Recent Materials Developed for Dispersive Solid Phase Extraction

Solid phase extraction (SPE) is an analytical procedure developed with the purpose of separating a target analyte from a complex sample matrix prior to quantitative or qualitative determination. The purpose of such treatment is twofold: elimination of matrix constituents that could interfere with the detection process or even damage analytical equipment as well as enriching the analyte in the sample so that it is readily available for detection. Dispersive solid phase extraction (dSPE) is a recent development of the standard SPE technique that is attracting growing attention due to its remarkable simplicity, short extraction time and low requirement for solvent expenditure, accompanied by high effectiveness and wide applicability. This review aims to thoroughly survey recently conducted analytical studies focusing on methods utilizing novel, interesting nanomaterials as dSPE sorbents, as well as known materials that have been only recently successfully applied in dSPE techniques, and evaluate their performance and suitability based on comparison with previously reported analytical procedures.

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Optimization of Clean-up Process Conditions by Comparative Analysis of Dispersive Solid Phase Extraction and Automated Micro Solid Phase Extraction Clean-up for GC-MS/MS Analysis of Pesticides in Tuber Crops

Analytical Chemistry Letters ◽

10.1080/22297928.2021.1877196 ◽

2021 ◽

Vol 11 (1) ◽

pp. 29-38

Author(s):

Sarvendra Pratap Singh ◽

Jyoti Sharma

Keyword(s):

Comparative Analysis ◽

Solid Phase Extraction ◽

Solid Phase ◽

Process Conditions ◽

Phase Extraction ◽

Dispersive Solid Phase Extraction ◽

Ms Analysis ◽

Tuber Crops

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Dispersive solid-phase extraction for simultaneous determination of four amphetamines drugs in urine using gas chromatography–mass spectrometry

Journal of the Iranian Chemical Society ◽

10.1007/s13738-021-02339-0 ◽

2021 ◽

Author(s):

Mahir Z. Elboraie ◽

Abdalla A. Elbashir ◽

Eltayeb E. M. Eid ◽

Hassan Y. Aboul-Enein

Keyword(s):

Mass Spectrometry ◽

Gas Chromatography ◽

Solid Phase Extraction ◽

Simultaneous Determination ◽

Solid Phase ◽

Gas Chromatography Mass Spectrometry ◽

Phase Extraction ◽

Dispersive Solid Phase Extraction ◽

Chromatography Mass Spectrometry

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Multivariate optimization of low-temperature cleanup followed by dispersive solid-phase extraction for detection of Bisphenol A and benzophenones in infant formula

Journal of Chromatography A ◽

10.1016/j.chroma.2020.461757 ◽

2021 ◽

Vol 1635 ◽

pp. 461757

Author(s):

Marcella Vitoria Galindo ◽

Wellington da Silva Oliveira ◽

Helena Teixeira Godoy

Keyword(s):

Low Temperature ◽

Bisphenol A ◽

Solid Phase Extraction ◽

Infant Formula ◽

Solid Phase ◽

Phase Extraction ◽

Dispersive Solid Phase Extraction ◽

Multivariate Optimization

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Magnetic Dispersive Solid Phase Extraction of Cu (II) as 1- (2-pyridylazo)-2-naphthol Chelates on Fe3O4@XAD-16

Iranian Journal of Science and Technology Transactions A Science ◽

10.1007/s40995-021-01194-1 ◽

2021 ◽

Author(s):

Ozgur Ozalp ◽

Mustafa Soylak

Keyword(s):

Solid Phase Extraction ◽

Solid Phase ◽

Phase Extraction ◽

Dispersive Solid Phase Extraction

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Development of Surface Molecularly Imprinted Polymers as Dispersive Solid Phase Extraction Coupled with HPLC Method for the Removal and Detection of Griseofulvin in Surface Water

International Journal of Environmental Research and Public Health ◽

10.3390/ijerph17010134 ◽

2019 ◽

Vol 17 (1) ◽

pp. 134 ◽

Cited By ~ 1

Author(s):

Kamran Bashir ◽

Zhimin Luo ◽

Guoning Chen ◽

Hua Shu ◽

Xia Cui ◽

...

Keyword(s):

Surface Water ◽

Solid Phase Extraction ◽

Molecularly Imprinted Polymers ◽

Water Samples ◽

Solid Phase ◽

Phase Extraction ◽

Dispersive Solid Phase Extraction ◽

Molecularly Imprinted ◽

Imprinted Polymers ◽

Surface Water Samples

Griseofulvin (GSF) is clinically employed to treat fungal infections in humans and animals. GSF was detected in surface waters as a pharmaceutical pollutant. GSF detection as an anthropogenic pollutant is considered as a possible source of drug resistance and risk factor in ecosystem. To address this concern, a new extraction and enrichment method was developed. GSF-surface molecularly imprinted polymers (GSF-SMIPs) were prepared and applied as solid phase extraction (SPE) sorbent. A dispersive solid phase extraction (DSPE) method was designed and combined with HPLC for the analysis of GSF in surface water samples. The performance of GSF-SMIPs was assessed for its potential to remove GSF from water samples. The factors affecting the removal efficiency such as sample pH and ionic strength were investigated and optimized. The DSPE conditions such as the amount of GSF-SMIPs, the extraction time, the type and volume of desorption solvents were also optimized. The established method is linear over the range of 0.1–100 µg/mL. The limits of detection and quantification were 0.01 and 0.03 µg/mL respectively. Good recoveries (91.6–98.8%) were achieved after DSPE. The intra-day and inter-day relative standard deviations were 0.8 and 4.3% respectively. The SMIPs demonstrated good removal efficiency (91.6%) as compared to powder activated carbon (67.7%). Moreover, the SMIPs can be reused 10 times for water samples. This is an additional advantage over single-use activated carbon and other commercial sorbents. This study provides a specific and sensitive method for the selective extraction and detection of GSF in surface water samples.

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