scholarly journals 3D Spatial Distribution of Arsenic in an Abandoned Mining Area: A Combined Geophysical and Geochemical Approach

Minerals ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1130
Author(s):  
Jesús Ruiz-Roso ◽  
Mari García-Lorenzo ◽  
Pedro Castiñeiras ◽  
Alfonso Muñoz-Martín ◽  
Elena Crespo-Feo

Abandoned mine wastes, containing high sulfide contents, are of particular concern because of the formation of acid mine drainage (AMD), becoming an active and harmful point source of potentially toxic elements (PTEs) to the environment. A detailed evaluation of the chemical and mineralogical composition of mining wastes is necessary to determine effective remediation actions. Due to the high amount of generated wastes as a result of mining and processing activities, the cost and time consumed for this characterization are limiting. Hence, efficient tools could be applied to predict the composition of these wastes and their spatial distribution. This study aims to determine the physico-chemical characterization of wastes from mining activities using geochemical and geophysical techniques. The obtained results, both geochemical and geophysical, allow us to locate areas with a high potential risk of contamination by As in an economic and simple way, and enable us to design detailed geochemical sampling campaigns. In addition, the fact that there are conductive fractures in depth suggests the possible circulation of contaminants through them as well as the preferential lines of circulation.

Alergologia ◽  
2020 ◽  
Vol 1 (4) ◽  
pp. 7
Author(s):  
Mariana Vieru ◽  
Florin-Dan Popescu ◽  
Laura Haidar ◽  
Carmen Bunu-Panaitescu

2010 ◽  
Vol 35 (5) ◽  
pp. 261-267 ◽  
Author(s):  
Wissemn Gallala ◽  
Mohamed Essghaier Gaied ◽  
Borhen Kchaou

2001 ◽  
Vol 71 (3) ◽  
pp. 342-349
Author(s):  
Lucian Eva ◽  
Letitia Doina Duceac ◽  
Liviu Stafie ◽  
Constantin Marcu ◽  
Geta Mitrea ◽  
...  

The fourth generation cephalosporin antibacterial agent, cefepime, was loaded into layered double hydroxides for enhancing antibiotic efficiency, reducing side effects, as well as achieving the sustained release property. The intercalation of antibiotic into the inter-gallery of ZnAl-layered double hydroxide (LDH) was carried out using ion exchange method, by this constituting a nano-sized organic-inorganic hybrid material for a controlled release novel formulation. Although cefepime is a broad spectrum antibiotic, it has various adverse effects and a significant degradation rate. Thus, the preparation and physico-chemical characterization of nanomaterials able to intercalate this drug is an important study for medical and pharmaceutical field. The antibiotic inclusion into LDHs nanostructure was confirmed by advanced characterization techniques and the release profile of cefepime was analysed with the respect to pH of the simulated media.


2012 ◽  
Vol 358 (23) ◽  
pp. 3280-3288 ◽  
Author(s):  
S. Petrescu ◽  
M. Constantinescu ◽  
E.M. Anghel ◽  
I. Atkinson ◽  
M. Olteanu ◽  
...  

1986 ◽  
Vol 73 ◽  
Author(s):  
William L. Olson

ABSTRACTAlumina sols derived from aluminum sec-butoxide (Yoldas) were characterized. The distribution of the polymer sizes within the sol, determined by gel filtration chromatography (GFC), was found to be dramatically affected by small changes in the chemical processing or preparative procedure. Aging the sol at room temperature for two weeks produced no significant change in the GFC elution curves of the alumina sol. Sols with a “milky” appearance were found to exhibit a wider distribution of polymers by GFC than transparent sols. Rotary evaporation of the sol followed by redissolution of the residue was found to change the polymer size distribution described by the gel filtration elution curves. These observations coupled with 27Al NMR spectroscopy and viscometry measurements were used to elucidate the effects of process conditions and aging on the molecular structure of the sol.


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