scholarly journals The Synergistic Effect of Pyridinic Nitrogen and Graphitic Nitrogen of Nitrogen-Doped Graphene Quantum Dots for Enhanced TiO2 Nanocomposites’ Photocatalytic Performance

Catalysts ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 438 ◽  
Author(s):  
Fei Li ◽  
Ming Li ◽  
Yi Luo ◽  
Ming Li ◽  
Xinyu Li ◽  
...  

In this study, nitrogen-doped graphene quantum dots (N-GQDs) and a TiO2 nanocomposite were synthesized using a simple hydrothermal route. Ammonia water was used as a nitrogen source to prepare the N-GQDs. When optically characterized by UV-vis, N-GQDs reveal stronger absorption peaks in the range of ultraviolet (UV) light than graphene quantum dots (GQDs). In comparison with GQDs/TiO2 and pure TiO2, the N-GQDs/TiO2 have significantly improved photocatalytic performance. In particular, it was found that, when the added amount of ammonia water was 50 mL, the content of pyridinic N and graphitic N were as high as 22.47% and 31.44%, respectively. Most important, the photocatalytic activity of N-GQDs/TiO2-50 was about 95% after 12 min. The results illustrated that pyridinic N and graphitic N play a significant role in photocatalytic performance.

2017 ◽  
Vol 508 ◽  
pp. 154-158 ◽  
Author(s):  
Lang Sun ◽  
Yi Luo ◽  
Ming Li ◽  
Guanghui Hu ◽  
Yongjie Xu ◽  
...  

2021 ◽  
Vol 623 ◽  
pp. 119077
Author(s):  
Rumwald Leo G. Lecaros ◽  
Reincess E. Valbuena ◽  
Lemmuel L. Tayo ◽  
Wei-Song Hung ◽  
Chien-Chieh Hu ◽  
...  

2021 ◽  
Author(s):  
Hemalatha Kuzhandaivel ◽  
Sornalatha Manickam ◽  
Suresh Kannan Balasingam ◽  
Manik Clinton Franklin ◽  
Hee-Je Kim ◽  
...  

Sulfur and nitrogen-doped graphene quantum dots/polyaniline nanocomposites were synthesized and their electrochemical charge storage properties were tested for supercapacitor applications.


ACS Omega ◽  
2021 ◽  
Vol 6 (3) ◽  
pp. 2167-2176
Author(s):  
Rania Adel ◽  
Shaker Ebrahim ◽  
Azza Shokry ◽  
Moataz Soliman ◽  
Marwa Khalil

Nanomaterials ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 140
Author(s):  
Madison Frieler ◽  
Christine Pho ◽  
Bong Han Lee ◽  
Hana Dobrovolny ◽  
Giridhar R. Akkaraju ◽  
...  

With 18 million new cases diagnosed each year worldwide, cancer strongly impacts both science and society. Current models of cancer cell growth and therapeutic efficacy in vitro are time-dependent and often do not consider the Emax value (the maximum reduction in the growth rate), leading to inconsistencies in the obtained IC50 (concentration of the drug at half maximum effect). In this work, we introduce a new dual experimental/modeling approach to model HeLa and MCF-7 cancer cell growth and assess the efficacy of doxorubicin chemotherapeutics, whether alone or delivered by novel nitrogen-doped graphene quantum dots (N-GQDs). These biocompatible/biodegradable nanoparticles were used for the first time in this work for the delivery and fluorescence tracking of doxorubicin, ultimately decreasing its IC50 by over 1.5 and allowing for the use of up to 10 times lower doses of the drug to achieve the same therapeutic effect. Based on the experimental in vitro studies with nanomaterial-delivered chemotherapy, we also developed a method of cancer cell growth modeling that (1) includes an Emax value, which is often not characterized, and (2), most importantly, is measurement time-independent. This will allow for the more consistent assessment of the efficiency of anti-cancer drugs and nanomaterial-delivered formulations, as well as efficacy improvements of nanomaterial delivery.


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