scholarly journals Coordination Polymers and Metal-Organic Frameworks: Structures and Applications—A Themed Issue in Honor of Professor Christoph Janiak on the Occasion of His 60th Birthday

Chemistry ◽  
2021 ◽  
Vol 3 (3) ◽  
pp. 831-833
Author(s):  
Catherine E. Housecroft
Keyword(s):  
Ionic Liquids ◽  
Supramolecular Chemistry ◽  
Hybrid Materials ◽  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Inorganic Materials ◽  
60Th Birthday ◽  
Organic Hybrid ◽  
Metal Organic

This themed issue of Chemistry is in honor of Professor Christoph Janiak on the occasion of his 60th birthday, and celebrates his innovative contributions to the fields of supramolecular chemistry, coordination polymers, networks and metal-organic frameworks, inorganic/organic hybrid materials and inorganic materials from ionic liquids [...]

scholarly journals Prospects for electroactive and conducting framework materials

2019 ◽  
Vol 377 (2149) ◽  
pp. 20180226 ◽  
Author(s):  
Ryuichi Murase ◽  
Bowen Ding ◽  
Qinyi Gu ◽  
Deanna M. D'Alessandro
Keyword(s):  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Inorganic Materials ◽  
Framework Materials ◽  
Solar Energy Harvesting ◽  
Harvesting Systems ◽  
Potential Applications ◽  
History Of ◽  
Metal Organic ◽  
The Rich

Electroactive and conducting framework materials, encompassing coordination polymers and metal–organic frameworks, have captured the imagination of the scientific community owing to their highly designable nanoporous structures and their potential applications in electrochromic devices, electrocatalysts, porous conductors, batteries and solar energy harvesting systems, among many others. While they are now considered integral members of the broader field of inorganic materials, it is timely to reflect upon their strengths and challenges compared with ‘traditional’ solid-state materials such as minerals, pigments and zeolites. Indeed, the latter have been known since ancient times and have been prized for centuries in fields as diverse as art, archaeology and industrial catalysis. This opinion piece considers a brief historical perspective of traditional electroactive and conducting inorganic materials, with a view towards very recent experimental progress and new directions for future progress in the burgeoning area of coordination polymers and metal–organic frameworks. Overall, this article bears testament to the rich history of electroactive solids and looks at the challenges inspiring a new generation of scientists. This article is part of the theme issue ‘Mineralomimesis: natural and synthetic frameworks in science and technology’.

scholarly journals Nanoscale Metamaterials: Meta-MOFs and Framework Materials with Anomalous Behavior

2019 ◽  
Author(s):  
François-Xavier Coudert ◽  
Jack D. Evans
Keyword(s):  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Chemical Properties ◽  
Anomalous Behavior ◽  
Inorganic Materials ◽  
Covalent Organic Frameworks ◽  
Crystalline Materials ◽  
Framework Materials ◽  
Metal Organic ◽  
Structural Responses

As the number of framework materials known and characterized in the literature grows, it becomes apparent that they can carry properties rarely encountered in more conventional, dense inorganic materials. Among these materials with unusual physical or chemical properties are the ubiquitous metal–organic frameworks, covalent organic frameworks, dense coordination polymers, and molecular frameworks. Many can respond to stimulation by displaying structural responses and changes in properties that range from counter-intuitive to thermodynamically forbidden. In that, they share large similarities with metamaterials, which are engineered to generate properties not found in “normal” materials. We review here the surprising behavior of these meta-MOFs and other framework materials that display properties “beyond” (μετά) the boundaries of common crystalline materials.<br>

Long Afterglow MOFs: The Frontier Study on Synthesis and Applications

2021 ◽  
Author(s):  
Jiangyan Yuan ◽  
Jie Dong ◽  
Sheng-Bin Lei ◽  
Wenping Hu
Keyword(s):  
Surface Area ◽  
Hybrid Materials ◽  
Metal Organic Frameworks ◽  
Internal Surface ◽  
Optical Characteristics ◽  
Internal Surface Area ◽  
Organic Hybrid ◽  
Long Afterglow ◽  
Metal Organic ◽  
New Type

As a new type of inorganic-organic hybrid materials with adjustable structures, high internal surface area and unique optical characteristics, Metal-Organic Frameworks (MOFs) with long afterglow behavior have attract more attention....

scholarly journals Nanoscale Metamaterials: Meta-MOFs and Framework Materials with Anomalous Behavior

2019 ◽  
Author(s):  
François-Xavier Coudert ◽  
Jack D. Evans
Keyword(s):  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Chemical Properties ◽  
Anomalous Behavior ◽  
Inorganic Materials ◽  
Covalent Organic Frameworks ◽  
Crystalline Materials ◽  
Framework Materials ◽  
Metal Organic ◽  
Structural Responses

As the number of framework materials known and characterized in the literature grows, it becomes apparent that they can carry properties rarely encountered in more conventional, dense inorganic materials. Among these materials with unusual physical or chemical properties are the ubiquitous metal–organic frameworks, covalent organic frameworks, dense coordination polymers, and molecular frameworks. Many can respond to stimulation by displaying structural responses and changes in properties that range from counter-intuitive to thermodynamically forbidden. In that, they share large similarities with metamaterials, which are engineered to generate properties not found in “normal” materials. We review here the surprising behavior of these meta-MOFs and other framework materials that display properties “beyond” (μετά) the boundaries of common crystalline materials.<br>

scholarly journals Meta-MOFs: Framework Materials with Anomalous Behavior

2018 ◽  
Author(s):  
François-Xavier Coudert ◽  
Jack D. Evans
Keyword(s):  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Chemical Properties ◽  
Anomalous Behavior ◽  
Inorganic Materials ◽  
Covalent Organic Frameworks ◽  
Crystalline Materials ◽  
Framework Materials ◽  
Metal Organic ◽  
Structural Responses

As the number of framework materials known and characterized in the literature grows, it becomes apparent that they can carry properties rarely encountered in more conventional, dense inorganic materials. Among these materials with unusual physical or chemical properties are the ubiquitous metal–organic frameworks, covalent organic frameworks, dense coordination polymers, and molecular frameworks. Many can respond to stimulation by displaying structural responses and changes in properties that range from counter-intuitive to thermodynamically forbidden. In that, they share large similarities with metamaterials, which are engineered to generate properties not found in “normal” materials. We review here the surprising behavior of these meta-MOFs, that display properties “beyond” (μετά) the boundaries of common crystalline materials.<br>

Single crystal to single crystal transformation of spin-crossover coordination polymers from 3D frameworks to 2D layers

2021 ◽  
Vol 9 (15) ◽  
pp. 5082-5087
Author(s):  
Yu Gong ◽  
Wang-Kang Han ◽  
Hui-Shu Lu ◽  
Qing-Tao Hu ◽  
Huan Tu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Ligand Exchange ◽  
Spin Crossover ◽  
Metal Organic Frameworks ◽  
Crystal Transformation ◽  
Metal Organic

New Hofmann-type metal–organic frameworks display rare and complete ligand exchange induced single crystal to single crystal transformations from 3D frameworks to 2D layers, accompanied by magnetic properties transition from two-step SCO behavior to hysteretic SCO behavior.

Inverted metal–organic frameworks: isoreticular decoration with organic anions using principles of supramolecular chemistry

2021 ◽  
Vol 74 (1-3) ◽  
pp. 169-177
Author(s):  
Claude L. Mertzenich ◽  
Giannis S. Papaefstathiou ◽  
Tomislav Friščić ◽  
Tamara D. Hamilton ◽  
Dejan-Krešimir Bučar ◽  
...  
Keyword(s):  
Supramolecular Chemistry ◽  
Metal Organic Frameworks ◽  
Organic Anions ◽  
Metal Organic

Synthesis, designing strategies and photocatalytic charge dynamics of Metal-Organic Frameworks (MOFs): A catalyzed Photo-degradation approach towards Organic Dyes

2021 ◽  
Author(s):  
Ayushi Singh ◽  
Ashish Kumar Singh ◽  
Jian-Qiang Liu ◽  
Abhinav Kumar
Keyword(s):  
Small Molecule ◽  
Coordination Polymers ◽  
Organic Dyes ◽  
Metal Organic Frameworks ◽  
Gas Storage ◽  
New Variety ◽  
Photo Degradation ◽  
Charge Dynamics ◽  
Potential Applications ◽  
Metal Organic

Metal-organic frameworks (MOFs) or coordination polymers (CPs) are regarded as new variety of materials that find potential applications in plethora of areas such as gas/small molecule absorption/separation, gas storage, membranes...

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