scholarly journals Evaluation of Formate Salt PCM’s for Latent Heat Thermal Energy Storage

Energies ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 765
Author(s):  
Samuel Gage ◽  
Prashant Sharan ◽  
Craig Turchi ◽  
Judy Netter
Keyword(s):  
Energy Storage ◽  
Latent Heat ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Sodium Formate ◽  
Heat Of Fusion ◽  
Ftir Analysis ◽  
Sodium Potassium ◽  
Sodium Calcium ◽  
Calcium Formate

This work examines formate salts as potential phase change materials (PCMs) for middle-high temperature (≤250 °C) latent heat thermal energy storage applications. The thermophysical properties of three formate salts were characterized: pure sodium formate and binary blends of sodium/potassium formate and sodium/calcium formate. The stability of formate PCM’s was evaluated by thermal cycling using differential scanning calorimetry where sodium formate and sodium/potassium formate appeared stable over 600 cycles, while sodium/calcium formate exhibited a monotonic decrease in heat of fusion over the test period. A longer test with sodium formate led to gas release and decomposition of the salt. FTIR analysis of the PCM showed degradation of formate to oxalate. T-history experiments with 50-g PCM quantities demonstrated a bulk supercooling of only 2–3 °C for these salts. Thermal conductivity enhancement of over 700% was achieved by embedding aluminum in the solid PCM. Finally, mild carbon steel was immersed in molten sodium formate for up to 2000 h. Sodium formate was found to be non-corrosive, as calculated by mass loss and confirmed by cross-sectional high-resolution microscopy. FTIR analysis of the PCM after 2000 h shows oxidation at the free surface, while the bulk PCM remained unchanged, further indicating a need to protect the formate from atmospheric exposure when used as a PCM.

scholarly journals Development of Binary Eutectic Organic Phase Change Materials for Solar Thermal Energy Storage Systems

2019 ◽  
Vol 9 (2) ◽  
pp. 2207-2210
Keyword(s):  
Energy Storage ◽  
Melting Point ◽  
Latent Heat ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Solar Thermal ◽  
Heat Of Fusion ◽  
Solar Thermal Energy ◽  
Latent Heat Of Fusion ◽  
High Latent Heat

Solar thermal energy storage unit anchored fatty acids as Phase Change Materials (PCMs) having narrow range of transition temperature and high latent heat of fusion. In this paper, a new novel eutectic PCM was developed by using a fatty acid (acetamide) and non-paraffin organic PCM (acetanilide) for a sharp melting point and high latent heat of fusion. The optimized eutectic PCM may be used for middle temperature range solar thermal energy storage systems. The binary mixture of acetamide and acetanilide at various compositions by mass ratio (wt%) was prepared and optimized experimentally for lowest value of melting point at a eutectic mixture composition of 60 wt% of acetamide and 40 wt% of acetanilide. Eutectic PCM was analyzed by Differential Scanning Calorimetry (DSC) and Field-Emission Scanning Electron Microscopy (FE-SEM). DSC results revealed that optimized eutectic PCM has a sharp melting point of 65.37°C and high latent heat of fusion of 224.67 kJ/kg. Accelerated thermal cycle testing of optimized eutectic PCM was performed for 100 melting and freezing cycles and change in melting temperature and latent heat of fusion was acceptable.

Heat Exchanger Performance in Latent Heat Thermal Energy Storage

1980 ◽  
Vol 102 (2) ◽  
pp. 112-118 ◽  
Author(s):  
R. N. Smith ◽  
T. E. Ebersole ◽  
F. P. Griffin
Keyword(s):  
Heat Transfer ◽  
Energy Storage ◽  
Latent Heat ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Solid Phase ◽  
Storage System ◽  
Temperature Drop ◽  
Heat Of Fusion ◽  
Analytical Prediction

An experimental study was made of the heat transfer in a component of a low temperature thermal energy storage system using latent heat of fusion of a phase change material (PCM). Measurements were made of the temperature rise of water flowing in a channel adjacent to a container filled with a freezing PCM, Gulfwax 33. In addition, temperature measurements within the PCM provided the location of the liquid/solid interface as a function of time. A simple analytical prediction is compared with the data to provide a verification of the qualitative observations. Certain multidimensional effects which occur during the freezing (discharge) mode of operation are identified especially the enhancement of freezing rates when the PCM container sidewalls (those not in contact with the heat exhange fluid) are conducting and are closely spaced. One limitation to storage systems of this type is the resistance to heat transfer of the solid phase, requiring a significant temperature drop for acceptable discharge rates. The additional “heat path” provided by the conducting container walls is shown to significantly reduce this resistance. Some observations concerning the implications for design of actual storage components are also provided.

scholarly journals Thermal Stability and Reliability Test of Some Saturated Fatty Acids for Low and Medium Temperature Thermal Energy Storage

Energies ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4509
Author(s):  
Abhishek Anand ◽  
Karunesh Kant ◽  
Amritanshu Shukla ◽  
Chang-Ren Chen ◽  
Atul Sharma
Keyword(s):  
Fatty Acids ◽  
Energy Storage ◽  
Latent Heat ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Saturated Fatty Acids ◽  
Heat Of Fusion ◽  
Gravimetric Analysis ◽  
Ternary Blends ◽  
Latent Heat Storage

Phase change materials have been overwhelmingly used for thermal energy storage applications. Among organics, fatty acids are an important constituent of latent heat storage. Most of the saturated fatty acid PCMs so far studied are either unary or binary constituents of pure fatty acids. In the present study, ternary blends of saturated fatty acids i.e., capric, lauric, myristic, stearic, and palmitic acids have been developed with different weight proportions. A series of 28 ternary blends viz. CA-LA-MA, CA-LA-PA, CA-LA-SA, CA-MA-PA, CA-MA-SA, and CA-PA-SA were prepared and analyzed with differential scanning calorimetry, thermal gravimetric analysis, and Fourier transform infrared spectroscopy. DSC analysis revealed that the prepared materials lie in the 15–30 °C temperature range. Also, 300 thermal melt/freeze cycles were conducted which showed ±10% variation in terms of the melting peak for most of the PCMs, with the average latent heat of fusion between 130 and 170 kJ/kg. The TGA analysis showed that most of the PCMs are thermally stable up to 100 °C and useful for medium-low storage applications, and FTIR analysis showed that the materials are chemically stable after repeated thermal cycles. Based on cycle test performances, the developed materials were found to be reliable for long-term use in building and photovoltaic applications.

Preperation and Characterization Study of Phase Change Materials for Thermal Energy Storage Applications

2015 ◽  
Vol 787 ◽  
pp. 77-81
Author(s):  
Pasam Bhagyalakshmi ◽  
K. Rajan ◽  
K. Senthil Kumar
Keyword(s):  
Energy Storage ◽  
Phase Change ◽  
Latent Heat ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Phase Change Materials ◽  
Eutectic Mixture ◽  
High Energy ◽  
Heat Of Fusion ◽  
Differential Scanning Calorimetric

Thermal Energy Storage using phase change materials (PCM) has become an interesting area of energy research because of its high energy storage density, isothermal nature of storage process and small volume changes. In the present work paraffin wax (PW) and Palmitic acids(PA) are chosen as phase change materials and mixed in different proportions(40-60% PW-PA, 50-50% PW-PA and 60-40% PW-PA) to prepare eutectic PCMs. And also paraffin is combined with Copper oxide nano powder to prepare composite PCM. Differential Scanning Calorimetric (DSC) Tests have been conducted to find the latent heat capacity of the above combination of PCMs. The results showed that 40-60%PW-PA eutectic mixture is effective in increasing the latent heat of fusion compared to the other combinations.

scholarly journals Latent Heat Phase Change Heat Transfer of a Nanoliquid with Nano–Encapsulated Phase Change Materials in a Wavy-Wall Enclosure with an Active Rotating Cylinder

2021 ◽  
Vol 13 (5) ◽  
pp. 2590
Author(s):  
S. A. M. Mehryan ◽  
Kaamran Raahemifar ◽  
Leila Sasani Gargari ◽  
Ahmad Hajjar ◽  
Mohamad El Kadri ◽  
...  
Keyword(s):  
Heat Transfer ◽  
Energy Storage ◽  
Phase Change ◽  
Latent Heat ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Wavy Wall ◽  
Governing Equations ◽  
Stefan Number ◽  
Change Material

A Nano-Encapsulated Phase-Change Material (NEPCM) suspension is made of nanoparticles containing a Phase Change Material in their core and dispersed in a fluid. These particles can contribute to thermal energy storage and heat transfer by their latent heat of phase change as moving with the host fluid. Thus, such novel nanoliquids are promising for applications in waste heat recovery and thermal energy storage systems. In the present research, the mixed convection of NEPCM suspensions was addressed in a wavy wall cavity containing a rotating solid cylinder. As the nanoparticles move with the liquid, they undergo a phase change and transfer the latent heat. The phase change of nanoparticles was considered as temperature-dependent heat capacity. The governing equations of mass, momentum, and energy conservation were presented as partial differential equations. Then, the governing equations were converted to a non-dimensional form to generalize the solution, and solved by the finite element method. The influence of control parameters such as volume concentration of nanoparticles, fusion temperature of nanoparticles, Stefan number, wall undulations number, and as well as the cylinder size, angular rotation, and thermal conductivities was addressed on the heat transfer in the enclosure. The wall undulation number induces a remarkable change in the Nusselt number. There are optimum fusion temperatures for nanoparticles, which could maximize the heat transfer rate. The increase of the latent heat of nanoparticles (a decline of Stefan number) boosts the heat transfer advantage of employing the phase change particles.

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