scholarly journals NBT-Pluronic F-127 Hydrogels Printed on Flat Textiles as UV Radiation Sensors

Materials ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3435
Author(s):  
Elżbieta Sąsiadek ◽  
Malwina Jaszczak ◽  
Joanna Skwarek ◽  
Marek Kozicki

This work reports on the surface-modified woven fabrics for use as UV radiation sensors. The cotton and polyamide fabrics were printed with radiochromic hydrogels using a screen-printing method. The hydrogels used as a printing paste were composed of water, poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) (Pluronic F-127) as a gel matrix and nitro blue tetrazolium chloride as a radiation-sensitive compound. The development of the hydrogels’ colour occurs after exposure to UV radiation and its intensity increases with increasing absorbed dose. The features of the NBT-Pluronic F-127 radiochromic hydrogels and the fabrics printed with the hydrogels were examined using UV-Vis and reflectance spectrophotometry as well as scanning electron microscopy (SEM). The effects of NBT concentration and UV radiation type (UVA, UVB, UVC) on dose responses of the hydrogels and printed fabrics were also examined. The results obtained reveal that the fabrics printed with NBT-Pluronic F-127 hydrogels can be potentially useful as UV radiation sensors.

2011 ◽  
Vol 413 ◽  
pp. 148-153 ◽  
Author(s):  
Xue Na Hu ◽  
Ya Han ◽  
Jia Yan Li ◽  
Jun Yan Wu ◽  
Jian Rong Chen ◽  
...  

Thiol-functionalized MCM-48 (SH-MCM-48) was synthesized by co-condensation method, with co-templates of cetyltrimethylammonium bromide (CTAB) and nonionic poly (ethylene oxide)–poly (propylene oxide)–poly (ethylene oxide) triblock copolymer (Pluronic P123). The resulting material was characterized by XRD and FT-IR spectrum. The potential of SH-MCM-48 for adsorption Zn (II) from aqueous solution was examined. Batch adsorption studies were carried out to investigate the effect of experimental parameters including pH, metal ions concentration and adsorption time. The maximum adsorption capacities of Zn (II) onto SH-MCM-48 were 30.12, 34.01 and 38.02 mg g-1 at the temperature of 303, 313 and 323K, respectively. The adsorption kinetics data were found to follow the pseudo-second-order kinetic model, and adsorption isotherms were fitted well with Langmuir and Freundlich models. Moreover, the adsorption thermodynamic parameters (△G0, △H0 and △S0) were measured, and indicated that the adsorption was an exothermic and spontaneous process.


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