The Cyclobutanocucurbit[5–8]uril Family: Electronegative Cavities in Contrast to Classical Cucurbituril while the Electropositive Outer Surface Acts as a Crystal Packing Driver
Keyword(s):
X Ray
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The structural parameters for the cyclobutanoQ[5–8] family were determined through single crystal X-ray diffraction. It was found that the electropositive cyclobutano methylene protons (CH2) are important in forming interlinking crystal packing arrangements driven by the dipole–dipole interactions between these protons and the portal carbonyl O of a near neighbor. This type of interaction was observed across the whole family. Electrostatic potential maps also confirmed the electropositive nature of the cyclobutano CH2 but, more importantly, it was established that the cavities are electronegative in contrast to classical Q[5–8], which are near neutral.
2013 ◽
Vol 834-836
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pp. 515-518
2015 ◽
Vol 71
(3)
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pp. 285-292
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2018 ◽
Vol 74
(3)
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pp. 307-311
Keyword(s):
2019 ◽
Vol 75
(6)
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pp. 1186-1196
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2017 ◽
Vol 73
(5)
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pp. 399-406
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