scholarly journals The Cyclops Ophiolite as a Source of High-Cr Spinels from Marine Sediments on the Jayapura Regency Coast (New Guinea, Indonesia)

Minerals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 735
Author(s):  
Karol Zglinicki ◽  
Krzysztof Szamałek ◽  
Irena Górska

The first detailed mineralogy, geochemistry and origin of heavy minerals in marine sediments along the Jayapura Regency coast on the Indonesian part of New Guinea Island are reported as part of a larger set of investigations conducted since 2009. In these sediments, the following heavy minerals were identified: high-Al and high-Cr spinels, chromian andradite, Mg-olivine, magnetite, mixture of iron (III) oxyhydroxides (limonite) and minerals from serpentine-group minerals (lizardite, antigorite). The heavy mineral fraction of marine sediments contains increased concentrations of metals, including W (up to 257.72 ppm) and Ag (up to 1330.29 ppb) as well as minor amounts of Ni (7.1–3560.9 ppm) and Cr (68.0–5816.0 ppm). The present state of geological knowledge suggests that there are no known prospects for rich Ti, Ni, Co, Cr, Au deposits along the examined part of the Jayapura coast. However, the average content of Ag and W is high enough to provide an impulse for suggested further deposit research. The source of marine sediments is Cyclops ophiolite, which contains a typical ophiolite sequence. Cyclops Mountain rocks have undergone intense chemical weathering processes and the resulting eroded material has been deposited on the narrow continental shelf. The chemical composition of chromian spinels indicates that their source is depleted peridotites from the SSZ (supra-subduction zone) environment of the Cyclops ophiolite. A detailed geochemical examination indicates that the evolution of parental melt of these rocks evolved towards magma with geochemical parameters similar to mid-ocean ridge basalt (MORB).

2021 ◽  
Author(s):  
Philippe Negrel ◽  
Anna Ladenberger ◽  
Clemens Reimann ◽  
Alecos Demetriades ◽  
Manfred Birke ◽  
...  

<p>Collection of agricultural soil samples in Europe (0–20 cm, 33 countries, 5.6 million km<sup>2</sup>) during the GEMAS (GEochemical Mapping of Agricultural and grazing land Soil) continental-scale project allowed the study of geochemical behaviour of major elements during weathering (SiO<sub>2</sub>, TiO<sub>2</sub>, Al<sub>2</sub>O<sub>3</sub>, Fe<sub>2</sub>O<sub>3</sub>, MgO, CaO, Na<sub>2</sub>O, K<sub>2</sub>O, P<sub>2</sub>O<sub>5</sub>) using their total concentrations (XRF data). The chemical composition of soil represents to a large extent the primary mineralogy of the source bedrock, the effects of pre- and post-depositional weathering and element mobility, either by leaching or mineral sorting with the addition of formation of secondary products such as clays.</p><p>Bulk geochemistry is used to calculate a set of weathering indices such as chemical index of alteration CIA, reductive and oxidative mafic index of alteration MIA, the change in mass balance t (calculation relative to immobile Nb) for soil derived from silicate parent materials defined as granite, gneiss and schist at the European continental-scale. Silicate minerals of soil parent materials can be either very resistant to weathering or very soluble and export of elements in dissolved form and precipitation of secondary phases can occur at a large scale. Either way, they leave a strong chemical signature in derived soil, which can be quantified and classified with help of geochemical indices that are useful tools to evaluate chemical weathering trends. Weathering indices and gain-loss mass transfer coefficients were applied to agricultural soil to provide an insight into the weathering processes affecting three silicate parent rocks and their impact on soil development at the European scale. Distinct chemical composition and weathering patterns has been evidenced in silicate derived soil. The interpretation of geographical distribution of soil types with silicate substrate allows better understanding of soil nutritional status, metal enrichments, degradation mechanisms under various climate conditions.</p>


1998 ◽  
Vol 135 (5) ◽  
pp. 669-683 ◽  
Author(s):  
A. B. KAMPUNZU ◽  
P. AKANYANG ◽  
R. B. M. MAPEO ◽  
B. N. MODIE ◽  
M. WENDORFF

The c. 1.1 Ga Kgwebe metavolcanic rocks exposed in the northwest of Botswana are late Kibaran rocks. They represent a bimodal suite of Within-Plate low titanium-phosphorus (LTP) continental tholeiites and post-orogenic Within-Plate high-K rhyolites. The chemical compositions of the Kgwebe mafic rocks are characterized by low values of Ce/Pb (<10) and high La/Nb ratios (average c. 2, maximum 4). Mid-ocean ridge basalts (MORB)-normalized spidergrams show marked enrichment in mobile elements (Sr, K, Rb, Ba) and negative anomalies in Nb. These features suggest they may have originated in a mantle, enriched during a previous subduction event. The Kgwebe metarhyolites are marked by Y>60 ppm, Sr/Y<1, Rb/Th>20 and high K-contents. They cannot therefore be the product of melting of sediments or a subducting slab. It is inferred that they represent felsic magmas resulting from melting of Mesoproterozoic (Kibaran) calcalkaline rocks underplated in the middle and/or lower crust. The Kgwebe bimodal metavolcanic rocks pre-date the Neoproterozoic Ghanzi Group rocks which are correlated with the lower part of the Damara sequence. The chemical composition and field relations suggest that these metavolcanic rocks were emplaced during a late orogenic collision-associated extensional collapse. This collapse affected a crust thickened during the Kibaran orogeny in the Namaqua-Natal Belt of southwest Africa.


2006 ◽  
Vol 143 (3) ◽  
pp. 329-342 ◽  
Author(s):  
P. FAUPL ◽  
A. PAVLOPOULOS ◽  
U. KLÖTZLI ◽  
K. PETRAKAKIS

Two heavy mineral populations characterize the siliciclastic material of the mid-Cretaceous turbidites of the Katafito Formation (‘First Flysch’) of the Pindos zone: a stable, zircon-rich group and an ophiolite-derived, chrome spinel-rich one. U/Pb and Pb/Pb dating on magmatic zircons from the stable heavy mineral group clearly illustrate the existence of Variscan magmatic complexes in the source terrain, but also provide evidence for magmatism as old as Precambrian. Based on microprobe analyses, the chrome spinel detritus was predominantly supplied from peridotites of mid-ocean ridge as well as suprasubduction zone origin. A small volcanic spinel population was mainly derived from MORB and back-arc basin basalts. The lithological variability of the mid-Cretaceous ophiolite bodies, based on spinel chemistry, is much broader than that of ophiolite complexes presently exposed in the Hellenides. The chrome spinel detritus compares closely with that from the Outer and Inner Dinarides. The source terrain of the ophiolite-derived heavy minerals was situated in a more internal palaeogeographic position than that of the Pindos zone. The zircon-rich heavy mineral group could have had either an external and/or an internal source, but the chrome spinel constantly accompanying the stable mineral detritus seems to be more indicative of an internal source terrain.


2019 ◽  
Author(s):  
Yung Ping Lee ◽  
◽  
Jonathan E. Snow ◽  
Yongjun Gao
Keyword(s):  

2021 ◽  
Vol 566 ◽  
pp. 116951
Author(s):  
Suzanne K. Birner ◽  
Elizabeth Cottrell ◽  
Jessica M. Warren ◽  
Katherine A. Kelley ◽  
Fred A. Davis

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Frances M. Deegan ◽  
Martin J. Whitehouse ◽  
Valentin R. Troll ◽  
Harri Geiger ◽  
Heejin Jeon ◽  
...  

AbstractMagma plumbing systems underlying subduction zone volcanoes extend from the mantle through the overlying crust and facilitate protracted fractional crystallisation, assimilation, and mixing, which frequently obscures a clear view of mantle source compositions. In order to see through this crustal noise, we present intracrystal Secondary Ion Mass Spectrometry (SIMS) δ18O values in clinopyroxene from Merapi, Kelut, Batur, and Agung volcanoes in the Sunda arc, Indonesia, under which the thickness of the crust decreases from ca. 30 km at Merapi to ≤20 km at Agung. Here we show that mean clinopyroxene δ18O values decrease concomitantly with crustal thickness and that lavas from Agung possess mantle-like He-Sr-Nd-Pb isotope ratios and clinopyroxene mean equilibrium melt δ18O values of 5.7 ‰ (±0.2 1 SD) indistinguishable from the δ18O range for Mid Ocean Ridge Basalt (MORB). The oxygen isotope composition of the mantle underlying the East Sunda Arc is therefore largely unaffected by subduction-driven metasomatism and may thus represent a sediment-poor arc end-member.


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