scholarly journals State-of-Charge Monitoring by Impedance Spectroscopy during Long-Term Self-Discharge of Supercapacitors and Lithium-Ion Batteries

Batteries ◽  
2018 ◽  
Vol 4 (3) ◽  
pp. 35 ◽  
Author(s):  
Peter Kurzweil ◽  
Mikhail Shamonin
Keyword(s):  
Impedance Spectroscopy ◽  
Lithium Ion Batteries ◽  
Lithium Ion ◽  
Charge Transfer Resistance ◽  
The State ◽  
State Of Charge ◽  
Transfer Resistance ◽  
Storage Devices ◽  
Electrochemical Storage

Frequency-dependent capacitance C(ω) is a rapid and reliable method for the determination of the state-of-charge (SoC) of electrochemical storage devices. The state-of-the-art of SoC monitoring using impedance spectroscopy is reviewed, and complemented by original 1.5-year long-term electrical impedance measurements of several commercially available supercapacitors. It is found that the kinetics of the self-discharge of supercapacitors comprises at least two characteristic time constants in the range of days and months. The curvature of the Nyquist curve at frequencies above 10 Hz (charge transfer resistance) depends on the available electric charge as well, but it is of little use for applications. Lithium-ion batteries demonstrate a linear correlation between voltage and capacitance as long as overcharge and deep discharge are avoided.

scholarly journals Estimation of lithium-ion battery state-of-charge using an extended kalman filter

2021 ◽  
Vol 10 (4) ◽  
pp. 1759-1768
Author(s):  
Mouhssine Lagraoui ◽  
Ali Nejmi ◽  
Hassan Rayhane ◽  
Abderrahim Taouni
Keyword(s):  
Kalman Filter ◽  
Lithium Ion Battery ◽  
Extended Kalman Filter ◽  
Lithium Ion ◽  
The State ◽  
Operating Conditions ◽  
State Of Charge ◽  
Ohmic Loss ◽  
Battery Management System ◽  
Transfer Resistance

The main goal of a battery management system (BMS) is to estimate parameters descriptive of the battery pack operating conditions in real-time. One of the most critical aspects of BMS systems is estimating the battery's state of charge (SOC). However, in the case of a lithium-ion battery, it is not easy to provide an accurate estimate of the state of charge. In the present paper we propose a mechanism based on an extended kalman filter (EKF) to improve the state-of-charge estimation accuracy on lithium-ion cells. The paper covers the cell modeling and the system parameters identification requirements, the experimental tests, and results analysis. We first established a mathematical model representing the dynamics of a cell. We adopted a model that comprehends terms that describe the dynamic parameters like SOC, open-circuit voltage, transfer resistance, ohmic loss, diffusion capacitance, and resistance. Then, we performed the appropriate battery discharge tests to identify the parameters of the model. Finally, the EKF filter applied to the cell test data has shown high precision in SOC estimation, even in a noisy system.

Accuracy analysis of the State-of-Charge and remaining run-time determination for lithium-ion batteries

Measurement ◽  
2009 ◽  
Vol 42 (8) ◽  
pp. 1131-1138 ◽  
Author(s):  
V. Pop ◽  
H.J. Bergveld ◽  
P.H.L. Notten ◽  
J.H.G. Op het Veld ◽  
P.P.L. Regtien
Keyword(s):  
Lithium Ion Batteries ◽  
Lithium Ion ◽  
The State ◽  
State Of Charge ◽  
Accuracy Analysis ◽  
Time Determination ◽  
Run Time

The State of Charge Estimation of Lithium-Ion Batteries Based on a Proportional-Integral Observer

2014 ◽  
Vol 63 (4) ◽  
pp. 1614-1621 ◽  
Author(s):  
Jun Xu ◽  
Chunting Chris Mi ◽  
Binggang Cao ◽  
Junjun Deng ◽  
Zheng Chen ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Lithium Ion ◽  
The State ◽  
State Of Charge ◽  
Proportional Integral ◽  
State Of Charge Estimation

scholarly journals Electrochemical Impedance Spectroscopy on the Performance Degradation of LiFePO4/Graphite Lithium-Ion Battery Due to Charge-Discharge Cycling under Different C-Rates

Energies ◽  
2019 ◽  
Vol 12 (23) ◽  
pp. 4507 ◽  
Author(s):  
Yusuke Abe ◽  
Natsuki Hori ◽  
Seiji Kumagai
Keyword(s):  
Charge Transfer ◽  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Electrochemical Impedance ◽  
Specific Capacity ◽  
Lithium Ion ◽  
Performance Degradation ◽  
Charge Transfer Resistance ◽  
Transfer Resistance ◽  
Charge Discharge

Lithium-ion batteries (LIBs) using a LiFePO4 cathode and graphite anode were assembled in coin cell form and subjected to 1000 charge-discharge cycles at 1, 2, and 5 C at 25 °C. The performance degradation of the LIB cells under different C-rates was analyzed by electrochemical impedance spectroscopy (EIS) and scanning electron microscopy. The most severe degradation occurred at 2 C while degradation was mitigated at the highest C-rate of 5 C. EIS data of the equivalent circuit model provided information on the changes in the internal resistance. The charge-transfer resistance within all the cells increased after the cycle test, with the cell cycled at 2 C presenting the greatest increment in the charge-transfer resistance. Agglomerates were observed on the graphite anodes of the cells cycled at 2 and 5 C; these were more abundantly produced in the former cell. The lower degradation of the cell cycled at 5 C was attributed to the lowered capacity utilization of the anode. The larger cell voltage drop caused by the increased C-rate reduced the electrode potential variation allocated to the net electrochemical reactions, contributing to the charge-discharge specific capacity of the cells.

Electrochemical Decomposition of Poly(Vinylidene Fluoride) Binder for a Graphite Negative Electrode in Lithium-Ion Batteries

2017 ◽  
Vol 893 ◽  
pp. 127-131 ◽  
Author(s):  
Min Ji Kim ◽  
Chang Hee Lee ◽  
Mun Hui Jo ◽  
Soon Ki Jeong
Keyword(s):  
Lithium Ion Batteries ◽  
Vinylidene Fluoride ◽  
Electrochemical Impedance ◽  
Negative Electrode ◽  
Reduction Process ◽  
Lithium Ion ◽  
Charge Transfer Resistance ◽  
Transfer Resistance ◽  
Electrode Resistance ◽  
Poly Vinylidene Fluoride

To clarify the electrochemical decomposition of poly (vinylidene fluoride) (PVdF) used as a binder for lithium-ion batteries while simultaneously verifying the correlation between electrode resistance and the PVdF content in graphite negative electrodes, in this study, we applied lithium bis (trifluoromethanesulfonyl) imide, which suppresses graphite exfoliation, as a salt. As a result, the electrochemical decomposition of PVdF was observed at a higher potential than that at which the electrolyte was decomposed during the reduction process. Additionally, this study demonstrated (through electrochemical impedance spectroscopy analysis) that electrode resistances such as solid electrolyte interface and charge transfer resistance proportionally increased with the PVdF content.

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