scholarly journals Visible-Light Driven Photocatalytic Degradation of Pirimicarb by Pt-Doped AgInS2 Nanoparticles

Catalysts ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 857
Author(s):  
Hweiyan Tsai ◽  
Janah Shaya ◽  
Siriluck Tesana ◽  
Vladimir B. Golovko ◽  
Syuan-Yun Wang ◽  
...  
Keyword(s):  
Visible Light ◽  
Active Species ◽  
Optimal Dosage ◽  
Catalytic Activities ◽  
Photodegradation Rate ◽  
Photocatalytic Activities ◽  
Visible Light Driven ◽  
Prospective Application ◽  
Acidic Conditions

This study describes the synthesis and characterization of Pt-doped AgInS2 nanoparticles and reports their prospective application as visible-light catalysts for photodegradation of frequently used pirimicarb insecticides, which pose serious health and environmental concerns. The nanomaterials were characterized by XRD, SEM, TEM, XPS, photoluminescence (PL), and UV–vis diffuse reflectance spectra (DRS). The presented photocatalytic method for water treatment from pirimicarb has the advantages of using visible light source without any costly additive such as H2O2 needed in other employed methods. The Pt-doped AgInS2 exhibited higher photocatalytic activities for pirimicarb degradation than undoped AgInS2. The 1.0 wt% Pt/AgInS2 photocatalyst exhibited the highest photodegradation rate, showing enhancement of 56% in comparison to the pure AgInS2 photocatalyst. The photodegradation rate was found to increase with increasing the catalyst dosage until reaching the optimal dosage of 1.0 g L−1. The pirimicarb degradation was significantly more efficient under acidic conditions, and the rates drastically dropped upon increasing the pH. The photocatalytic mechanism of Pt/AgInS2 composites and the main active species involved in the process were investigated. The mechanism of pirimicarb degradation was proposed via two different pathways, N-dealkylation and decarbamoylation. Lastly, the photocatalysts demonstrated remarkable stability and were reusable in three successive catalytic tests without compromising catalytic activities. The Pt/AgInS2 photocatalyst also exhibited efficiency and feasibility in pirimicarb removal from environmental lake and river water samples.

Synthesis and characterization of visible light-driven W-doped Bi 2 MoO 6 photocatalyst and its photocatalytic activities

2017 ◽  
Vol 194 ◽  
pp. 114-117 ◽  
Author(s):  
Anukorn Phuruangrat ◽  
Phattranit Dumrongrojthanath ◽  
Somchai Thongtem ◽  
Titipun Thongtem
Keyword(s):  
Visible Light ◽  
Synthesis And Characterization ◽  
Photocatalytic Activities ◽  
Visible Light Driven

Synthesis and characterization of CdS@ZnO nanoribbon@quantum dot and their enhanced visible-light-driven photocatalytic activities

2020 ◽  
Vol 34 (10) ◽  
pp. 2050088
Author(s):  
Qiang-Ye Gao ◽  
Yong-Dong Xie ◽  
Bai-Chun Zhan ◽  
Xing-Zhen Xu
Keyword(s):  
Thermal Decomposition ◽  
Quantum Dot ◽  
Visible Light ◽  
Decomposition Temperature ◽  
Ethanol Solution ◽  
Photoelectric Device ◽  
Photocatalytic Activities ◽  
Visible Light Driven ◽  
Cds Nanobelts

CdS/ZnO nanoribbon/quantum dot was prepared using thermal decomposition method. Size and distribution of ZnO quantum dots on CdS nanobelt were controlled by concentrations of zinc acetate ethanol solution and thermal decomposition temperature. The structure and optical properties of CdS nanobelts and CdS/ZnO heterostructures are studied by XRD, TEM, PL and Raman scattering and UV–Vis absorption spectra. The photocatalytic performances of CdS nanobelts and CdS/ZnO heterostructures are tested by photocatalytic degradation of RhB aqueous solution under visible light irradiation. Compared with that (83.57%) of CdS nanobelts, the degradation rate (88.66%) of RhB using CdS/ZnO heterostructures as catalyst is significantly improved, which suggests better development prospect in photocatalytic technology and photoelectric device.

scholarly journals Ionic Liquid-Assisted Synthesis of Ag3PO4 Spheres for Boosting Photodegradation Activity under Visible Light

Catalysts ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 788
Author(s):  
Beibei Zhang ◽  
Lu Zhang ◽  
Yulong Zhang ◽  
Chao Liu ◽  
Jiexiang Xia ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Visible Light ◽  
High Efficiency ◽  
Chemical Precipitation ◽  
Active Species ◽  
Precipitation Method ◽  
Dihydrogen Phosphate ◽  
Xrd Pattern ◽  
Simple Chemical ◽  
Visible Light Driven

In this work, a simple chemical precipitation method was employed to prepare spherical-like Ag3PO4 material (IL-Ag3PO4) with exposed {111} facet in the presence of reactive ionic liquid 1-butyl-3-methylimidazole dihydrogen phosphate ([Omim]H2PO4). The crystal structure, microstructure, optical properties, and visible-light photocatalytic performance of as-prepared materials were studied in detail. The addition of ionic liquids played a crucial role in forming spherical-like morphology of IL-Ag3PO4 sample. Compared with traditional Ag3PO4 material, the intensity ratio of {222}/{200} facets in XRD pattern of IL-Ag3PO4 was significantly enhanced, indicating the main {111} facets exposed on the surface of IL-Ag3PO4 sample. The presence of exposed {111} facet was advantageous for facilitating the charge carrier transfer and separation. The light-harvesting capacity of IL-Ag3PO4 was larger than that of Ag3PO4. The photocatalytic activity of samples was evaluated by degrading rhodamine B (RhB) and p-chlorophenol (4-CP) under visible light. The photodegradation efficiencies of IL-Ag3PO4 were 1.94 and 2.45 times higher than that of Ag3PO4 for RhB and 4-CP removal, respectively, attributing to a synergy from the exposed {111} facet and enhanced photoabsorption. Based on active species capturing experiments, holes (h+), and superoxide radical (•O2−) were the main active species for visible-light-driven RhB photodegradation. This study will provide a promising prospect for designing and synthesizing ionic liquid-assisted photocatalysts with a high efficiency.

scholarly journals Real roles of perylene diimides for improving photocatalytic activity

RSC Advances ◽  
2020 ◽  
Vol 10 (39) ◽  
pp. 23024-23037 ◽  
Author(s):  
Fengxia Zhang ◽  
Wenjing Li ◽  
Tianyi Jiang ◽  
Xuemei Li ◽  
Yuanyuan Shao ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Photocatalytic Activity ◽  
Visible Light ◽  
Hydrothermal Method ◽  
Perylene Diimides ◽  
Photodegradation Rate ◽  
Composite Photocatalysts ◽  
Visible Light Driven

Three novel visible-light-driven composite photocatalysts were synthesized by hydrothermal method. The effects of introducing PDIs with different structures into TiO2 were evaluated by assaying the photodegradation rate of methylene blue.

Solvothermal synthesis and visible light-driven photocatalytic degradation for tetracycline of Fe-doped SrTiO3

RSC Advances ◽  
2014 ◽  
Vol 4 (88) ◽  
pp. 47615-47624 ◽  
Author(s):  
Ping Li ◽  
Chunbo Liu ◽  
Guoling Wu ◽  
Yang Heng ◽  
Shuang Lin ◽  
...  
Keyword(s):  
Visible Light ◽  
Photocatalytic Degradation ◽  
Visible Light Irradiation ◽  
Solvothermal Synthesis ◽  
Solvothermal Method ◽  
Light Irradiation ◽  
Photocatalytic Activities ◽  
Visible Light Driven ◽  
Facile Solvothermal Method

In this paper, Fe-doped SrTiO3 (FSTO) photocatalysts were successfully prepared via a facile solvothermal method, and their photocatalytic activities for degrading tetracycline (TC) under visible light irradiation were examined.

Enhanced visible-light-driven photocatalytic activities of Bi2Fe4O9/g-C3N4 composite photocatalysts

2018 ◽  
Vol 104 ◽  
pp. 104-111 ◽  
Author(s):  
Geming Wang ◽  
Shutong Liu ◽  
Tiancheng He ◽  
Xuan Liu ◽  
Quanrong Deng ◽  
...  
Keyword(s):  
Visible Light ◽  
Composite Photocatalysts ◽  
Photocatalytic Activities ◽  
Visible Light Driven

scholarly journals Silver Orthophosphate Immobilized on Flaky Layered Double Hydroxides as the Visible-Light-Driven Photocatalysts

2012 ◽  
Vol 2012 ◽  
pp. 1-6 ◽  
Author(s):  
Xianlu Cui ◽  
Yaogang Li ◽  
Qinghong Zhang ◽  
Hongzhi Wang
Keyword(s):  
Visible Light ◽  
Diffuse Reflectance Spectroscopy ◽  
Diffraction Field ◽  
X Ray Diffraction ◽  
Transmission Electron ◽  
Photocatalytic Activities ◽  
Visible Light Driven ◽  
Double Hydroxide ◽  
Double Hydroxides ◽  
Acid Red G

Flaky layered double hydroxide (FLDH) was prepared by the reconstruction of its oxide in alkali solution. The composites with FLDH/Ag3PO4mass ratios at 1.6 : 1 and 3 : 1 were fabricated by the coprecipitation method. The powders were characterized by X-ray diffraction, field-emission scanning electron microscopy, transmission electron microscope, and UV-vis diffuse reflectance spectroscopy. The results indicated that the well-distributed Ag3PO4in a fine crystallite size was formed on the surface of FLDH. The photocatalytic activities of the Ag3PO4immobilized on FLDH were significantly enhanced for the degradation of acid red G under visible light irradiation compared to bare Ag3PO4. The composite with the FLDH/Ag3PO4mass ratio of 3 : 1 showed a higher photocatalytic efficiency.

Few-Layered MoS2 Nanoparticles Loaded TiO2 Nanosheets with Exposed {001} Facets for Enhanced Photocatalytic Activity

NANO ◽  
2018 ◽  
Vol 13 (11) ◽  
pp. 1850129 ◽  
Author(s):  
Chujun Chen ◽  
Xia Xin ◽  
Jinniu Zhang ◽  
Gang Li ◽  
Yafeng Zhang ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Charge Carrier ◽  
Visible Light ◽  
Recombination Rate ◽  
Active Species ◽  
Molar Ratio ◽  
Carrier Recombination ◽  
Tio2 Nanosheets ◽  
Photocatalytic Activities ◽  
Charge Carrier Recombination

To improve the high charge carrier recombination rate and low visible light absorption of {001} facets exposed TiO2 [TiO2(001)] nanosheets, few-layered MoS2 nanoparticles were loaded on the surfaces of TiO2(001) nanosheets by a simple photodeposition method. The photocatalytic activities towards Rhodamine B (RhB) were investigated. The results showed that the MoS2–TiO2(001) nanocomposites exhibited much enhanced photocatalytic activities compared with the pure TiO2(001) nanosheets. At an optimal Mo/Ti molar ratio of 25%, the MoS2–TiO2(001) nanocomposites displayed the highest photocatalytic activity, which took only 30[Formula: see text]min to degrade 50[Formula: see text]mL of RhB (50[Formula: see text]mg/L). The active species in the degradation reaction were determined to be h[Formula: see text] and [Formula: see text]OH according to the free radical trapping experiments. The reduced charge carrier recombination rate, enhanced visible light utilization and increased surface areas contributed to the enhanced photocatalytic performances of the 25% MoS2–TiO2(001) nanocomposites.

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