against sulfate attack. In this regard, the resistance of concrete with fly ash and slag to sulfate attack was investigated by wet-dry cycle method. The degree of sulfate attack on specimens after different cycles was observed using scanning electron microscopy. The results of compressive strength and percentage of compressive strength evolution factor at various cycling times show an increase in the sulfate resistance of concrete with 60% of fly ash and slag than that only with 40% fly ash. The microstructural study indicates that the primary cause of deterioration of concrete under wet-dry cycle condition is swelling of the sulfate crystal rather chemical attack.


2001 ◽  
Vol 2001.54 (0) ◽  
pp. 75-76
Author(s):  
Nobuyuki FUCHIMOTO ◽  
Kazuyoshi MATSUZAKI ◽  
Kazunori KOURA ◽  
Sinya WAKAMIZU ◽  
Hiroaki KURISIMA ◽  
...  

Author(s):  
C. B. Baxi

Due to problems with the availability and the price of water, and the concerns relating to adverse environmental effects of wet cooling systems, the need for water conserving cooling systems has been increasing. Presently, dry cooling accounts for over 30,000 MWe of capacity in more than 30 countries. GT-MHR is specially suited for use of dry cooling due to 1) high efficiency, 2) high heat rejection temperatures and 3) large temperature difference between the turbine inlet and heat rejection temperatures. Higher efficiency means the amount of energy rejected to the cooling per MWe is less. The majority of heat is rejected in precooler and intercooler at helium temperature of more than 100 °C. This results in higher temperature difference for heat rejection. Also due to large temperature difference between the turbine inlet and heat rejection temperatures, changes in ambient temperature have a smaller effect on overall thermal efficiency. Preliminary evaluation shows that pure dry cooling is economical for GT-MHR for water cost of more than 0.8$/m3 and power cost of 3.5 c/kWh. A combination of dry and wet cooling can reduce large percentage of the water use without affecting the efficiency.


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