scholarly journals Thermophysical Properties of Nanofluids Composed of Ethylene Glycol and Long Multi-Walled Carbon Nanotubes

Fluids ◽  
2020 ◽  
Vol 5 (4) ◽  
pp. 241
Author(s):  
Karolina Brzóska ◽  
Bertrand Jóźwiak ◽  
Adrian Golba ◽  
Marzena Dzida ◽  
Sławomir Boncel
Keyword(s):  
Thermal Conductivity ◽  
Carbon Nanotubes ◽  
Ethylene Glycol ◽  
Chemical Vapor ◽  
Step Method ◽  
Mwcnt Content ◽  
Multi Walled Carbon Nanotubes ◽  
The Stability ◽  
Walled Carbon Nanotubes ◽  
Rotary Viscometer

In this work, thermal conductivity, viscosity, isobaric heat capacity, and density of stable carbon-based nanofluids are presented. The nanofluids under study are composed of 1,2-ethanediol (ethylene glycol, EG) and long multi-walled carbon nanotubes (MWCNTs), so-called ‘in-house 16h’ (synthesized in our laboratory via catalytic chemical vapor deposition during 16 h with a diameter of 60–80 nm and length of 770 μm). Poly(N-vinylpyrrolidone) (PVP) was used to increase the stability of nanofluids. The nanofluids were prepared via an ultrasonication-assisted, three-step method while their key thermophysical characteristics were obtained using the hot-wire technique and rotary viscometer. As a result, the addition of MWCNTs significantly improved the thermal conductivity of nanofluids by 31.5% for the highest 1.0 wt% (0.498 vol%) long MWCNT content, leaving the Newtonian character of the nanofluids practically intact.

Thermal Conductivity Measurement for Carbon-Nanotube Suspensions with 3ω Method

2009 ◽  
Vol 60-61 ◽  
pp. 394-398 ◽  
Author(s):  
Gen Sheng Wu ◽  
Jue Kuan Yang ◽  
Shu Lin Ge ◽  
Yu Juan Wang ◽  
Min Hua Chen ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Carbon Nanotubes ◽  
Volume Fraction ◽  
Aqueous Suspension ◽  
Conductivity Measurement ◽  
3Ω Method ◽  
Conductivity Enhancement ◽  
Multi Walled Carbon Nanotubes ◽  
The Stability ◽  
Walled Carbon Nanotubes

The stable and homogeneneous aqueous suspension of carbon nanotubes was prepared in this study. The stability of the nanofluids was improved greatly due to the use of a new dispersant, humic acid. The thermal conductivity of the aqueous suspension was measured with the 3ω method. The experimental results showed that the thermal conductivity of the suspensions increases with the temperature and also is nearly proportional to the loading of the nanoparticles. The thermal conductivity enhancement of single-walled carbon nanotubes (SWNTs) suspensions is better than that of the multi-walled carbon nanotubes (MWNTs) suspensions. Especially for a volume fraction of 0.3846% SWNTs, the thermal conductivity is enhanced by 40.5%. Furthermore, the results at 30°C match well with Jang and Choi’s model.

scholarly journals Thermophysical Properties of IoNanofluids Composed of 1-ethyl-3-methylimidazolium Thiocyanate and Carboxyl-functionalized Long Multi-walled Carbon Nanotubes

Fluids ◽  
2020 ◽  
Vol 5 (4) ◽  
pp. 214
Author(s):  
Bertrand Jóźwiak ◽  
Justyna Dziadosz ◽  
Adrian Golba ◽  
Krzysztof Cwynar ◽  
Grzegorz Dzido ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Carbon Nanotubes ◽  
Carboxylic Group ◽  
Conductivity Enhancement ◽  
Multi Walled Carbon Nanotubes ◽  
Vibrating Tube Densimeter ◽  
Carbon Based Nanomaterials ◽  
Walled Carbon Nanotubes ◽  
Rotary Viscometer

The concept of IoNanofluids (INFs) as the stable dispersions of nanoparticles in ionic liquids was proposed in 2009 by Nieto de Castro’s group. INFs characterize exciting properties such as improved thermal conductivity, non-volatility, and non-flammability. This work is a continuation of our studies on the morphology and physicochemistry of carbon-based nanomaterials affecting thermal conductivity, viscosity, and density of INFs. We focus on the characterization of dispersions composed of long carboxylic group-functionalized multi-walled carbon nanotubes and 1-ethyl-3-methylimidazolium thiocyanate. The thermal conductivity of INFs was measured using KD2 Pro Thermal Properties Analyzer (Decagon Devices Inc., Pullman, WA, USA). The viscosity was investigated using rotary viscometer LV DV-II+Pro (Brookfield Engineering, Middleboro, MA, USA). The density of INFs was measured using a vibrating tube densimeter Anton Paar DMA 5000 (Graz, Austria). The maximum thermal conductivity enhancement of 22% was observed for INF composed of 1 wt% long carboxylic group-functionalized multi-walled carbon nanotubes.

Green Synthesis of Poly(ethylene Glycol) Modified Multi-Walled Carbon Nanotubes and their Dispersibility

2013 ◽  
Vol 320 ◽  
pp. 456-459
Author(s):  
Jin Gang Yu ◽  
Xin Yu Jiang ◽  
Xiao Qing Chen ◽  
Fei Peng Jiao ◽  
Zhi Guang Peng ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Ethylene Glycol ◽  
Green Synthesis ◽  
Ethanol Solution ◽  
Poly Ethylene Glycol ◽  
Reduced Pressure ◽  
Multi Walled Carbon Nanotubes ◽  
Poly Ethylene ◽  
The Stability ◽  
Walled Carbon Nanotubes

Poly (ethylene glycol) modified multi-walled carbon nanotubes were prepared by a green synthesis procedure, including oxidation, acyl chlorination and alcoholysis. All the liquid reagents were recycled by distillation or reduced pressure distillation, and complicated washing or purification was simplified. Fourier transform infrared spectroscopy, scanning electron microscopy and thermogravimetric analysis were used to characterize the samples. The results indicated that PEG was grafted to the functionalized carbon nanotubes (f-CNTs) and the mass percentage of the grafted PEG was about 12%. After sonicatingf-CNTs in ethanol, the dispersibility off-CNTs in ethanol was about 0.46 mg/mL. The stability off-CNTs in ethanol was also tested by left standing a 0.4 mg/mLf-CNT/ethanol solution, no precipitation was found after 10 days.

scholarly journals Stability and Thermo-Physical Properties of Ethylene Glycol Based Nanofluids for Solar Thermal Applications

2021 ◽  
Vol 39 (1) ◽  
pp. 137-144
Author(s):  
Raviteja Surakasi ◽  
Jaikumar Sagari ◽  
Krishna Bharath Vinjamuri ◽  
Bhanuteja Sanduru ◽  
Srinivas Vadapalli
Keyword(s):  
Thermal Conductivity ◽  
Carbon Nanotubes ◽  
Ethylene Glycol ◽  
Physical Properties ◽  
Dynamic Viscosity ◽  
Temperature Range ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes ◽  
Thermo Physical Properties ◽  
Surfactant Assisted

This article summarizes research involving the evaluation of the thermo-physical properties of ethylene- glycol-based solar thermic fluids oxidized multi-walled carbon nanotubes. Nanofluids were prepared with Ethylene glycol and water as base fluids in 100:0, 90:10 and 80:20 ratios. Base fluids of three categories were dispersed with surfactant-assisted multi-walled carbon nanotubes (MWCNTs) and oxidized MWCNTs in the weight fractions of 0.125, 0.25, and 0.5 percentages to check the influence of surface modification technique on the thermophysical properties. The variation in zeta potential is studied to examine the dispersion stability during 2 months. Thermal conductivity and dynamic viscosity were measured by hot disk method and Anton paar viscometer, respectively. Significant enhancement of thermal conductivity by 15 to 24 % was observed when the base fluids are dispersed with oxidized MWCNTs. In the case of nanofluids dispersed with surfactant-assisted MWCNTs, the improvement is significantly less compared to oxidized MWCNTs. Nanofluids' dynamic viscosity is found to be higher compared to base fluids in the temperature range of 50 to 70 oC. A comprehensive mathematical equation suitable for all weight fraction of MWCNTs and volume percentages of Ethylene glycol was developed, which can forecast the temperature range. The correlation could fit well with the experimental data in reasonable limits.

scholarly journals Stabilizing effect of methylcellulose on the dispersion of multi-walled carbon nanotubes in cementitious composites

2020 ◽  
Vol 9 (1) ◽  
pp. 93-104
Author(s):  
Mingrui Du ◽  
Yuan Gao ◽  
Guansheng Han ◽  
Luan Li ◽  
Hongwen Jing
Keyword(s):  
Carbon Nanotubes ◽  
Pore Solution ◽  
Cementitious Materials ◽  
High Ionic Strength ◽  
Cementitious Composites ◽  
Uniform Distributions ◽  
Stabilizing Effect ◽  
Multi Walled Carbon Nanotubes ◽  
The Stability ◽  
Walled Carbon Nanotubes

AbstractMulti-walled carbon nanotubes (MWCNTs) have been added in the plain cementitious materials to manufacture composites with the higher mechanical properties and smart behavior. The uniform distributions of MWCNTs is critical to obtain the desired enhancing effect, which, however, is challenged by the high ionic strength of the cement pore solution. Here, the effects of methylcellulose (MC) on stabilizing the dispersion of MWCNTs in the simulated cement pore solution and the viscosity of MWCNT suspensions werestudied. Further observations on the distributions of MWCNTs in the ternary cementitious composites were conducted. The results showed that MC forms a membranous envelope surrounding MWCNTs, which inhibits the adsorption of cations and maintains the steric repulsion between MWCNTs; thus, the stability of MWCNT dispersion in cement-based composites is improved. MC can also work as a viscosity adjuster that retards the Brownian mobility of MWCNTs, reducing their re-agglomerate within a period. MC with an addition ratio of 0.018 wt.% is suggested to achieve the optimum dispersion stabilizing effect. The findings here provide a way for stabilizing the other dispersed nano-additives in the cementitious composites.

Two-step synthesis of polyurethane/multi-walled carbon nanotubes polymer composite to achieve high percentage particle reinforcement for mechanical applications

2021 ◽  
pp. 002199832199945
Author(s):  
Dinesh Kumar ◽  
Suneev Anil Bansal ◽  
Navin Kumar ◽  
Prashant Jindal
Keyword(s):  
Carbon Nanotubes ◽  
Synthesis Method ◽  
Step Method ◽  
Molding Method ◽  
Uniform Dispersion ◽  
Noticeable Improvement ◽  
Multi Walled Carbon Nanotubes ◽  
Mixing Method ◽  
Compressive Testing ◽  
Walled Carbon Nanotubes

The present work has been aimed to synthesize Polyurethane (PU)/Multi-Walled Carbon Nanotubes (MWCNTs) composite using a two-step method to enhance mechanical properties. In the first step, films (0.2 mm thickness) have been synthesized using a solution mixing method to disperse MWCNTs in the PU matrix. In the second step, thin films of uniformly dispersed MWCNTs in the PU matrix have been compression molded to synthesize PU/MWCNTs composite required for real mechanical applications. The two-step method has the advantages of solution mixing as well as compression molding method. The results of quasi-static nanoindentation tests indicated that in comparison to pure PU, elastic modulus and hardness have been enhanced by 124% and 53% respectively for 10 wt% PU/MWCNTs composite. Fracture resistance of PU/MWCNTs composites, with 7 wt% of MWCNTs, has been enhanced by 52% as compared to pure PU. To understand bulk behavior, nanoindentation results have been cross-verified with compression testing. Results of compressive testing shown that the modulus of composite material has been significantly improved under the influence of the increasing composition of MWCNTs. A noticeable improvement of 52% has been observed in compressive modulus of 10 wt% composite in equivalence to pure PU. The overall improvement in mechanical behavior has been attributed to the uniform dispersion of MWCNTs in the PU matrix by the two-step synthesis method.

Sign in / Sign up

Export Citation Format

Share Document