scholarly journals Distribution of Characteristic Times: A High-Resolution Spectrum Approach for Visualizing Chemical Relaxation and Resolving Kinetic Parameters of Ionic-Electronic Conducting Ceramic Oxides

Coatings ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1240
Author(s):  
Fuyao Yan ◽  
Yiheng Wang ◽  
Ying Yang ◽  
Lei Zhu ◽  
Hui Hu ◽  
...  

Surface exchange coefficient (k) and bulk diffusion coefficient (D) are important properties to evaluate the performance of mixed ionic-electronic conducting (MIEC) ceramic oxides for use in energy conversion devices, such as solid oxide fuel cells. The values of k and D are usually estimated by a non-linear curve fitting procedure based on electrical conductivity relaxation (ECR) measurement. However, the rate-limiting mechanism (or the availability of k and D) and the experimental imperfections (such as flush delay for gaseous composition change, τf) are not reflected explicitly in the time–domain ECR data, and the accuracy of k and D demands a careful sensitivity analysis of the fitting error. Here, the distribution of characteristic times (DCT) converted from time–domain ECR data is proposed to overcome the above challenges. It is demonstrated that, from the DCT spectrum, the rate-limiting mechanism and the effect of τf are easily recognized, and the values of k, D and τf can be determined conjunctly. A strong robustness of determination of k and D is verified using noise-containing ECR data. The DCT spectrum opens up a way towards visible and credible determination of kinetic parameters of MIEC ceramic oxides.

1999 ◽  
Vol 121 (1) ◽  
pp. 37-41 ◽  
Author(s):  
W. A. Moussa ◽  
A. N. AbdelHamid

A practical technique is investigated for the determination of dynamic stresses in pipelines through the use of finite element method (FEM) and field measurement vibrations at selected points. Numerical simulation of a randomly loaded pipeline structure is used to establish the validity of the technique in the time domain. The analysis is carried out for a fixed-hinged pipe model. The results show that lack of coincidence between the vibration measurement points (VMPs) and the exciting force, or the use of only translational vibration measurements (TVMs) produce an approximate stress picture. The extent of the “error” in these cases is found to depend on the density of the VMPs and the proximity between these points and the exciting force location. A safety-related risk assessment is applied to find the minimum distance between measuring points that is needed to meet design codes reliability specifications.


2020 ◽  
Vol 1 (1) ◽  
pp. 21
Author(s):  
Syahrial Ayub ◽  
Muhammad Zuhdi ◽  
Muhammad Taufik ◽  
Gunawan Gunawan

Volcanic earthquakes of mount Merapi have been investigated periodically. The investigation aims to determine the hypocenter and epicenter of mount Merapi's volcanic earthquake using wave polarization analysis. The analysis was carried out in three domains, which are the time domain, the frequency domain, and the space domain. The analysis in the time domain was conducted by the arrival time of the volcanic earthquake, and the analysis in the frequency domain was done by observing the spectrum to get information on source frequency and bandwidth passed from polarization analysis, while the analysis in the space domain was conducted especially on hypocenter determination of the volcanic earthquakes. The analysis leads to the frequency of source 6 Hz and a bandwidth of 0.1 Hz. Thus, the hypocenter of volcanic earthquakes by polarization analysis was distributed to depth from 670 m to 3250 m from Merapi's top


1981 ◽  
Vol 4 (3) ◽  
pp. 615-623
Author(s):  
Sudhangshu B. Karmakar

This paper illustrates by means of a simple example a new approach for the determination of the time domain response of a class of nonlinear systems. The system under investigation is assumed to be described by a nonlinear differential equation with forcing term. The response of the system is first obtained in terms of the input in the form of a Volterra functional expansion. Each of the components in the expansion is first transformed into a multidimensional frequency domain and then to a single dimensional frequency domain by the technique of association of variables. By taking into consideration the conditions for the rapid convergence of the functional expansion the response of the system in the frequency domain can effectively be obtained by taking only the first few terms of the expansion. Time domain response is then found by inverse Laplace transform.


2003 ◽  
Vol 11 (03) ◽  
pp. 491-501 ◽  
Author(s):  
Andrzej Hanyga

A method previously developed for asymptotic solution of systems of integro-differential equations with singular memory is applied to the determination of the time-domain asymptotic Green's function of Biot's poroelasticity. Asymptotic time-domain Green's functions are constructed in a neighborhood of the wavefronts. The general anisotropic medium as well as the isotropic case are considered.


2013 ◽  
Vol 30 (7) ◽  
pp. 1447-1459 ◽  
Author(s):  
V. Venkatesh ◽  
S. J. Frasier

Abstract Spaced antenna baseline wind retrievals, in conjunction with traditional Doppler measurements, are a potential means of fine angular resolution weather radar wind vector retrieval. A spaced antenna implementation on an X-band active phased array architecture is investigated via Monte Carlo simulations of the backscattered electric fields at the antenna array. Several retrieval methods are exercised on the data produced by the simulator. Parameters of the X-band spaced-antenna design are then optimized. Benefiting from the parametric fitting procedure inherent in the time domain slope at zero lag and full correlation analysis, the study finds both of these algorithms to be more immune to thermal noise than the spectral retrieval algorithms investigated. With appropriately chosen baselines, these time domain algorithms are shown to perform adequately for 5-dB SNR and above. The study also shows that the Gaussian slope at zero lag (G-SZL) algorithm leads to more robust estimates over a wider range of beamwidths than the Gaussian full correlation analysis (G-FCA) algorithm. The predicted performance of the X-band array is compared to a similar spaced antenna implementation on the S-band National Weather Radar Testbed (NWRT). Since the X-band signal decorrelates more rapidly (relative to S band), the X-band array accumulates more independent samples, thereby obtaining lower retrieval uncertainty. However, the same rapid decorrelation also limits the maximum range of the X-band array, as the pulse rate must be sufficiently high to sample the cross-correlation function. It also limits the range of tolerable turbulence velocity within the resolution cell.


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