Long Afterglow MOFs: The Frontier Study on Synthesis and Applications

Author(s):  
Jiangyan Yuan ◽  
Jie Dong ◽  
Sheng-Bin Lei ◽  
Wenping Hu

As a new type of inorganic-organic hybrid materials with adjustable structures, high internal surface area and unique optical characteristics, Metal-Organic Frameworks (MOFs) with long afterglow behavior have attract more attention....

The Analyst ◽  
2016 ◽  
Vol 141 (4) ◽  
pp. 1279-1285 ◽  
Author(s):  
Min-Qiang Wang ◽  
Cui Ye ◽  
Shu-Juan Bao ◽  
Yan Zhang ◽  
Ya-Nan Yu ◽  
...  

Metal–organic frameworks (MOFs) have recently attracted much interest in electrochemical fields due to their controlled porosity, large internal surface area, and countless structural topologies.


2015 ◽  
Vol 17 (18) ◽  
pp. 11962-11973 ◽  
Author(s):  
Yi Bao ◽  
Richard L. Martin ◽  
Maciej Haranczyk ◽  
Michael W. Deem

Metal–organic frameworks (MOFs) offer unprecedented atom-scale design and structural tunability, largely due to the vast number of possible organic linkers which can be utilized in their assembly.


Chemistry ◽  
2021 ◽  
Vol 3 (3) ◽  
pp. 831-833
Author(s):  
Catherine E. Housecroft

This themed issue of Chemistry is in honor of Professor Christoph Janiak on the occasion of his 60th birthday, and celebrates his innovative contributions to the fields of supramolecular chemistry, coordination polymers, networks and metal-organic frameworks, inorganic/organic hybrid materials and inorganic materials from ionic liquids [...]


2021 ◽  
Vol 33 (2) ◽  
pp. 245-252
Author(s):  
ABHINANDAN RANA

Metal-organic frameworks (MOFs) are inorganic-organic hybrid porous materials that are composed of positively charged metal ions and organic linkers. The metal ions form nodes that connect the arms of the linkers together to form one-, two-, or three-dimensional structures. Due to this void structure, MOFs have an unusually large internal surface area. They have received enormous interest in recent years particularly as newly developed porous materials. They possess a wide range of potential applications like gas storage, catalysis, sensors, drug delivery, adsorption, etc. In present review article, synthetic methods and applications of MOFs have been discussed.


Energies ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 964
Author(s):  
Thomas Steiner ◽  
Daniel Neurauter ◽  
Peer Moewius ◽  
Christoph Pfeifer ◽  
Verena Schallhart ◽  
...  

This study investigates geometric parameters of commercially available or recently published models of catalyst substrates for passenger vehicles and provides a numerical evaluation of their influence on heat-up behavior. Parameters considered to have a significant impact on the thermal economy of a monolith are: internal surface area, heat transfer coefficient, and mass of the converter, as well as its heat capacity. During simulation experiments, it could be determined that the primary role is played by the mass of the monolith and its internal surface area, while the heat transfer coefficient only has a secondary role. Furthermore, an optimization loop was implemented, whereby the internal surface area of a commonly used substrate was chosen as a reference. The lengths of the thin wall and high cell density monoliths investigated were adapted consecutively to obtain the reference internal surface area. The results obtained by this optimization process contribute to improving the heat-up performance while simultaneously reducing the valuable installation space required.


Sensors ◽  
2021 ◽  
Vol 21 (5) ◽  
pp. 1679
Author(s):  
Roberta Puglisi ◽  
Anna L. Pellegrino ◽  
Roberto Fiorenza ◽  
Salvatore Scirè ◽  
Graziella Malandrino

Gadolinium metal-organic frameworks (Gd-MOFs) and Eu-doped Gd-MOFs have been synthesized through a one-pot green approach using commercially available reagents. The 1,4-benzenedicarboxylic acid (H2-BDC) and 2,6-naphthalenedicarboxylic acid (H2-NDC) were chosen as ditopic organic linkers to build the 3D structure of the network. The Gd-MOFs were characterized using powder X-ray diffraction (XRD), FT-IR spectroscopy, field emission scanning electron microscopy (FE-SEM) and N2 adsorption–desorption analysis. The Gd-MOF structures were attributed comparing the XRD patterns, supported by the FT-IR spectra, with data reported in the literature for Ln-MOFs of similar lanthanide ionic radius. FE-SEM characterization points to the effect of the duration of the synthesis to a more crystalline and organized structure, with grain dimensions increasing upon increasing reaction time. The total surface area of the MOFs has been determined from the application of the Brunauer–Emmett–Teller method. The study allowed us to correlate the processing conditions and ditopic linker dimension to the network surface area. Both Gd-MOF and Eu-doped Gd-MOF have been tested for sensing of the inorganic ions such as Fe3+ and Cr2O72−.


2021 ◽  
Vol 45 (7) ◽  
pp. 3432-3440
Author(s):  
Yu Xin ◽  
Jun Zhou ◽  
Yong Heng Xing ◽  
Feng Ying Bai ◽  
Li Xian Sun

Seven 3D metal-organic frameworks have been designed and synthesized by the hydrothermal synthetic method based on the ligand 5-aminoisophthalic acid. Complexes 1-4 have better photocatalytic degradation properties for dyes CV.


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