scholarly journals Preparation of Hollow Core–Shell Fe3O4/Nitrogen-Doped Carbon Nanocomposites for Lithium-Ion Batteries

Molecules ◽  
2022 ◽  
Vol 27 (2) ◽  
pp. 396
Author(s):  
Jie Wang ◽  
Qin Hu ◽  
Wenhui Hu ◽  
Wei Zhu ◽  
Ying Wei ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Iron Oxides ◽  
Electrode Materials ◽  
Low Cost ◽  
Lithium Ion ◽  
Cycle Performance ◽  
Etching Time ◽  
Core Shell ◽  
Hollow Core ◽  
Carbon Nanocomposites

Iron oxides are potential electrode materials for lithium-ion batteries because of their high theoretical capacities, low cost, rich resources, and their non-polluting properties. However, iron oxides demonstrate large volume expansion during the lithium intercalation process, resulting in the electrode material being crushed, which always results in poor cycle performance. In this paper, to solve the above problem, iron oxide/carbon nanocomposites with a hollow core–shell structure were designed. Firstly, an Fe2O3@polydopamine nanocomposite was prepared using an Fe2O3 nanocube and dopamine hydrochloride as precursors. Secondly, an Fe3O4@N-doped C composite was obtained by means of further carbonization treatment. Finally, Fe3O4@void@N-Doped C-x composites with core–shell structures with different void sizes were obtained by means of Fe3O4 etching. The effect of the etching time on the void size was studied. The electrochemical properties of the composites when used as lithium-ion battery materials were studied in more detail. The results showed that the sample that was obtained via etching for 5 h using 2 mol L−1 HCl solution at 30 °C demonstrated better electrochemical performance. The discharge capacity of the Fe3O4@void@N-Doped C-5 was able to reach up to 1222 mA g h−1 under 200 mA g−1 after 100 cycles.

A Simple and Low‐Cost Method to Synthesize Cr‐Doped α‐Fe 2 O 3 Electrode Materials for Lithium‐Ion Batteries

2019 ◽  
Vol 6 (3) ◽  
pp. 856-864 ◽  
Author(s):  
Huan Liu ◽  
Shao‐hua Luo ◽  
Dong‐xu Zhang ◽  
Dong‐bei Hu ◽  
Ting‐Feng Yi ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Electrode Materials ◽  
Low Cost ◽  
Lithium Ion

Hollow core-shell structured Si@NiAl-LDH composite as high-performance anode material in lithium-ion batteries

2020 ◽  
Vol 331 ◽  
pp. 135331 ◽  
Author(s):  
Qiongguang Li ◽  
Yanhong Wang ◽  
Bin Lu ◽  
Jing Yu ◽  
Menglei Yuan ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Material ◽  
High Performance ◽  
Lithium Ion ◽  
Core Shell ◽  
Hollow Core

Fracture and debonding in lithium-ion batteries with electrodes of hollow core–shell nanostructures

2012 ◽  
Vol 218 ◽  
pp. 6-14 ◽  
Author(s):  
Kejie Zhao ◽  
Matt Pharr ◽  
Lauren Hartle ◽  
Joost J. Vlassak ◽  
Zhigang Suo
Keyword(s):  
Lithium Ion Batteries ◽  
Lithium Ion ◽  
Core Shell ◽  
Hollow Core ◽  
Shell Nanostructures

Hollow core–shell structured Si/C nanocomposites as high-performance anode materials for lithium-ion batteries

Nanoscale ◽  
2014 ◽  
Vol 6 (6) ◽  
pp. 3138-3142 ◽  
Author(s):  
Huachao Tao ◽  
Li-Zhen Fan ◽  
Wei-Li Song ◽  
Mao Wu ◽  
Xinbo He ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Materials ◽  
High Performance ◽  
Lithium Ion ◽  
Core Shell ◽  
Discharge Process ◽  
Hollow Core ◽  
A Charge ◽  
Large Volume Change ◽  
Charge Discharge

Hollow core–shell structured Si/C nanocomposites were prepared to adapt for the large volume change during a charge–discharge process.

Synthesis and Application of Carbon-Based Nanocomposites

2013 ◽  
Vol 345 ◽  
pp. 172-175
Author(s):  
Shi Jun Yu ◽  
Xu Han ◽  
Da Wei Yu ◽  
Yan Ming Chen ◽  
Xiao Li Wang
Keyword(s):  
Lithium Ion Batteries ◽  
Electrode Materials ◽  
Lithium Ion ◽  
High Volume ◽  
High Energy ◽  
High Energy Density ◽  
Cycle Performance ◽  
Active Metal ◽  
Electrochemically Active ◽  
Carbon Coated

Lithium ion batteries have been considered as the most effective and practical technologies for electrochemical energy storage. To meet the demand for lithium ion batteries with high energy density and excellent cycle performance, numerous efforts have been devoted to the development of new electrode materials. Electrochemically active metal oxides have emerged as the most promising candidates for the anode materials in the next generation lithium ion batteries duo to their high theoretical capacities and natural abundance. However, the extremely high volume change induced by the alloying reaction with lithium in the bottleneck for the commercialization of these materials. To overcome these obstacles, carbonaceous materials are commonly introduced as matrices to absorb the volume changes and improve the structural stability of the electrode materials. Hence, the present article describes the synthetic pathway of carbon-coated nanomaterials and applications.

Facile synthesis of CuO nanoparticles as anode for lithium ion batteries with enhanced performance

2014 ◽  
Vol 07 (06) ◽  
pp. 1440008 ◽  
Author(s):  
Linlin Wang ◽  
Kaibin Tang ◽  
Min Zhang ◽  
Xiaozhu Zhang ◽  
Jingli Xu
Keyword(s):  
Lithium Ion Batteries ◽  
Large Scale ◽  
Low Cost ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Cuo Nanoparticles ◽  
Cycle Performance ◽  
Scale Production ◽  
Large Scale Production ◽  
Average Size

Particle size effects on the electrochemical performance of the CuO particles toward lithium are essential. In this work, a low-cost, large-scale production but simple approach has been developed to fabricate CuO nanoparticles with an average size in ~ 130 nm through thermolysis of Cu ( OH )2 precursors. As anode materials for lithium ion batteries (LIBs), the CuO nanoparticles deliver a high reversible capacity of 540 mAh g-1 over 100 cycles at 0.5 C. It also exhibits a rate capacity of 405 mAh g-1 at 2 C. These results suggest that the facile synthetic method of producing the CuO nanoparticles can enhance cycle performance, superior to that of some different sizes of the CuO nanoparticles and many reported CuO -based anodes.

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