scholarly journals Petrogenetic Constraints of Early Cenozoic Mafic Rocks in the Southwest Songliao Basin, NE China: Implications for the Genesis of Sandstone-Hosted Qianjiadian Uranium Deposits

Minerals ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1014
Author(s):  
Dong-Guang Yang ◽  
Jian-Hua Wu ◽  
Feng-Jun Nie ◽  
Christophe Bonnetti ◽  
Fei Xia ◽  
...  

The tectonic inversion of the Songliao Basin during the Cenozoic may have played an important role in controlling the development of sandstone-type uranium deposits. The widely distributed mafic intrusions in the host sandstones of the Qianjiadian U ore deposits provided new insights to constrain the regional tectonic evolution and the genesis of the U mineralization. In this study, zircon U-Pb dating, whole-rock geochemistry, Sr-Nd-Pb isotope analysis, and mineral chemical compositions were presented for the mafic rocks from the Qianjiadian area. The mafic rocks display low SiO2 (44.91–52.05 wt.%), high TFe2O3 contents (9.97–16.46 wt.%), variable MgO (4.59–15.87 wt.%), and moderate K2O + Na2O (3.19–6.52 wt.%), and can be subdivided into AB group (including basanites and alkali olivine basaltic rocks) and TB group (mainly tholeiitic basaltic rocks). They are characterized by homogenous isotopic compositions (εNd (t) = 3.47–5.89 and 87Sr/86Sr = 0.7032–0.7042) and relatively high radiogenic 206Pb/204Pb (18.13–18.34) and Nb/U ratios (23.0–45.6), similar to the nearby Shuangliao basalts, suggesting a common asthenospheric origin enriched with slab-derived components prior to melting. Zircon U-Pb and previous Ar-Ar dating show that the AB group formed earlier (51–47 Ma) than the TB group (42–40 Ma). Compared to the TB group, the AB group has higher TiO2, Na2O, K2O, P2O5, Ce, and HREE contents and Ta/Yb and Sr/Yb ratios, which may have resulted from variable depth of partial melting in association with lithospheric thinning. Combined with previous research, the Songliao Basin experienced: (1) Eocene (~50–40 Ma) lithospheric thinning and crustal extension during which mafic rocks intruded into the host sandstones of the Qianjiadian deposit, (2) a tectonic inversion from extension to tectonic uplift attributed to the subduction of the Pacific Plate occurring at ~40 Ma, and (3) Oligo–Miocene (~40–10 Ma) tectonic uplift, which is temporally associated with U mineralization. Finally, the close spatial relation between mafic intrusions and the U mineralization, dike-related secondary reduction, and secondary oxidation of the mafic rocks in the Qianjiadian area suggest that Eocene mafic rocks and their alteration halo in the Songliao Basin may have played a role as a reducing barrier for the U mineralization.

2017 ◽  
Vol 6 (1) ◽  
pp. 155
Author(s):  
Yao Honoré Koffi ◽  
Sagbrou Chérubin Djro ◽  
Urbain Wenmenga

The Djarkadougou gold prospect is located on the Birimian greenstone belt of the Houndé exploration permit held by the company Orezone Inc. The permit is at 275 km far from the capital Ouagadougou south- western Burkina Faso, West Africa. This area is based on sheared and metamorphosed greenschist facies rocks. Metamorphism locally reaches to the amphibolite facies around intrusions. There are two major lithological units whose interface is marked by a NW-SE trending shear corridor: an unit of andesite-basaltic rocks of andesitic breccias in the East and volcaniclastic and sedimentary unit composed flows, tuffs and felsic to mafic breccia, interbedded volcano-sedimentary rocks. All this together is intruded by plutonic rocks, and various felsic to mafic dykes. These rocks have undergone ductile to brittle heterogeneous deformations and hydrothermal alteration sericite ±carbonate ±quartz±sulphide within deformation corridors. The rocks of the East and West domains affected by three phases of brittle-ductile deformation (D1, D2, and D3) and the meteoric alteration is systematic in superficial facies of Djarakadougou core drilling.Geochemical analysis shows a tholeiitic to calc-alkaline volcanic serie characteristic a bimodal volcanism. The spectra of normalized REE chondrites are generally flat and constant reminding those of N-MORB basalt. The chemical compositions of andesite and basalt are deferred on several discrimination diagrams especially Th / Yb - Nb / Yb and 2 Nb - Zr / 4 - Y show that andesites and basalts of the prospect are issued in geotectonic setting of volcanism preponderant arc.


Minerals ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 123 ◽  
Author(s):  
Miloš René ◽  
Zdeněk Dolníček ◽  
Jiří Sejkora ◽  
Pavel Škácha ◽  
Vladimír Šrein

Uraninite-coffinite vein-type mineralisation with significant predominance of uraninite over coffinite occurs in the Příbram, Jáchymov and Horní Slavkov ore districts and the Potůčky, Zálesí and Předbořice uranium deposits. These uranium deposits are hosted by faults that are mostly developed in low- to high-grade metamorphic rocks of the basement of the Bohemian Massif. Textural features and the chemical composition of uraninite, coffinite and ningyoite were studied using an electron microprobe. Collomorphic uraninite was the only primary uranium mineral in all deposits studied. The uraninites contained variable and elevated concentrations of PbO (1.5 wt %–5.4 wt %), CaO (0.7 wt %–8.3 wt %), and SiO2 (up to 10.0 wt %), whereas the contents of Th, Zr, REE and Y were usually below the detection limits of the electron microprobe. Coffinite usually forms by gradual coffinitization of uraninite in ore deposits and the concentration of CaO was lower than that in uraninites, varying from 0.6 wt % to 6.5 wt %. Coffinite from the Jáchymov ore district was partly enriched in Zr (up to 3.3 wt % ZrO2) and Y (up to 5.5 wt % Y2O3), and from the Potůčky uranium deposit, was distinctly enriched in P (up to 8.8 wt % P2O5), occurring in association with ningyoite. The chemical composition of ningyoite was similar to that from type locality; however, ningyoite from Potůčky was distinctly enriched in REE, containing up to 22.3 wt % REE2O3.


1975 ◽  
Vol 40 (309) ◽  
pp. 25-32 ◽  
Author(s):  
K. A. Rodgers

SummaryEocene tholeiitic basalts occur throughout the length of New Caledonia where their emplacement preceded that of the peridotite massifs. In the south, two areas of basaltic rocks are intimately associated with Eocene sediments, which have been overridden by the peridotites. The aphyric, holocrystalline basalts consist of plagioclase, clinopyroxene, titanomagnetite, and minor quartz together with their abundant alteration products, which include epidote and uralite. The chemical compositions of these rocks fail to show agreement with oceanic tholeiitites, as suggested by earlier writers, although strong similarities exist with the basalts of the Papuan Ultramafic Belt.


Minerals ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 993
Author(s):  
Li Zhang ◽  
Changmin Zhang ◽  
Luxing Dou

The limited knowledge of Late Cretaceous terrestrial environments and their response to tectonic events in mid-latitudes can be addressed through continental basin deposits such as paleosols. Paleosols have been discovered in the Late Cretaceous Yaojia Formation in the southern Songlaio Basin and are recognized by evidence of soil structures controlled by pedogenesis. Sedimentary facies research on red paleosols was conducted on the Late Cretaceous Yaojia Formation in the outcrop of the southern Songliao Basin to interpret the depositional environments and tectonic significance of red paleosols during the greenhouse period. Mudflat, lake margin, and shallow lake depositional environments in a semi-arid climate are interpreted from the outcrops based on sedimentary descriptions and interpretation as well as geochemical and micromorphological analyses of paleosols in outcrops. We reconstructed the paleoenvironmental and paleoclimatic conditions through the paleosols in the mudflats and lake margin. The red paleosols in the mudflats and lake margin deposits formed in a stable landscape influenced by the tectonic uplift of the Songliao Basin, which is considered as new important evidence for tectonic uplift influenced by the collision of the Okhotomorsk Block with East Asia. The tectonic uplift process in East Asia is identified from the evolution of the depositional environments and drainage conditions inferred from different types of paleosols. Thus, the paleosols-bearing red bed deposits in outcrops provide an important contribution of the Late Cretaceous terrestrial paleoclimate and the tectonic setting research.


2020 ◽  
Vol 88 ◽  
pp. 88-105 ◽  
Author(s):  
Yinhang Cheng ◽  
Shaoyi Wang ◽  
Tianfu Zhang ◽  
Xueming Teng ◽  
Cong Ao ◽  
...  

2021 ◽  
Author(s):  
C Mueller ◽  
S J Piercey ◽  
M G Babechuk ◽  
D Copeland

Stratigraphic and lithogeochemical data were collected from selected drill core from the Nugget Pond gold deposit in the Betts Cove area, Newfoundland. The stratigraphy consists of a lower unit of basaltic rocks that are massive to pillowed (Mount Misery Formation). This is overlain by sedimentary rocks of the Scrape Point Formation that consist of lower unit of turbiditic siltstone and hematitic cherts/iron formations (the Nugget Pond member); the unit locally has a volcaniclastic rich-unit at its base and grades upwards into finer grained volcaniclastic/turbiditic rocks. This is capped by basaltic rocks of the Scrape Point Formation that contain pillowed and massive mafic flows that are distinctively plagioclase porphyritic to glomeroporphyritic. The mafic rocks of the Mount Misery Formation have island arc tholeiitic affinities, whereas Scrape Point Formation mafic rocks have normal mid-ocean ridge (N-MORB) to backarc basin basalt (BABB) affinities. One sample of the latter formation has a calc-alkalic affinity. All of these geochemical features are consistent with results and conclusions from previous workers in the area. Clastic sedimentary rocks and Fe-rich sedimentary rocks of the Scrape Point Formation have features consistent with derivation from local, juvenile sources (i.e., intra-basinal mafic rocks). The Scrape Point Formation sedimentary rocks with the highest Fe/Al ratios, inferred to have greatest amount of hydrothermally derived Fe, have positive Ce anomalies on Post-Archean Australian Shale (PAAS)-normalized trace element plots. These features are consistent with having formed via hydrothermal venting into an anoxic/ sub-oxic water column. Further work is needed to test whether these redox features are a localized feature (i.e., restricted basin) or a widespread feature of the late Cambrian-early Ordovician Iapetus Ocean, as well as to delineate the role that these Fe-rich sedimentary rocks have played in the localization of gold mineralization within the Nugget Pond deposit.


1996 ◽  
Vol 465 ◽  
Author(s):  
M. Fayek ◽  
T. K. Kyser ◽  
R. C. Ewing ◽  
M. L. Miller

ABSTRACTExceptionally low δ 18O values of primary uraninite and pitchblende (i.e. -32 per mil to -19.5 per mil) from Proterozoic unconformity-type uranium deposits in Saskatchewan, Canada, in conjunction with theoretical uraninite-water oxygen isotope fractionation factors suggest that primary uranium mineralization is not in oxygen isotopie equilibrium with clays and silicates. The low δ 18O values have been interpreted to have resulted from the recrystallization of primary uranium mineralization in the presence of modern meteoric fluids having low δ 18O values of ca. -18 per mil. The absence of apparent alteration in many of the uraninite and pitchblende samples requires that the uranium minerals exchange oxygen isotopes with fluids, with only minor disturbances to their original chemical compositions and textures. However, experiments on the interaction between water and natural uraninites, from these deposits, and detailed electron micro-probe analyses of natural uraninite and pitchblende indicate that, in the presence of water, old uraninite rapidly alters to curite (Pb2U5O174H2O). The hydration of uraninite to curite releases uranium and calcium into solution and becquerelite (Ca(UO2)6O4(OH)6H2O) is precipitated. In the presence of Si-saturated waters, uranium silicate minerals, soddyite ((UO2)2(SiO4)2H2O) and kasolite (Pb(UO2)SiO4H2O are precipitated in addition to, curite and schoepite ((UO2)8O2(OH)12(H2O)12). The mineral paragenesis observed in these experiments is similar to sequences observed in oxidized zones in uranium deposits and UO2-water experiments. Therefore, it is unlikely that natural uraninite and pitchblende can simply exchange oxygen with an oxidizing fluid without a concomitant change in phase chemistry or structure, nor will oxidation of uraninite lead to the formation of U3O7. as predicted by theoretical calculations used in natural analogue studies for the disposal of high level nuclear waste.


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