scholarly journals Optimizing Precursors and Reagents for the Development of Alkali-Activated Binders in Ambient Curing Conditions

2021 ◽  
Vol 5 (2) ◽  
pp. 59
Author(s):  
Dhruv Sood ◽  
Khandaker M. Anwar Hossain

Alkali-activated binders (AABs) are developed through the activation of aluminosilicate-rich materials using alkaline reagents. The characteristics of AABs developed using a novel dry-mixing technique incorporating powder-based reagents/activators are extensively explored. A total of forty-four binder mixes are assessed in terms of their fresh and hardened state properties. The influence of mono/binary/ternary combinations of supplementary cementitious materials (SCMs)/precursors and different types/combinations/dosages of powder-based reagents on the strength and workability properties of different binder mixes are assessed to determine the optimum composition of precursors and the reagents. The binary (55% fly ash class C and 45% ground granulated blast furnace slag) and ternary (25% fly ash class C, 35% fly ash class F and 40% ground granulated blast furnace slag) binders with reagent-2 (calcium hydroxide and sodium sulfate = 2.5:1) exhibited desired workability and 28-day compressive strengths of 56 and 52 MPa, respectively. Microstructural analyses (in terms of SEM/EDS and XRD) revealed the formation of additional calcium aluminosilicate hydrate with sodium or mixed Ca/Na compounds in binary and ternary binders incorporating reagent-2, resulting in higher compressive strength. This research confirms the potential of producing powder-based cement-free green AABs incorporating binary/ternary combinations of SCMs having the desired fresh and hardened state properties under ambient curing conditions.

2018 ◽  
Vol 20 (2) ◽  
pp. 208-215

The paper presents a laboratory study of concrete mixes based on the alkali-activation of an industrial by-product, ground granulated blast furnace slag (GGBS). A number of factors potentially affecting the resulting concrete quality in terms of workability and strengths were investigated (namely activator type, molarity, curing conditions and times). The statistical significance of the effect of these factors was supported by ANOVA. Higher workability and strengths (with lower activator concentrations) were obtained for KOH containing mixes. Curing at constant moisture and ambient temperature was successful for most alkaline activators and mixes, which showed good concrete strengths at all curing times; when Na2SiO3 was used in addition to NaOH or KOH activators of moderate to high molarity, strengths exceeded those of Ordinary Portland Cement (CEM-I) concrete of a similar water/cement ratio.


2011 ◽  
Vol 287-290 ◽  
pp. 916-921
Author(s):  
Kyung Taek Koh ◽  
Gum Sung Ryu ◽  
Si Hwan Kim ◽  
Jang Hwa Lee

This paper examines the effects of the mixture ratio of fly ash/slag, the type of alkaline activators and curing conditions on the workability, compressive strength and microstructure of cementless alkali-activated mortar. The investigation showed that the mixture ratio of fly ash/slag and the type of alkaline activator have significant influence on the workability and strength, whereas the curing temperature has relatively poor effect. An alkali-activated mortar using a binder composed of 50% of fly ash and 50% of granulated blast furnace slag and alkaline activator made of 9M NaOH and sodium silicate in proportion of 1:1 is seen to be able to develop a compressive strength of 65 MPa at age of 28 days even when cured at ambient temperature of 20°C.


Kilat ◽  
2021 ◽  
Vol 10 (1) ◽  
pp. 101-107
Author(s):  
Muhammad Sofyan

Mortar salah satu material yang memiliki manfaat yang beraneka ragam dalam konstruksi bangunan.  Sejauh ini, mortar konvensional digunakan sebagai bahan plester atau coating pada bangunan. Bahan pengikat utama mortar pada dasarnya masih mengandalkan semen. Pemanfaatan Batu bara pada pembangkit listrik tenaga uap masih menjadi salah satu arus utama sebagai pendukung kebutuhan energi listrik. Penumpukan hasil sisa pembakaran batu bara seperti fly ash dan bottom ash berpotensi mengganggu stabilitas Ekosistem lingkungan. Alkali-Activated mortar dengan mengandalkan larutan alkali activator yang direaksikan dengan material pozzolanic seperti fly ash, Ground Granulated Blast Furnace Slag (GGBFS), Palm Oil Fuel Ash (POFA)ldan lain-lain dapat menjadi salah satu solusi dalam mengurangi limbah fly-ash yang menumpuk. Dalam beberapa riset riset terdahulu idealnya kontrol mutu dari Alkali Activated mortar dapat ditinjiau pada kekuatan mekanisnya seperti kuat tekan dan lentur Dalam artikel ini akan ditinjau bagaimana kekuatan mekanis pada beberapa jenis Alkali-Activated Mortar. Dari studi-studi yang akan dibahas tersebut akan ditarik sebuah kesimpulan berdasarkan data-data pengujian mekanis yan pada akhirnya dapat memberi rekomendasi tentang bagaimana performa mekanis pada Alkali-Activated mortar.


Materials ◽  
2022 ◽  
Vol 15 (1) ◽  
pp. 375
Author(s):  
Syafiadi Rizki Abdila ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
Romisuhani Ahmad ◽  
Dumitru Doru Burduhos Nergis ◽  
Shayfull Zamree Abd Rahim ◽  
...  

Geopolymers, or also known as alkali-activated binders, have recently emerged as a viable alternative to conventional binders (cement) for soil stabilization. Geopolymers employ alkaline activation of industrial waste to create cementitious products inside treated soils, increasing the clayey soils’ mechanical and physical qualities. This paper aims to review the utilization of fly ash and ground granulated blast furnace slag (GGBFS)-based geopolymers for soil stabilization by enhancing strength. Previous research only used one type of precursor: fly ash or GGBFS, but the strength value obtained did not meet the ASTM D 4609 (<0.8 Mpa) standard required for soil-stabilizing criteria of road construction applications. This current research focused on the combination of two types of precursors, which are fly ash and GGBFS. The findings of an unconfined compressive strength (UCS) test on stabilized soil samples were discussed. Finally, the paper concludes that GGBFS and fly-ash-based geo-polymers for soil stabilization techniques can be successfully used as a binder for soil stabilization. However, additional research is required to meet the requirement of ASTM D 4609 standard in road construction applications, particularly in subgrade layers.


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