scholarly journals Study of Superbase-Based Deep Eutectic Solvents as the Catalyst in the Chemical Fixation of CO2 into Cyclic Carbonates under Mild Conditions

Materials ◽  
2017 ◽  
Vol 10 (7) ◽  
pp. 759 ◽  
Author(s):  
Sara García-Argüelles ◽  
Maria Ferrer ◽  
Marta Iglesias ◽  
Francisco Del Monte ◽  
María Gutiérrez
Keyword(s):  
Deep Eutectic Solvents ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Mild Conditions

Anion-induced 3d–4f luminescent coordination clusters: structural characteristics and chemical fixation of CO2 under mild conditions

2018 ◽  
Vol 47 (21) ◽  
pp. 7159-7165 ◽  
Author(s):  
Ruilian Zhang ◽  
Li Wang ◽  
Cong Xu ◽  
Huan Yang ◽  
Wanmin Chen ◽  
...  
Keyword(s):  
Structural Characteristics ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Mild Conditions

Anion-induced clusters with luminescence exhibit excellent catalysis to transform CO2 into cyclic carbonates under mild conditions.

An imidazolium-functionalized mesoporous cationic metal–organic framework for cooperative CO2 fixation into cyclic carbonate

2018 ◽  
Vol 54 (4) ◽  
pp. 342-345 ◽  
Author(s):  
Jun Liang ◽  
Ya-Qiang Xie ◽  
Xu-Sheng Wang ◽  
Qiang Wang ◽  
Tao-Tao Liu ◽  
...  
Keyword(s):  
Co2 Fixation ◽  
Metal Organic Framework ◽  
Cyclic Carbonate ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Co Catalyst ◽  
Mild Conditions ◽  
Catalyst Free ◽  
Metal Organic ◽  
Organic Framework

A mesoporous cationic Cr-based metal–organic framework (MOF), FJI-C10, has been obtained and exhibited excellent performances in chemical fixation of CO2 into cyclic carbonates under co-catalyst free and mild conditions.

An efficient metal- and solvent-free organocatalytic system for chemical fixation of CO2 into cyclic carbonates under mild conditions

2016 ◽  
Vol 18 (5) ◽  
pp. 1229-1233 ◽  
Author(s):  
Lin Wang ◽  
Guangyou Zhang ◽  
Koichi Kodama ◽  
Takuji Hirose
Keyword(s):  
Significant Loss ◽  
Solvent Free ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Mild Conditions

An efficient organocatalytic system was developed for the synthesis of cyclic carbonates from epoxides and CO2 (25–45 °C, 1 atm) in high-to-excellent yields (85–97%). Moreover, the 2,6-pyridinedimethanol system could be recycled several times without significant loss of activity.

Construction of 3D lanthanide based MOFs with pores decorated with basic imidazole groups for selective capture and chemical fixation of CO2

2020 ◽  
Vol 44 (21) ◽  
pp. 9090-9096
Author(s):  
Sandeep Singh Dhankhar ◽  
C. M. Nagaraja
Keyword(s):  
Value Added ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Mild Conditions ◽  
Rational Construction

Rational construction of three new 3D lanthanide-based MOFs exhibiting selective CO2 capture and conversion to value-added cyclic carbonates under mild conditions is reported.

Metal β-diketonate complexes as highly efficient catalysts for chemical fixation of CO2 into cyclic carbonates under mild conditions

2019 ◽  
Vol 48 (42) ◽  
pp. 15970-15976 ◽  
Author(s):  
Hongmei Wang ◽  
Zulei Zhang ◽  
Hailong Wang ◽  
Liping Guo ◽  
Lei Li
Keyword(s):  
Room Temperature ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Mild Conditions ◽  
Highly Efficient

Metal β-diketonate complexes could efficiently catalyze the chemical fixation of CO2 at 1 atm and near room temperature.

Dual-ionic liquid system: an efficient catalyst for chemical fixation of CO2 to cyclic carbonates under mild conditions

2018 ◽  
Vol 20 (13) ◽  
pp. 2990-2994 ◽  
Author(s):  
Jiayin Hu ◽  
Jun Ma ◽  
Huizhen Liu ◽  
Qingli Qian ◽  
Chao Xie ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Liquid System ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Efficient Catalyst ◽  
Mild Conditions

An easily prepared novel dual-ionic liquid system can catalyze the reactions of CO2 and epoxides to form cyclic carbonates under mild conditions (1 atmos CO2, T = 30–60 °C) with excellent yields in the absence of any solvents or additives.

scholarly journals Design of bifunctional quaternary phosphonium salt catalysts for CO2 fixation reaction with epoxides under mild conditions

2016 ◽  
Vol 18 (17) ◽  
pp. 4611-4615 ◽  
Author(s):  
Shiyao Liu ◽  
Naoki Suematsu ◽  
Keiji Maruoka ◽  
Seiji Shirakawa
Keyword(s):  
Co2 Fixation ◽  
Phosphonium Salt ◽  
Cyclic Carbonates ◽  
Efficient Synthesis ◽  
Reaction Conditions ◽  
Mild Conditions ◽  
Phosphonium Iodide ◽  
Fixation Reaction ◽  
Quaternary Phosphonium Salt

An efficient synthesis of cyclic carbonates from epoxides and CO2 under mild reaction conditions was achieved via the use of a designed bifunctional quaternary phosphonium iodide catalyst.

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