scholarly journals Thermal Energy Storage and Heat Transfer of Nano-Enhanced Phase Change Material (NePCM) in a Shell and Tube Thermal Energy Storage (TES) Unit with a Partial Layer of Eccentric Copper Foam

Molecules ◽  
2021 ◽  
Vol 26 (5) ◽  
pp. 1491
Author(s):  
Mohammad Ghalambaz ◽  
Seyed Abdollah Mansouri Mehryan ◽  
Kasra Ayoubi Ayoubloo ◽  
Ahmad Hajjar ◽  
Mohamad El Kadri ◽  
...  

Thermal energy storage units conventionally have the drawback of slow charging response. Thus, heat transfer enhancement techniques are required to reduce charging time. Using nanoadditives is a promising approach to enhance the heat transfer and energy storage response time of materials that store heat by undergoing a reversible phase change, so-called phase change materials. In the present study, a combination of such materials enhanced with the addition of nanometer-scale graphene oxide particles (called nano-enhanced phase change materials) and a layer of a copper foam is proposed to improve the thermal performance of a shell-and-tube latent heat thermal energy storage (LHTES) unit filled with capric acid. Both graphene oxide and copper nanoparticles were tested as the nanometer-scale additives. A geometrically nonuniform layer of copper foam was placed over the hot tube inside the unit. The metal foam layer can improve heat transfer with an increase of the composite thermal conductivity. However, it suppressed the natural convection flows and could reduce heat transfer in the molten regions. Thus, a metal foam layer with a nonuniform shape can maximize thermal conductivity in conduction-dominant regions and minimize its adverse impacts on natural convection flows. The heat transfer was modeled using partial differential equations for conservations of momentum and heat. The finite element method was used to solve the partial differential equations. A backward differential formula was used to control the accuracy and convergence of the solution automatically. Mesh adaptation was applied to increase the mesh resolution at the interface between phases and improve the quality and stability of the solution. The impact of the eccentricity and porosity of the metal foam layer and the volume fraction of nanoparticles on the energy storage and the thermal performance of the LHTES unit was addressed. The layer of the metal foam notably improves the response time of the LHTES unit, and a 10% eccentricity of the porous layer toward the bottom improved the response time of the LHTES unit by 50%. The presence of nanoadditives could reduce the response time (melting time) of the LHTES unit by 12%, and copper nanoparticles were slightly better than graphene oxide particles in terms of heat transfer enhancement. The design parameters of the eccentricity, porosity, and volume fraction of nanoparticles had minimal impact on the thermal energy storage capacity of the LHTES unit, while their impact on the melting time (response time) was significant. Thus, a combination of the enhancement method could practically reduce the thermal charging time of an LHTES unit without a significant increase in its size.

Molecules ◽  
2021 ◽  
Vol 26 (5) ◽  
pp. 1235
Author(s):  
Mohammad Ghalambaz ◽  
Seyed Abdollah Mansouri Mehryan ◽  
Ahmad Hajjar ◽  
Obai Younis ◽  
Mikhail A. Sheremet ◽  
...  

Thermal energy storage is a technique that has the potential to contribute to future energy grids to reduce fluctuations in supply from renewable energy sources. The principle of energy storage is to drive an endothermic phase change when excess energy is available and to allow the phase change to reverse and release heat when energy demand exceeds supply. Unwanted charge leakage and low heat transfer rates can limit the effectiveness of the units, but both of these problems can be mitigated by incorporating a metal foam into the design of the storage unit. This study demonstrates the benefits of adding copper foam into a thermal energy storage unit based on capric acid enhanced by copper nanoparticles. The volume fraction of nanoparticles and the location and porosity of the foam were optimized using the Taguchi approach to minimize the charge leakage expected from simulations. Placing the foam layer at the bottom of the unit with the maximum possible height and minimum porosity led to the lowest charge time. The optimum concentration of nanoparticles was found to be 4 vol.%, while the maximu possible concentration was 6 vol.%. The use of an optimized design of the enclosure and the optimum fraction of nanoparticles led to a predicted charging time for the unit that was approximately 58% shorter than that of the worst design. A sensitivity analysis shows that the height of the foam layer and its porosity are the dominant variables, and the location of the porous layer and volume fraction of nanoparticles are of secondary importance. Therefore, a well-designed location and size of a metal foam layer could be used to improve the charging speed of thermal energy storage units significantly. In such designs, the porosity and the placement-location of the foam should be considered more strongly than other factors.


2012 ◽  
Vol 260-261 ◽  
pp. 137-141 ◽  
Author(s):  
Yong Qi Xie ◽  
Jun Song ◽  
Peng Tao Chi ◽  
Jian Zu Yu

An experimental study has been carried out to evaluate how fin and copper foam enhance the heat transfer performance of phase change thermal energy storage unit. The thickness of fins is 0.8mm, the porosity of the copper foam is 96% and the phase change material (PCM) is 99% pure eicosane. The samples with fin, copper foam and paraffin (FCFP) or with single copper foam and paraffin (CFP) were processed and their response to temperature variations were tested for vertical placement and horizontal placement under different heat flux conditions. The experimental results show that the use of fin and copper foam can make the sample melt much faster than single copper foam and the effective thermal conductivity of the FCFP composite is 10.83 W/(m∙K), which is 2.7 times as that of the CFP composite. In addition, horizontal placement is more contributive to the heat transfer than vertical placement for high thermal conductivity composite.


Author(s):  
Bernardo Buonomo ◽  
Davide Ercole ◽  
Oronzio Manca ◽  
Hasan Celik ◽  
Moghtada Mobedi

In this paper, a numerical investigation on Latent Heat Thermal Energy Storage System (LHTESS) based on a phase change material (PCM) is accomplished. The geometry of the system under investigation is a vertical shell and tube LHTES made with two concentric aluminum tubes. The internal surface of the hollow cylinder is assumed at a constant temperature above the melting temperature of the PCM to simulate the heat transfer from a hot fluid. The other external surfaces are assumed adiabatic. The phase change of the PCM is modeled with the enthalpy porosity theory while the metal foam is considered as a porous media that obeys to the Darcy-Forchheimer law. The momentum equations are modified by adding of suitable source term which it allows to model the solid phase of PCM and natural convection in the liquid phase of PCM. Both local thermal equilibrium (LTE) and local thermal non-equilibrium (LTNE) models are examined. Results as a function of time for the charging phase are carried out for different porosities and assigned pore per inch (PPI). The results show that at high porosity the LTE and LTNE models have the same melting time while at low porosity the LTNE has a larger melting time. Moreover, the presence of metal foam improves significantly the heat transfer in the LHTES giving a very faster phase change process with respect to pure PCM, reducing the melting time more than one order of magnitude.


Author(s):  
Bernardo Buonomo ◽  
Davide Ercole ◽  
Oronzio Manca ◽  
Sergio Nardini

In this paper, a numerical investigation on Latent Heat Thermal Energy Storage System (LHTESS) based on a phase change material (PCM) in a metal foam is accomplished. A vertical shell and tube LHTESS made with two concentric aluminum tubes is investigated. The internal surface of the hollow cylinder is at a constant temperature above the PCM melting temperature to simulate the heat transfer from a hot fluid. The other external surfaces are assumed adiabatic. The phase change of the PCM is modeled with the enthalpy porosity theory while the metal foam is considered as a porous media that obeys to the Darcy-Forchheimer law. Local thermal non-equilibrium (LTNE) model is assumed to analyze the metal foam and some comparison are accomplished with the local thermal equilibrium model assumption. The governing equations are solved employing the Ansys-Fluent 15 code. Numerical simulations for PCM, PCM in the porous medium in LTE and in LTNE assumptions are obtained. Results as a function of time for the charging phase are carried out for different porosities and assigned pore per inch (PPI). The results show that at high porosity the LTE and LTNE models have the same melting time while at low porosity the LTNE has a larger melting time. Moreover, the presence of metal foam improves significantly the heat transfer in the LHTESS giving a very faster phase change process with respect to pure PCM, reducing the melting time more than one order of magnitude.


2021 ◽  
Vol 13 (5) ◽  
pp. 2590
Author(s):  
S. A. M. Mehryan ◽  
Kaamran Raahemifar ◽  
Leila Sasani Gargari ◽  
Ahmad Hajjar ◽  
Mohamad El Kadri ◽  
...  

A Nano-Encapsulated Phase-Change Material (NEPCM) suspension is made of nanoparticles containing a Phase Change Material in their core and dispersed in a fluid. These particles can contribute to thermal energy storage and heat transfer by their latent heat of phase change as moving with the host fluid. Thus, such novel nanoliquids are promising for applications in waste heat recovery and thermal energy storage systems. In the present research, the mixed convection of NEPCM suspensions was addressed in a wavy wall cavity containing a rotating solid cylinder. As the nanoparticles move with the liquid, they undergo a phase change and transfer the latent heat. The phase change of nanoparticles was considered as temperature-dependent heat capacity. The governing equations of mass, momentum, and energy conservation were presented as partial differential equations. Then, the governing equations were converted to a non-dimensional form to generalize the solution, and solved by the finite element method. The influence of control parameters such as volume concentration of nanoparticles, fusion temperature of nanoparticles, Stefan number, wall undulations number, and as well as the cylinder size, angular rotation, and thermal conductivities was addressed on the heat transfer in the enclosure. The wall undulation number induces a remarkable change in the Nusselt number. There are optimum fusion temperatures for nanoparticles, which could maximize the heat transfer rate. The increase of the latent heat of nanoparticles (a decline of Stefan number) boosts the heat transfer advantage of employing the phase change particles.


2000 ◽  
Vol 122 (4) ◽  
pp. 176-182 ◽  
Author(s):  
Mounir Ibrahim ◽  
Pavel Sokolov ◽  
Thomas Kerslake ◽  
Carol Tolbert

Two sets of experimental data for cylindrical canisters with thermal energy storage applications were examined in this paper: 1) Ground Experiments and 2) Space Experiments. A 2-D computational model was developed for unsteady heat transfer (conduction and radiation) with phase-change. The radiation heat transfer employed a finite volume method. The following was found in this study: 1) Ground Experiments, the convection heat transfer is equally important to that of the radiation heat transfer; Radiation heat transfer in the liquid is found to be more significant than that in the void; Including the radiation heat transfer in the liquid resulted in lower temperatures (about 15 K) and increased the melting time (about 10 min.); Generally, most of the heat flow takes place in the radial direction. 2) Space Experiments, Radiation heat transfer in the void is found to be more significant than that in the liquid (exactly the opposite to the Ground Experiments); Accordingly, the location and size of the void affects the performance considerably; Including the radiation heat transfer in the void resulted in lower temperatures (about 40 K). [S0199-6231(00)00304-X]


Author(s):  
D. Zhou ◽  
C. Y. Zhao

Phase change materials (PCMs) have been widely used for thermal energy storage systems due to their capability of storing and releasing large amounts of energy with a small volume and a moderate temperature variation. Most PCMs suffer the common problem of low thermal conductivity, being around 0.2 and 0.5 for paraffin and inorganic salts, respectively, which prolongs the charging and discharging period. In an attempt to improve the thermal conductivity of phase change materials, the graphite or metallic matrix is often embedded within PCMs to enhance the heat transfer. This paper presents an experimental study on heat transfer characteristics of PCMs embedded with open-celled metal foams. In this study both paraffin wax and calcium chloride hexahydrate are employed as the heat storage media. The transient heat transfer behavior is measured. Compared to the results of pure PCMs samples, the investigation shows that the additions of metal foams can double the overall heat transfer rate during the melting process. The results of calcium chloride hexahydrate are also compared with those of paraffin wax.


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