scholarly journals Multiple Energy Transfer in Luminescence-Tunable Single-Phased Phosphor NaGdTiO4: Tm3+, Dy3+, Sm3+

Nanomaterials ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 1249 ◽  
Author(s):  
Jun Xiao ◽  
Cong Wang ◽  
Xin Min ◽  
Xiaowen Wu ◽  
Yangai Liu ◽  
...  

Advances in solid-state white-light-emitting diodes (WLEDs) necessitate the urgent development of highly efficient single-phase phosphors with tunable photoluminescence properties. Herein, the Tm3+, Dy3+, and Sm3+ ions are incorporated into the orthorhombic NaGdTiO4 (NGT) phosphors, resulting in phosphors that fulfill the aforementioned requirement. The emission spectrum of Tm3+ ions overlaps well with the adsorption spectra of both Dy3+ and Sm3+ ions. Under the excitation at 358 nm, the single-phase NaGdTiO4: Tm3+, Dy3+, Sm3+ phosphor exhibits tunable emission peaks in the blue, yellow, and red regions simultaneously, resulting in an intense white-light emission. The coexisting energy transfer behaviors from Tm3+ to Dy3+ and Sm3+ ions and the energy transfer from Dy3+ to Sm3+ ions are demonstrated to be responsible for this phenomenon. The phosphors with multiple energy transfers enable the development of single-phase white-light-emitting phosphors for phosphor-converted WLEDs.

RSC Advances ◽  
2015 ◽  
Vol 5 (117) ◽  
pp. 96272-96280 ◽  
Author(s):  
Yang Zhang ◽  
Weitao Gong ◽  
Jingjie Yu ◽  
Yuan Lin ◽  
Guiling Ning

Novel single-phase white-light-emitting phosphors have been successfully synthesized by a solid-state reaction and their photoluminescence properties and energy transfer mechanism have been carefully investigated.


2019 ◽  
Vol 7 (10) ◽  
pp. 2927-2935 ◽  
Author(s):  
Mao Xia ◽  
Xianbo Wu ◽  
Yuan Zhong ◽  
H. T. (Bert) Hintzen ◽  
Zhi Zhou ◽  
...  

Energy transfer from Tb3+ to Eu3+ was observed and verified in a warm white light emission phosphor SZYP:Tb3+,Eu3+ with high thermal stability.


RSC Advances ◽  
2015 ◽  
Vol 5 (77) ◽  
pp. 62527-62533 ◽  
Author(s):  
Yang Zhang ◽  
Weitao Gong ◽  
Jingjie Yu ◽  
Hongchang Pang ◽  
Qiang Song ◽  
...  

A new single-phase white-emitting CaWO4:Dy3+ phosphor has been successfully synthesized and the photoluminescence properties and energy-transfer mechanism have been carefully investigated.


RSC Advances ◽  
2017 ◽  
Vol 7 (65) ◽  
pp. 41282-41288 ◽  
Author(s):  
Hongwei Xu ◽  
Lili Wang ◽  
Dan Qu ◽  
Zhiyun Si ◽  
Jinsheng Shi

A series of Sr6Ca4(PO4)6F2:Eu2+,Mn2+ phosphors were synthesized by traditional solid state reaction. Through controlling the ratio of Eu2+ and Mn2+, emission colors can be tuned from blue to yellow, including white-light-emitting.


2015 ◽  
Vol 3 (27) ◽  
pp. 7096-7104 ◽  
Author(s):  
Kai Li ◽  
Mengmeng Shang ◽  
Yang Zhang ◽  
Jian Fan ◽  
Hongzhou Lian ◽  
...  

A series of Ca9Bi(PO4)7:Ce3+,Tb3+,Mn2+phosphors synthesizedviathe high-temperature solid-state reaction method can emit intense tunable color from purple-blue to red including white under UV excitation, which shows their potential application in UV-pumped white-light-emitting diodes.


2016 ◽  
Vol 30 (25) ◽  
pp. 1650179
Author(s):  
S. T. Taide ◽  
N. B. Ingle ◽  
S. K. Omanwar

Rare-earth (RE) activated (Dy[Formula: see text]/Sm[Formula: see text] and Ce[Formula: see text]/Tb[Formula: see text]) polycrystalline CaSO4 phosphors were prepared by co-precipitation method. Powder XRD pattern confirmed their structure and phase, while FE-SEM investigation reflected the particle morphology. The optical absorption and emission analysis were carried out to find efficient energy transfer within codoped phosphors, a possible energy transfer mechanism was discussed and energy transfer efficiencies were calculated. The multicolor emission from these materials suggests sustainable and well-defined approach towards possibility of obtaining tunable emission for producing while light emission, which finds potential applications in field emission display (FED) and white light-emitting diodes (W-LEDs).


2018 ◽  
Vol 32 (04) ◽  
pp. 1850047 ◽  
Author(s):  
Jianlin Zhong ◽  
Lixin Yu ◽  
Songchu Li ◽  
Xiaoqin Man ◽  
Wei Sun

The BaZr[Formula: see text]Si2O[Formula: see text]: Eu[Formula: see text]/Eu[Formula: see text] phosphors were prepared with different concentrations of Eu2O3 by a self-reduction method under air condition. The X-ray diffraction and the photoluminescence properties of the prepared samples were analyzed. The emission spectra consisting of a broadband emission from the 4f[Formula: see text]5d transitions of Eu[Formula: see text] and sharp emissions from 5D0-7F[Formula: see text] (J = 0, 1, 2, 3, 4) transitions of Eu[Formula: see text] are observed. The different luminescent colors can be obtained and modulated by doping different concentrations of Eu2O3 and the white light emission can be observed as the concentration of europium is 6%.


2014 ◽  
Vol 633-634 ◽  
pp. 306-309 ◽  
Author(s):  
Jia Yue Sun ◽  
Liu Han ◽  
Qiu Mei Di ◽  
Qi Guang Xu

Novel Na3YSi2O7: Sm3+, Eu3+phosphors for white light-emitting diodes were prepared by high-temperature solid-state reaction. The photoluminescence excitation and emission spectra, energy transfer from Eu2+to Tb3+are investigated in detail. The current research suggests that Na3YSi2O7: Sm3+, Eu3+phosphor is a potential candidate for application in Phosphor-converted LEDs.


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