scholarly journals Direct One-Step Growth of Bimetallic Ni2Mo3N on Ni Foam as an Efficient Oxygen Evolution Electrocatalyst

Materials ◽  
2021 ◽  
Vol 14 (16) ◽  
pp. 4768
Author(s):  
Sang Heon Park ◽  
Soon Hyung Kang ◽  
Duck Hyun Youn

A simple and economical synthetic route for direct one-step growth of bimetallic Ni2Mo3N nanoparticles on Ni foam substrate (Ni2Mo3N/NF) and its catalytic performance during an oxygen evolution reaction (OER) are reported. The Ni2Mo3N/NF catalyst was obtained by annealing a mixture of a Mo precursor, Ni foam, and urea at 600 °C under N2 flow using one-pot synthesis. Moreover, the Ni2Mo3N/NF exhibited high OER activity with low overpotential values (336.38 mV at 50 mA cm−2 and 392.49 mV at 100 mA cm−2) and good stability for 5 h in Fe-purified alkaline electrolyte. The Ni2Mo3N nanoparticle surfaces converted into amorphous surface oxide species during the OER, which might be attributed to the OER activity.

2019 ◽  
Vol 55 (29) ◽  
pp. 4218-4221 ◽  
Author(s):  
Lingxi Zhou ◽  
Meichen Guo ◽  
Yao Li ◽  
Qin Gu ◽  
Wenqian Zhang ◽  
...  

A series of wire-in-plate nanostructured electrocatalysts for OER with high catalytic activity were fabricated.


Author(s):  
Junyeong Kim ◽  
Jun Neoung Heo ◽  
Jeong Yeon Do ◽  
Rama Krishna Chava ◽  
Misook Kang

For efficient electrode development in an electrolysis system, Fe2O3, MnO, and heterojunction Fe2O3-MnO materials were synthesized via a simple sol-gel method. These particles were coated on a Ni-foam electrode, and the resulting material was used as an electrode to be used during an oxygen evolution reaction (OER). A 1000-cycle OER test in a KOH alkaline electrolyte indicated that the heterojunction Fe2O3-MnO/NF electrode exhibited the most stable and highest OER activity: it exhibited a low overvoltage (n) of 370 mV and a small Tafel slope of 66 mV/dec. X-ray photoelectron spectroscopy indicated that the excellent redox performance contributed to the synergy of Mn and Fe, which enhanced the OER performance of the Fe2O3-MnO/NF electrode. Furthermore, the effective redox reaction of Mn and Fe indicated that the structure maintained stability even under 1000 repeated OER cycles.


2020 ◽  
Vol 22 (5) ◽  
pp. 1710-1719
Author(s):  
Dongjie Li ◽  
Suqin Liu ◽  
Guanying Ye ◽  
Weiwei Zhu ◽  
Kuangmin Zhao ◽  
...  

NixFe3−xO4/Ni hybrid nanosheet arrays have been directly fabricated on different substrates via template-free and annealing-free one-step electrodeposition, which show excellent catalytic performance for the oxygen evolution reaction.


2020 ◽  
Vol 8 (39) ◽  
pp. 20323-20330
Author(s):  
Zhongxin Jing ◽  
Qingyun Zhao ◽  
Dehua Zheng ◽  
Lei Sun ◽  
Jiahui Geng ◽  
...  

We synthesized nickel-doped pyrrhotite iron sulfide nanosheets via a one-pot synthetic route, with great oxygen evolution reaction and hydrogen evolution reaction activities.


2017 ◽  
Vol 9 (34) ◽  
pp. 28627-28634 ◽  
Author(s):  
Umair Yaqub Qazi ◽  
Cheng-Zong Yuan ◽  
Naseeb Ullah ◽  
Yi-Fan Jiang ◽  
Muhammad Imran ◽  
...  

2018 ◽  
Vol 6 (14) ◽  
pp. 5592-5597 ◽  
Author(s):  
Yanshuo Jin ◽  
Xin Yue ◽  
Hongyu Du ◽  
Kai Wang ◽  
Shangli Huang ◽  
...  

The large overpotential loss of the oxygen evolution reaction (OER) is a major obstacle restricting the wide commercial application of water-splitting devices.


2017 ◽  
Vol 19 (5) ◽  
pp. 1327-1335 ◽  
Author(s):  
Debanjan Das ◽  
Abhinaba Das ◽  
Meera Reghunath ◽  
Karuna Kar Nanda

A novel one-step, one-pot strategy to synthesize Co2P encapsulated N,P dual doped carbon nanotubes (Co2P/NPCNTs) is developed via a g-C3N4 intermediated approach.


Nanomaterials ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 1486 ◽  
Author(s):  
Junyeong Kim ◽  
Jun Neoung Heo ◽  
Jeong Yeon Do ◽  
Rama Krishna Chava ◽  
Misook Kang

For efficient electrode development in an electrolysis system, Fe2O3, MnO, and heterojunction Fe2O3-MnO materials were synthesized via a simple sol–gel method. These particles were coated on a Ni-foam (NF) electrode, and the resulting material was used as an electrode to be used during an oxygen evolution reaction (OER). A 1000-cycle OER test in a KOH alkaline electrolyte indicated that the heterojunction Fe2O3-MnO/NF electrode exhibited the most stable and highest OER activity: it exhibited a low overvoltage (n) of 370 mV and a small Tafel slope of 66 mV/dec. X-ray photoelectron spectroscopy indicated that the excellent redox performance contributed to the synergy of Mn and Fe, which enhanced the OER performance of the Fe2O3-MnO/NF electrode. Furthermore, the effective redox reaction of Mn and Fe indicated that the structure maintained stability even under 1000 repeated OER cycles.


2021 ◽  
Author(s):  
Zihao Liu ◽  
Shifeng Li ◽  
Fangfang Wang ◽  
Mingxia Li ◽  
Yonghong Ni

FeNi-layered double hydroxide (LDH) is thought to be an excellent electrocatalyst for oxygen evolution reaction (OER), but it always shows extremely poor electrocatalytic activity toward hydrogen evolution reaction (HER) in...


2021 ◽  
Author(s):  
Xinxin Sang ◽  
Hengbo Wu ◽  
Nan Zang ◽  
Huilian Che ◽  
Dongyin Liu ◽  
...  

Co2P hybridized with multi-doped carbon nanoleaves is obtained via direct carbonization of ZIF-L/PEI/PA and show good electro-catalytic performance in OER.


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