scholarly journals Expanded Graphite/Paraffin/Silicone Rubber as High Temperature Form-stabilized Phase Change Materials for Thermal Energy Storage and Thermal Interface Materials

Materials ◽  
2020 ◽  
Vol 13 (4) ◽  
pp. 894 ◽  
Author(s):  
Yafang Zhang ◽  
Wang Li ◽  
Juhua Huang ◽  
Ming Cao ◽  
Guoping Du

In this work, expanded graphite/paraffin/silicone rubber composite phase-change materials (PCMs) were prepared by blending the expanded graphite (EG), paraffin wax (PW) and silicone rubber (SR) matrix. It has been shown that PW fully penetrates into the three dimensional (3D) pores of EG to form the EG/PW particles, which are sealed by SR and evenly embedded in the SR matrix. As a result of the excellent thermal stability of SR and the capillary force from the 3D pores of EG, the EG/PW/SR PCMs are found to have good shape stability and high reliability. After being baked in an oven at 150 °C for 24 h, the shape of the EG/PW/SR PCMs is virtually unchanged, and their weight loss and latent heat drop are only 7.91 wt % and 11.3 J/g, respectively. The latent heat of the EG/PW/SR composites can reach up to 43.6 and 41.8 J/g for the melting and crystallizing processes, respectively. The super cooling of PW decreased from 4.2 to 2.4 due to the heterogeneous nucleation on the large surface of EG and the sealing effect of the SR. Meanwhile, the thermal conductivity of the EG/PW/SR PCMs reaches 0.56 W·m−1·K−1, which is about 2.8 times and 3.73 times of pure PW and pristine SR, respectively. The novel EG/PW/SR PCMs with superior shape and thermal stabilities will have a potential application in heat energy storage and thermal interface materials (TIM) for electronic devices.

Energies ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3821
Author(s):  
Kassianne Tofani ◽  
Saeed Tiari

Latent heat thermal energy storage systems (LHTES) are useful for solar energy storage and many other applications, but there is an issue with phase change materials (PCMs) having low thermal conductivity. This can be enhanced with fins, metal foam, heat pipes, multiple PCMs, and nanoparticles (NPs). This paper reviews nano-enhanced PCM (NePCM) alone and with additional enhancements. Low, middle, and high temperature PCM are classified, and the achievements and limitations of works are assessed. The review is categorized based upon enhancements: solely NPs, NPs and fins, NPs and heat pipes, NPs with highly conductive porous materials, NPs and multiple PCMs, and nano-encapsulated PCMs. Both experimental and numerical methods are considered, focusing on how well NPs enhanced the system. Generally, NPs have been proven to enhance PCM, with some types more effective than others. Middle and high temperatures are lacking compared to low temperature, as well as combined enhancement studies. Al2O3, copper, and carbon are some of the most studied NP materials, and paraffin PCM is the most common by far. Some studies found NPs to be insignificant in comparison to other enhancements, but many others found them to be beneficial. This article also suggests future work for NePCM and LHTES systems.


Energies ◽  
2021 ◽  
Vol 14 (19) ◽  
pp. 6176 ◽  
Author(s):  
Hamidreza Behi ◽  
Mohammadreza Behi ◽  
Ali Ghanbarpour ◽  
Danial Karimi ◽  
Aryan Azad ◽  
...  

Usage of phase change materials’ (PCMs) latent heat has been investigated as a promising method for thermal energy storage applications. However, one of the most common disadvantages of using latent heat thermal energy storage (LHTES) is the low thermal conductivity of PCMs. This issue affects the rate of energy storage (charging/discharging) in PCMs. Many researchers have proposed different methods to cope with this problem in thermal energy storage. In this paper, a tubular heat pipe as a super heat conductor to increase the charging/discharging rate was investigated. The temperature of PCM, liquid fraction observations, and charging and discharging rates are reported. Heat pipe effectiveness was defined and used to quantify the relative performance of heat pipe-assisted PCM storage systems. Both experimental and numerical investigations were performed to determine the efficiency of the system in thermal storage enhancement. The proposed system in the charging/discharging process significantly improved the energy transfer between a water bath and the PCM in the working temperature range of 50 °C to 70 °C.


2020 ◽  
Vol 24 (5 Part B) ◽  
pp. 3185-3193
Author(s):  
Sina Dang ◽  
Hongjun Xue ◽  
Xiaoyan Zhang ◽  
Chengwen Zhong

To strengthen the heat and mass transfer capacity and improve the temperature regulation rate, potential storage is taken as the research object in this research to study the heat energy storage of the battery in the low temperature environment. Lattice Boltzmann method is adopted to study the heat energy storage influence mechanism of the temperature regulation system of the low temperature phase-change materials. In addition, the influence of different physical parameters (thermal conductivity and latent heat of phase change) on the thermal insulation of the system in the process of temperature control is revealed. The results show that the mechanism of heat and mass transfer in the process of heat storage and temperature control is related to the different physical properties of phase change materials. The decrease of thermal conductivity and the increase of latent heat of phase change materials will greatly increase the effect of heat energy storage. Therefore, under the action of phase change latent heat, phase change material can effectively extend the holding time of the battery in the low temperature environment.


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