scholarly journals Amino Functionalization of Reduced Graphene Oxide/Tungsten Disulfide Hybrids and Their Bismaleimide Composites with Enhanced Mechanical Properties

Polymers ◽  
2018 ◽  
Vol 10 (11) ◽  
pp. 1199 ◽  
Author(s):  
Liulong Guo ◽  
Hongxia Yan ◽  
Zhengyan Chen ◽  
Qi Liu ◽  
Yuanbo Feng ◽  
...  

A novel graphene-based nanocomposite particles (NH2-rGO/WS2), composed of reduced graphene oxide (rGO) and tungsten disulfide (WS2) grafted with active amino groups (NH2-rGO/WS2), was successfully synthesized by an effective and facile method. NH2-rGO/WS2 nanoparticles were then used to fabricate new bismaleimide (BMI) composites (NH2-rGO/WS2/BMI) via a casting method. The results demonstrated that a suitable amount of NH2-rGO/WS2 nanoparticles significantly improved the mechanical properties of the BMI resin. When the loading of NH2-rGO/WS2 was only 0.6 wt %, the impact and flexural strength of the composites increased by 91.3% and 62.6%, respectively, compared to the neat BMI resin. Rare studies have reported such tremendous enhancements on the mechanical properties of the BMI resin with trace amounts of fillers. This is attributable to the unique layered structure of NH2-rGO/WS2 nanoparticles, fine interfacial adhesion, and uniform dispersion of NH2-rGO/WS2 in the BMI resin. Besides, the thermal gravimetrical analysis (TGA) revealed that the addition of NH2-rGO/WS2 could also improve the stability of the composites.

2020 ◽  
Vol 2020 ◽  
pp. 1-9 ◽  
Author(s):  
Tomasz Rydzkowski ◽  
Kazimierz Reszka ◽  
Mieczysław Szczypiński ◽  
Michał Marek Szczypiński ◽  
Elżbieta Kopczyńska ◽  
...  

The aim of the present study is to examine the effect of the addition of carbon nanoparticles (σsp2 hybridization) on the mechanical properties of foamed polystyrene. In this work, we focus on the study of the impact of compressive stress, tensile strength, bending strength, thermal conductivity ratio (λ), and water absorption of expanded polystyrene (EPS) reinforced with reduced graphene oxide and graphite. The results were compared with pristine EPS and reduced graphene oxide-reinforced EPS. All the nanocomposite specimens used for testing had a similar density. The study reveals that the nanocomposites exhibit different thermal conductivities and mechanical properties in comparison to pristine EPS. The enhancement in the properties of the nanocomposite could be associated with a more extensive structure of elementary cells of expanded polystyrene granules.


ACS Nano ◽  
2013 ◽  
Vol 7 (2) ◽  
pp. 1638-1645 ◽  
Author(s):  
Priyank V. Kumar ◽  
Marco Bernardi ◽  
Jeffrey C. Grossman

2019 ◽  
Vol 163 ◽  
pp. 77-85 ◽  
Author(s):  
Faisal Nazeer ◽  
Zhuang Ma ◽  
Lihong Gao ◽  
Fuchi Wang ◽  
Muhammad Abubaker Khan ◽  
...  

2018 ◽  
Vol 33 (1) ◽  
pp. 85-96
Author(s):  
Thangamani Rajkumar ◽  
Nagamuthu Muthupandiyan ◽  
Chinnaswamy Thangavel Vijayakumar

Reduced graphene oxide (RGEO) and N-[4-(chlorocarbonyl)phenyl]maleimide-functionalized reduced graphene oxide (MFRGEO) were used as nanofillers for polymethyl methacrylate (PMMA) matrix nanocomposites to enhance thermal stability. Methyl methacrylate containing nanofiller of four different weight percent (0.2, 0.4, 0.6, and 0.8) was polymerized using ultrasonic radiation-assisted bulk polymerization. The Fourier-transform infrared spectra showed the absence of chemical interaction between the filler and the matrix phase. Morphology of nanocomposites studied using scanning electron microscope confirmed the assistance aided by ultrasonication in the uniform dispersion of nanofiller in the PMMA matrix. Thermogravimetric (TG) study revealed the presence of MFRGEO enhanced the thermal stability of PMMA by shifting the entire degradation to higher temperature. The thermal stability of PMMA nanocomposite was improved by as much as 40°C at just 0.8 wt% loading of MFRGEO. Differential TG study also supported the role of maleimide functionalization on RGEO in the enhancement of thermal stability of PMMA by means of retarding the degradation rate of unsaturated chain ends in the PMMA matrix. Unlike MFRGEO, RGEO failed to enhance the thermal stability of PMMA.


2018 ◽  
Vol 136 (10) ◽  
pp. 47164 ◽  
Author(s):  
Xin Zhang ◽  
Yahui Ma ◽  
Yingjin Pei ◽  
Shuojin Zheng ◽  
Qinghong Fang ◽  
...  

RSC Advances ◽  
2017 ◽  
Vol 7 (52) ◽  
pp. 32731-32731 ◽  
Author(s):  
Santosh Kr. Tiwari ◽  
Kartikey Verma ◽  
Pupulata Saren ◽  
Ramesh Oraon ◽  
Amrita De Adhikari ◽  
...  

Correction for ‘Manipulating selective dispersion of reduced graphene oxide in polycarbonate/nylon 66 based blend nanocomposites for improved thermo-mechanical properties’ by Santosh Kr. Tiwari et al., RSC Adv., 2017, 7, 22145–22155.


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