scholarly journals [NiFe]-(Oxy)Sulfides Derived from NiFe2O4 for the Alkaline Hydrogen Evolution Reaction

Energies ◽  
2022 ◽  
Vol 15 (2) ◽  
pp. 543
Author(s):  
David Tetzlaff ◽  
Vasanth Alagarasan ◽  
Christopher Simon ◽  
Daniel Siegmund ◽  
Kai junge Puring ◽  
...  

The development of noble-metal-free electrocatalysts is regarded as a key factor for realizing industrial-scale hydrogen production powered by renewable energy sources. Inspired by nature, which uses Fe- and Ni-containing enzymes for efficient hydrogen generation, Fe/Ni-containing chalcogenides, such as oxides and sulfides, received increasing attention as promising electrocatalysts to produce hydrogen. We herein present a novel synthetic procedure for mixed Fe/Ni (oxy)sulfide materials by the controlled (partial) sulfidation of NiFe2O4 (NFO) nanoparticles in H2S-containing atmospheres. The variation in H2S concentration and the temperature allows for a precise control of stoichiometry and phase composition. The obtained sulfidized materials (NFS) catalyze the hydrogen evolution reaction (HER) with increased activity in comparison to NFO, up to −10 and −100 mA cm−2 at an overpotential of approx. 250 and 450 mV, respectively.

RSC Advances ◽  
2018 ◽  
Vol 8 (36) ◽  
pp. 20341-20346 ◽  
Author(s):  
Renuka V. Digraskar ◽  
Vijay S. Sapner ◽  
Shankar S. Narwade ◽  
Shivsharan M. Mali ◽  
Anil V. Ghule ◽  
...  

A novel noble metal-free Co-doped CZTS-based nano-electrocatalyst fabricated by employing a sonochemical method for the enhanced hydrogen evolution reaction (HER) and it shows a superior HER performance and exhibits excellent current stability.


2021 ◽  
Author(s):  
Siyao Wang ◽  
Dongxu Jiao ◽  
Jingwei Liu ◽  
Jing-Xiang Zhao ◽  
Yongchen Shang

Searching for stable, efficient, and inexpensive metal-free electrocatalysts for hydrogen evolution reaction (HER) is crucial for sustainable hydrogen generation. Herein, by means of density functional theory (DFT) computations, we proposed...


2019 ◽  
Vol 3 (9) ◽  
pp. 2205-2210 ◽  
Author(s):  
Chien-Hong Chen ◽  
Tzung-Wen Chiou ◽  
Han-Chun Chang ◽  
Wei-Liang Li ◽  
Chi-Yen Tung ◽  
...  

In electrocatalytic water splitting, active, stable and low-cost hydrogen evolution electrocatalysts play key roles in the conversion and storage of renewable energy sources.


Author(s):  
Lana Regent ◽  
Maximina Luis-Sunga ◽  
Elena Pastor ◽  
Gonzalo García

Developing sustainable and renewable energy sources is critical as higher and higher global energy and environmental challenges arise. Hydrogen has the highest mass/energy density of any fuel and is considered one of the best sources of clean energy. Water splitting is regarded as one of the most promising solutions for hydrogen production on a large scale. Highly efficient, durable and cost-effective catalysts for hydrogen evolution reaction (HER) are critical in the realization of this goal. Among many materials proposed, graphene-based materials offer some unique properties for HER catalysis. In this review, we present recent progress on development of graphene-based electrocatalysts toward HER throughout the past few years.


2021 ◽  
Vol 13 (13) ◽  
pp. 7025
Author(s):  
Shiva Gorjian ◽  
Behnam Hosseingholilou ◽  
Laxmikant D. Jathar ◽  
Haniyeh Samadi ◽  
Samiran Samanta ◽  
...  

The food industry is responsible for supplying the food demand of the ever-increasing global population. The food chain is one of the major contributors to greenhouse gas (GHG) emissions, and global food waste accounts for one-third of produced food. A solution to this problem is preserving crops, vegetables, and fruits with the help of an ancient method of sun drying. For drying agricultural and marine products, several types of dryers are also being developed. However, they require a large amount of energy supplied conventionally from pollutant energy sources. The environmental concerns and depletion risks of fossil fuels persuade researchers and developers to seek alternative solutions. To perform drying applications, sustainable solar power may be effective because it is highly accessible in most regions of the world. Greenhouse dryers (GHDs) are simple facilities that can provide large capacities for drying agricultural products. This study reviews the integration of GHDs with different solar technologies, including photovoltaic (PV), photovoltaic-thermal (PVT), and solar thermal collectors. Additionally, the integration of solar-assisted greenhouse dryers (SGHDs) with heat pumps and thermal energy storage (TES) units, as well as their hybrid configuration considering integration with other renewable energy sources, is investigated to improve their thermal performance. In this regard, this review presents and discusses the most recent advances in this field. Additionally, the economic analysis of SGHDs is presented as a key factor to make these sustainable facilities commercially available.


2021 ◽  
Vol 372 ◽  
pp. 137859
Author(s):  
Leyla Gidi ◽  
Roxana Arce ◽  
José Ibarra ◽  
M. Isaacs ◽  
M.J. Aguirre ◽  
...  

2017 ◽  
Vol 5 (43) ◽  
pp. 22805-22812 ◽  
Author(s):  
Cuncai Lv ◽  
Zhipeng Huang ◽  
Qianpeng Yang ◽  
Guangfeng Wei ◽  
Zuofeng Chen ◽  
...  

A facile and ultrafast synthesis of molybdenum carbide coated with few-layer carbon (MoC/C) has been developed, and the effect of reducing the thickness of the carbon coating on its catalytic activity in the hydrogen evolution reaction (HER) has been demonstrated.


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