The Geochemical and Isotopic Record of Wilson Cycles in Northwestern South America: From the Iapetus to the Caribbean

Isotopic and geochemical data delineate passive margin, rift and active margin cycles in northwestern South America since ~623 Ma, spanning from the Iapetus Wilson Cycle. Ultramafic and mafic rocks record rifting associated with the formation of the Iapetus Ocean during 623–531 Ma, while the initiation of subduction of the Iapetus and Rheic oceans is recorded by continental arc plutons that formed during 499–414 Ma, with alternating compressive and extensional stages. Muscovite 40Ar/39Ar dates suggest there may have been a phase of Carboniferous metamorphism, although this remains tentative. A Passive margin was modified by active margin magmatism that started at ~294 Ma and culminated with collisional tectonics that signaled the final stages of the amalgamation of western Pangaea. Early Pangaea fragmentation included back-arc rifting during 245–216 Ma, leading to a Pacific active margin that spanned from 213–115 Ma. Trench retreat accelerated during 144–115 Ma, forming a highly attenuated continental margin prior to the collision of the Caribbean Large Igneous Province at ~75 Ma.

A new stratigraphic framework for the early Neoproterozoic successions of Scotland

The circum-North Atlantic region archives three major late-Mesoproterozoic to Neoproterozoic tectonic episodes, the Grenville-Sveconorwegian and Renlandian orogenies followed by rifting and formation of the Iapetus Ocean, and each is bracketed by sedimentary successions that define three megasequences. In this context, we summarise sedimentological and geochronological data and propose a new stratigraphic framework for the iconic Torridonian-Moine-Dalradian successions and related units in Scotland. The Iona, Sleat, Torridon and Morar groups of the Scottish mainland and Inner Hebrides, and the Westing, Sand Voe and Yell Sound groups in Shetland, form the newly named Wester Ross Supergroup. They were deposited c. 1000–950 Ma within a foreland basin to the Grenville Orogen and, collectively, are in Megasequence 1. Some of these units record Renlandian orogenesis at c. 960-920 Ma. The newly named Loch Ness Supergroup consists of the Glenfinnan, Loch Eil and Badenoch groups of the Scottish mainland, deposited c. 900–870 Ma and are assigned to Megasequence 2. These units record Knoydartian orogenesis c. 820-725 Ma. The regionally extensive Dalradian Supergroup belongs to Megasequence 3; it was deposited c. <725-500 Ma and records the opening of the Iapetus Ocean, ultimately leading to deposition of the passive margin Cambrian-Ordovician Ardvreck and Durness groups.

Detrital zircon U-Pb geochronology of a metasomatic calc-silicate in the Tsäkkok Lens, Scandinavian Caledonides

The Tsäkkok Lens of the Seve Nappe Complex in the Scandinavian Caledonides comprises eclogite bodies hosted within metasedimentary rocks. These rocks are thought to be derived from the outermost margin of Baltica along the periphery of the Iapetus Ocean, but detrital records from the sedimentary rocks are lacking.Many metasedimentary outcrops within the lens expose both well-foliated metapelitic rocks and massive calc-silicates. The contacts between these two lithologies are irregular and are observed to trend at all angles to the high-pressure foliation in the metapelites. Where folding is present in the metapelites, the calc-silicate rocks are also locally folded. These relationships suggest metasomatism of the metapelites during the Caledonian orogenesis. Zircon U-Pb geochronology was conducted on sixty-one zircon grains from a calc-silicate sample to investigate if they recorded the metasomatic event and to assess the detrital zircon populations. Zircon grains predominantly show oscillatory zoning, sometimes with thin, homogeneous rims that have embayed contacts with the oscillatory-zoned cores. The zircon cores yielded prominent early Stenian, Calymmian, and Statherian populations with a subordinate number of Tonian grains. The zircon rims exhibit dissolution-reprecipitation of the cores or new growth and provide ages that span similar time frames, indicating overprinting of successive tectonic events. Altogether, the zircon record of the calc-silicate suggests that the Tsäkkok Lens may be correlated to Neoproterozoic basins that are preserved in allochthonous positions within the northern extents of the Caledonian Orogen.

Petrologic constraints on subduction zone metamorphism from a coesite-bearing metapelite in the Northern Appalachian Orogen

&lt;p&gt;The Caledonian orogen formed following Paleozoic subduction of the Iapetus Ocean and preserves evidence of ultrahigh-pressure (UHP) metamorphism and exhumation of crustal rocks from mantle depths. The Appalachian orogen similarly formed in the Paleozoic following subduction of Iapetus Ocean crust, but evidence for (U)HP metamorphism in exhumed Appalachian rocks has been challenging to identify. We present results from a metapelite from high-pressure rocks of the Tillotson Peak Complex in the northern Appalachians, which formed during the middle-Ordovician Taconic orogeny. This sample contained mm-cm scale garnet porphyroblasts that host abundant mineral inclusions. Confocal Raman microspectroscopy of inclusions in the rims of a garnet porphyroblast identified relic coesite, preserved as a bi-mineralic inclusion composed of coesite in &amp;#945;-quartz. Raman depth profiling and 2-dimensional mapping indicate the relic coesite is ~10 &amp;#956;m&lt;sup&gt;3&lt;/sup&gt;, suggesting that mineralogical evidence of UHP metamorphism in the Appalachians may be preserved only as &amp;#956;m-scale inclusions contained in polymetamorphosed rocks. We applied quantitative WDS X-ray maps acquired with electron microprobe, quartz-in-garnet elastic thermobarometry, and Zr-in-rutile trace element thermometry to further constrain the metamorphic history of the coesite-bearing metapelite. Garnet zoning patterns in conjunction with elastic and trace element thermobarometry applied to co-entrapped mineral inclusions suggest that garnet nucleated at 14-15.5 kbar and 420-520 &amp;#176;C, and continuously crystallized to 15-19.5 kbar and 470-560 &amp;#176;C during subduction zone metamorphism. Peak metamorphic conditions based on the stability field of coesite and on Zr-in-rutile thermometry from inclusions in the garnet rims suggest UHP metamorphism at &gt;28 kbar and 530 &amp;#176;C. UHP metamorphism of pelitic sediments within the Taconic paleo-subduction zone invite comparisons with similar UHP rocks in the Caledonian orogeny. Future studies of UHP metamorphism in the Appalachian orogen will focus on constraining: 1) the spatial and temporal scales of UHP metamorphism, 2) the retrograde/exhumation P&amp;#8211;T path of the coesite-bearing metapelite, and 3) the P&amp;#8211;T history of other nearby metamorphic units, such as the Tillotson peak metabasites, to evaluate if these units shared a similar metamorphic history.&lt;/p&gt;

A mantle plume origin for the Scandinavian Dyke Complex: a “piercing point” for 615 Ma plate reconstruction of Baltica?

&lt;p&gt;The origin of Large Igneous Provinces (LIPs) associated with continental breakup and the reconstruction of continents older than c. 320 million years (pre-Pangea) are contentious research problems. Here we study the petrology of a 615 - 590 Myr dolerite dyke complex that intruded rift-basins of the magma-rich margin of Baltica and now is exposed in the Scandinavian Caledonides. These dykes are part of the Central Iapetus Magmatic Province (CIMP), a LIP emplaced in Baltica and Laurentia during opening of the Iapetus Ocean within the Caledonian Wilson Cycle. The &gt;1000 km long dyke complex displays lateral geochemical zonation from enriched to depleted basaltic compositions from south to north. Geochemical modelling of major and trace elements shows these compositions are best explained by melting hot mantle 75-250&amp;#176;C above ambient mantle. Although the trace element modelling solutions are non-unique, the best explanation involves melting a laterally zoned mantle plume with enriched and depleted peridotite lithologies, similar to present-day Iceland and to the North Atlantic Igneous Province. The origin of CIMP appears to have involved several mantle plumes. This is best explained if rifting and breakup magmatism coincided with plume generation zones at the margins of a Large Low Shear-wave Velocity Province (LLSVP) at the core mantle boundary. If the LLSVPs are quasi-stationary back in time as suggested in recent geodynamic models, the CIMP provides a guide for reconstructing the paleogeography of Baltica and Laurentia 615 million years ago to the LLSVP now positioned under the Pacific Ocean. Our results provide a stimulus for using LIPs as piercing points for plate reconstructions.&lt;/p&gt;

Suprasubduction zone ophiolite fragments in the central Appalachian orogen: Evidence for mantle and Moho in the Baltimore Mafic Complex (Maryland, USA)

Suprasubduction zone (SSZ) ophiolites of the northern Appalachians (eastern North America) have provided key constraints on the fundamental tectonic processes responsible for the evolution of the Appalachian orogen. The central and southern Appalachians, which extend from southern New York to Alabama (USA), also contain numerous ultra- mafic-mafic bodies that have been interpreted as ophiolite fragments; however, this interpretation is a matter of debate, with the origin(s) of such occurrences also attributed to layered intrusions. These disparate proposed origins, alongside the range of possible magmatic affinities, have varied potential implications for the magmatic and tectonic evolution of the central and southern Appalachian orogen and its relationship with the northern Appalachian orogen. We present the results of field observations, petrography, bulk-rock geochemistry, and spinel mineral chemistry for ultramafic portions of the Baltimore Mafic Complex, which refers to a series of ultramafic-mafic bodies that are discontinuously exposed in Maryland and southern Pennsylvania (USA). Our data indicate that the Baltimore Mafic Complex comprises SSZ ophiolite fragments. The Soldiers Delight Ultramafite displays geochemical characteristics—including highly depleted bulk-rock trace element patterns and high Cr# of spinel—characteristic of subduction-related mantle peridotites and serpentinites. The Hollofield Ultramafite likely represents the “layered ultramafics” that form the Moho. Interpretation of the Baltimore Mafic Complex as an Iapetus Ocean–derived SSZ ophiolite in the central Appalachian orogen raises the possibility that a broadly coeval suite of ophiolites is preserved along thousands of kilometers of orogenic strike.

Formation of Anorthositic Rocks within the Blair River Inlier of Northern Cape Breton Island, Nova Scotia (Canada)

Rocks from the Blair River inlier of Northern Cape Breton Island (Nova Scotia, Canada) have been correlated with either the Grenville basement of eastern Laurentia or the accreted Avalon terrane. Additional zircon U-Pb dates of spatially associated anorthositic dykes (425.1±2.2 Ma) and a metagabbro (423.8±2.5 Ma) from the Fox Back Ridge intrusion of the Blair River inlier reveal Late Silurian emplacement ages. Their contemporaneity suggests that they may be members of a larger intrusive complex. The anorthositic rocks have high Eu/Eu∗ values (&gt;2.5), and bulk compositions are similar to the mineral compositions of labradorite (An50-70) and andesine (An30-50). The metagabbro is compositionally similar to alkali basalt and does not seem to have been affected by crustal contamination (Nb/U&gt;24; Th/NbPM≤1.1) although it was metamorphosed. The high Tb/YbN (1.8-1.9) ratios suggest that the parental magma of the metagabbro was derived from a garnet-bearing peridotite. Fractional crystallization and mass balance calculations indicate that the anorthositic rocks can be derived by mineral accumulation from a mafic parental magma similar in composition to the metagabbro of this study. The Late Silurian ages suggest that the rocks were emplaced into the Avalon terrane after the closure of the Iapetus Ocean but before Early Devonian (415-410 Ma) sinistral transpression.

Stratigraphy and lithogeochemistry of rocks from the Nugget Pond Deposit area, Baie Verte Peninsula, Newfoundland

Stratigraphic and lithogeochemical data were collected from selected drill core from the Nugget Pond gold deposit in the Betts Cove area, Newfoundland. The stratigraphy consists of a lower unit of basaltic rocks that are massive to pillowed (Mount Misery Formation). This is overlain by sedimentary rocks of the Scrape Point Formation that consist of lower unit of turbiditic siltstone and hematitic cherts/iron formations (the Nugget Pond member); the unit locally has a volcaniclastic rich-unit at its base and grades upwards into finer grained volcaniclastic/turbiditic rocks. This is capped by basaltic rocks of the Scrape Point Formation that contain pillowed and massive mafic flows that are distinctively plagioclase porphyritic to glomeroporphyritic. The mafic rocks of the Mount Misery Formation have island arc tholeiitic affinities, whereas Scrape Point Formation mafic rocks have normal mid-ocean ridge (N-MORB) to backarc basin basalt (BABB) affinities. One sample of the latter formation has a calc-alkalic affinity. All of these geochemical features are consistent with results and conclusions from previous workers in the area. Clastic sedimentary rocks and Fe-rich sedimentary rocks of the Scrape Point Formation have features consistent with derivation from local, juvenile sources (i.e., intra-basinal mafic rocks). The Scrape Point Formation sedimentary rocks with the highest Fe/Al ratios, inferred to have greatest amount of hydrothermally derived Fe, have positive Ce anomalies on Post-Archean Australian Shale (PAAS)-normalized trace element plots. These features are consistent with having formed via hydrothermal venting into an anoxic/ sub-oxic water column. Further work is needed to test whether these redox features are a localized feature (i.e., restricted basin) or a widespread feature of the late Cambrian-early Ordovician Iapetus Ocean, as well as to delineate the role that these Fe-rich sedimentary rocks have played in the localization of gold mineralization within the Nugget Pond deposit.