scholarly journals Characterization of PM-Bound Heavy Metal at Road Environment in Tianjin: Size Distribution and Source Identification

Atmosphere ◽  
2021 ◽  
Vol 12 (9) ◽  
pp. 1130
Author(s):  
Qijun Zhang ◽  
Hongjun Mao ◽  
Yanjie Zhang ◽  
Lin Wu
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Particle Size ◽  
Size Fraction ◽  
Brake Pad ◽  
Particle Size Fraction ◽  
Vehicle Exhaust ◽  
Particle Size Fractions ◽  
Tire Wear ◽  
Pad Wear

To determine the size distribution and source identification of PM-bound heavy metals in roadside environments, four different particle size (<0.2 μm, 0.2–0.5 μm, 0.5–1.0 μm and 1.0–2.5 μm) samples were collected and analyzed from four different types of roads during the summer of 2015 in Tianjin. The results showed that the concentrations of PM-bound heavy metal from the roadside environment sampling sites were 597 ± 251 ng/m3 (BD), 546 ± 316 ng/m3 (FK), 518 ± 310 ng/m3 (JY) and 640 ± 237 ng/m3 (WH). There were differences in the concentrations of the heavy metal elements in the four different particle size fractions. The concentrations of Cu, Zn, Cd, Sn and Pb were the highest in the larger particle size fraction (0.5–2.5 μm). Cd, Cu, Zn and Pb were the elements that indicated emissions from tire wear and brake pad wear. The concentrations of Cr, Co and Ni were the highest in the smallest particle size fraction (<0.5 μm), indicating that motor vehicle exhaust was their main source. The correlation analysis results showed that there are differences in the concentration, distribution and correlation of different PM-bound heavy metals in different particle size fractions. The PCA results show that the accumulative interpretation variances of PM0.2, PM0.2–0.5, PM0.5–1.0 and PM1.0–2.5 reached 80.29%, 79.56%, 79.57% and 71.42%, respectively. Vehicle exhaust was the primary source of PM-bound heavy metal collected from the roadside sampling sites, while brake pad wear and tire wear were the second most common sources of the heavy metal.

Heavy metals in bulk and particle size fractions from street dust of Kathmandu city as the possible basis for risk assessment

2012 ◽  
Vol 10 (10) ◽  
pp. 84-88 ◽  
Author(s):  
Neena Karmacharya ◽  
Pawan Raj Shakya
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
Particle Size ◽  
Size Fraction ◽  
High Mobility ◽  
Street Dust ◽  
Particle Size Fraction ◽  
Size Fractions ◽  
Particle Size Fractions ◽  
Metal Abundance

Street dust has been sampled from eight major locations of Kathmandu city. The samples were separated into three particle size fractions (<425, 425-600 and >600 ?m) and analyzed for Pb, Cu, Zn and Fe using Atomic Absorption Spectrophotometric method. Results revealed that the bulk samples as well as all particle size fractions under investigation were found to have the metal abundance order as Fe > Zn > Cu > Pb. However, the trace metal concentrations increased with the decrease of dust particle size in all samples. About 35-68% of heavy metals were associated with the small particle size fraction (<425 ?m) and this particle size accounted for 64-81% of the total mass of street dust from all locations. The smaller particle size fraction has a higher heavy metal content, low density, high mobility in runoff, and thus is a higher risk for the residents of Kathmandu city. From the present study, we conclude that a monitoring plan and a suitable risk assessment are necessary to evaluate the evolution of metal concentration in dust in order to develop the proper measures for reducing the risk of inhalation and ingestion of dust for humans and environment. Scientific World, Vol. 10, No. 10, July 2012 p84-88 DOI: http://dx.doi.org/10.3126/sw.v10i10.6869

Influence of compost characteristics on heavy metal sorption from synthetic stormwater

2007 ◽  
Vol 55 (4) ◽  
pp. 219-226 ◽  
Author(s):  
N. Seelsaen ◽  
R. McLaughlan ◽  
S. Moore ◽  
R.M. Stuetz
Keyword(s):  
Heavy Metal ◽  
Particle Size ◽  
Size Fraction ◽  
Freundlich Isotherm ◽  
Particle Size Fraction ◽  
Sorption Data ◽  
Particle Size Fractions ◽  
Surface Areas ◽  
Removal Of Heavy Metals ◽  
Sorption Intensity

This paper has the aim to assess the ability of garden derived compost to remove dissolved heavy metal contaminants typically found in stormwater. Compost was found to have excellent chemical and physical properties for the sorption of dissolved metal ions (Cu2+, Pb2+ and Zn2+). Batch sorption data were used to determine the sorption efficiency of Cu (93%), Zn (88%) and Pb (97%) by compost. The relative sorption affinity of these metals by compost is found to be in the order of Pb2+ &gt;Cu2+∼ Zn2+. The effect of different particle size fractions of compost upon the sorption of Cu was also investigated. Sorption conformed to the linear form of the Freundlich isotherm and can be considered favourable because the sorption intensity values obtained in this study are between 0.1 and 1. Compost with a smaller particle size fraction has larger surface areas and greater sorption than the larger particle size fraction. Compost derived from garden waste is efficient for removal of heavy metals from wastewater or treating water for industries.

scholarly journals   Sulfur fractions in particle-size separates as influenced by long-term application of mineral and organic fertilizers

2012 ◽  
Vol 58 (No. 5) ◽  
pp. 242-248 ◽  
Author(s):  
H.W. Scherer ◽  
G. Welp ◽  
S. Förster
Keyword(s):  
Particle Size ◽  
Farmyard Manure ◽  
Size Fraction ◽  
Water Soluble ◽  
Organic Fertilizers ◽  
Particle Size Fraction ◽  
Size Fractions ◽  
Organic S ◽  
Particle Size Fractions

A field experiment established in 1962 was chosen to investigate the effect of long-term application of farmyard manure (FYM), compost (COM) and sewage sludge (SS), respectively, in two increments as compared to mineral fertilizer on inorganic and organic S fractions in particle-size separates (&lt; 0.002 mm, 0.002&ndash;0.02 mm, 0.02&ndash;2 mm). Independent of the particle-size the application of the high amounts of COM and SS resulted in the highest total S contents. It is evident that the particle-size fractions &lt; 0.002 mm contained the majority of total soil sulfur (S). The content of plant available S (water-soluble and adsorbed SO<sub>4</sub><sup>2&ndash;</sup>) decreased with increasing particle-size, while the influence of the kind and amount of organic fertilizers was negligible. As compared to C-bonded S sulfate esters were the dominant organic S fraction in size separates. The content of both organic S fractions was highest in the particle-size fraction &lt; 0.002 mm and lowest in the particle-size fraction 0.02&ndash;2 mm. The influence of the application of organic fertilizers was less pronounced. Only high application rates of COM and SS, respectively, resulted in the highest contents of both organic S fractions in the particle-size fractions 0.002&ndash;0.02 mm and 0.02&ndash;2 mm. &nbsp; &nbsp;

The Level of Zn in Guiyang Street Dust and its Different Particle Size Fraction Contributions

2013 ◽  
Vol 779-780 ◽  
pp. 1666-1669
Author(s):  
Xiao Yan Li ◽  
Bao Dong Li
Keyword(s):  
Particle Size ◽  
Fine Particles ◽  
Size Fraction ◽  
Industrial Area ◽  
Street Dust ◽  
Particle Size Fraction ◽  
Geometric Means ◽  
Particle Size Fractions ◽  
Zn Concentration ◽  
Functional Areas

By collecting dust samples from seven different functional areas of Guiyang city, we studied the distribution pattern of the level of Zn in dusts with particle size fractions. The result showed the geometric means of Zn concentration in dusts of Guiyang was 435mg/kg. The Zn in most functional areas was primarily associated with middle particles, while the Zn in industrial area and garbage stations were primarily associated with fine particles.

scholarly journals Determination of reactivity rates of silicate particle-size fractions

Revista CERES ◽  
2014 ◽  
Vol 61 (2) ◽  
pp. 265-272 ◽  
Author(s):  
Angélica Cristina Fernandes Deus ◽  
Leonardo Theodoro Büll ◽  
Juliano Corulli Corrêa ◽  
Roberto Lyra Villas Boas
Keyword(s):  
Particle Size ◽  
Soil Acidity ◽  
Size Fraction ◽  
Additional Treatment ◽  
Particle Size Fraction ◽  
Size Fractions ◽  
Particle Size Fractions ◽  
Incubation Periods ◽  
Different Sources

The efficiency of sources used for soil acidity correction depends on reactivity rate (RR) and neutralization power (NP), indicated by effective calcium carbonate (ECC). Few studies establish relative efficiency of reactivity (RER) for silicate particle-size fractions, therefore, the RER applied for lime are used. This study aimed to evaluate the reactivity of silicate materials affected by particle size throughout incubation periods in comparison to lime, and to calculate the RER for silicate particle-size fractions. Six correction sources were evaluated: three slags from distinct origins, dolomitic and calcitic lime separated into four particle-size fractions (2, 0.84, 0.30 and <0.30-mm sieves), and wollastonite, as an additional treatment. The treatments were applied to three soils with different texture classes. The dose of neutralizing material (calcium and magnesium oxides) was applied at equal quantities, and the only variation was the particle-size material. After a 90-day incubation period, the RER was calculated for each particle-size fraction, as well as the RR and ECC of each source. The neutralization of soil acidity of the same particle-size fraction for different sources showed distinct solubility and a distinct reaction between silicates and lime. The RER for slag were higher than the limits established by Brazilian legislation, indicating that the method used for limes should not be used for the slags studied here.

scholarly journals Long term trends in fertility of soils under continuous cultivation and cereal cropping in southern Queensland. III. Distribution and kinetics of soil organic carbon in particle size fractions

Soil Research ◽  
1986 ◽  
Vol 24 (2) ◽  
pp. 293 ◽  
Author(s):  
RC Dalal ◽  
RJ Mayer
Keyword(s):  
Particle Size ◽  
Organic Matter ◽  
Organic Carbon ◽  
Soil Organic Carbon ◽  
Size Fraction ◽  
Organic C ◽  
Size Fractions ◽  
Particle Size Fractions ◽  
Clay Size Fraction ◽  
Sand Size

Distribution of soil organic carbon in sand-, silt- and clay-size fractions during cultivation for periods ranging from 20 to 70 years was studied in six major soils used for cereal cropping in southern Queensland. Particle-size fractions were obtained by dispersion in water using cation exchange resin, sieving and sedimentation. In the soils' virgin state no single particle-size fraction was found to be consistently enriched as compared to the whole soil in organic C in all six soils, although the largest proportion (48%) of organic C was in the clay-size fraction; silt and sand-size fractions contained remaining organic C in equal amounts. Upon cultivation, the amounts of organic C declined from all particle-size fractions in most soils, although the loss rates differed considerably among different fractions and from the whole soil. The proportion of the sand-size fraction declined rapidly (from 26% to 12% overall), whereas that of the clay-size fraction increased from 48% to 61% overall. The proportion of silt-size organic C was least affected by cultivation in most soils. It was inferred, therefore, that the sand-size organic matter is rapidly lost from soil, through mineralization as well as disintegration into silt-size and clay-size fractions, and that the clay fraction provides protection for the soil organic matter against microbial and enzymic degradation.

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