scholarly journals Comparison of In-Situ Chlorophyll-a Time Series and Sentinel-3 Ocean and Land Color Instrument Data in Slovenian National Waters (Gulf of Trieste, Adriatic Sea)

Water ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 1903
Author(s):  
El Khalil Cherif ◽  
Patricija Mozetič ◽  
Janja Francé ◽  
Vesna Flander-Putrle ◽  
Jana Faganeli-Pucer ◽  
...  

While satellite remote sensing of ocean color is a viable tool for estimating large-scale patterns of chlorophyll-a (Chl-a) and global ocean primary production, its application in coastal waters is limited by the complex optical properties. An exploratory study was conducted in the Gulf of Trieste (Adriatic Sea) to assess the usefulness of Sentinel-3 satellite data in the Slovenian national waters. OLCI (Ocean and Land Colour Instrument) Chl-a level 2 products (OC4Me and NN) were compared to monthly Chl-a in-situ measurements at fixed sites from 2017 to 2019. In addition, eight other methods for estimating Chl-a concentration based on reflectance in different spectral bands were tested (OC3M, OC4E, MedOC4, ADOC4, AD4, 3B-OLCI, 2B-OLCI and G2B). For some of these methods, calibration was performed on in-situ data to achieve a better agreement. Finally, L1-regularized regression and random forest were trained on the available dataset to test the capabilities of the machine learning approach. The results show rather poor performance of the two originally available products. The same is true for the other eight methods and the fits to the measured values also show only marginal improvement. The best results are obtained with the blue-green methods (OC3, OC4 and AD4), especially the AD4SI (a designated fit of AD4) with R = 0.56 and RMSE = 0.4 mg/m³, while the near infrared (NIR) methods show underwhelming performance. The machine learning approach can only explain 30% of the variability and the RMSE is of the same order as for the blue-green methods. We conclude that due to the low Chl-a concentration and the moderate turbidity of the seawater, the reflectance provided by the Sentinel-3 OLCI spectrometer carries little information about Chl-a in the Slovenian national waters within the Gulf of Trieste and is therefore of limited use for our purposes. This requires that we continue to improve satellite products for use in those marine waters that have not yet proven suitable. In this way, satellite data could be effectively integrated into a comprehensive network that would allow a reliable assessment of ecological status, taking into account environmental regulations.

2020 ◽  
Vol 248 ◽  
pp. 111974
Author(s):  
Zhigang Cao ◽  
Ronghua Ma ◽  
Hongtao Duan ◽  
Nima Pahlevan ◽  
John Melack ◽  
...  

2021 ◽  
Vol 42 (19) ◽  
pp. 7381-7404
Author(s):  
Hamid Mohebzadeh ◽  
Esmaiil Mokari ◽  
Prasad Daggupati ◽  
Asim Biswas

2021 ◽  
Author(s):  
Urmi Ghosh ◽  
Tuhin Chakraborty

<p>Rapid technological improvements made in in-situ analysis techniques, including LA-ICPMS, have transformed the field of analytical geochemistry. This has a far-reaching impact for different petrogenetic and ore-genetic studies where minute major and trace element compositional changes between different mineral zones within a single crystal can now be demarcated. Minerals such as garnet although robust are quite sensitive to the changing P-T and fluid conditions during their formation. These minerals have become powerful tools to characterize mineralization types. Previously, Meinert (1992) has used in-situ major element EPMA analysis results to classify different skarn deposit based on the end-member composition of hydrothermal garnets. Alternatively, Tian et al. (2019) used the garnet trace element composition for the similar purpose. However, these discrimination plots/ classification schemes show major overlap in different skarn deposits, such as Fe, Cu, Zn, and Au. The present study is an attempt to use machine learning approach on available garnet data to found a more potent classification scheme for skarn deposits, thus reaffirming garnet as a faithful indicator for hydrothermal ore deposits. We have meticulously collected major and trace element data of Ca-rich garnets, associated with different skarn deposits worldwide from 40 publications. This collected data is then used to train a model for fingerprinting the skarn deposits. Stratified random sampling method has been used on the dataset with 80% of the samples as test set and the rest 20 % as training dataset. We have used K-nearest neighbour (KNN), Support Vector Machine (SVM) and Random Forest algorithms on the data by using Python as a platform. These ML classification algorithm performs better than the earlier existing models available for classification of ore types based on garnet composition in skarn system. Factor importance is calculated that shows which elements play a pivotal role in classification of the ore type. Our results depict that multiple garnet forming elements taken together can reliably be used to discriminate between different ore formation settings.</p>


2021 ◽  
Vol 13 (5) ◽  
pp. 969
Author(s):  
Ka Lok Chan ◽  
Ehsan Khorsandi ◽  
Song Liu ◽  
Frank Baier ◽  
Pieter Valks

In this paper, we present the estimation of surface NO2 concentrations over Germany using a machine learning approach. TROPOMI satellite observations of tropospheric NO2 vertical column densities (VCDs) and several meteorological parameters are used to train the neural network model for the prediction of surface NO2 concentrations. The neural network model is validated against ground-based in situ air quality monitoring network measurements and regional chemical transport model (CTM) simulations. Neural network estimation of surface NO2 concentrations show good agreement with in situ monitor data with Pearson correlation coefficient (R) of 0.80. The results also show that the machine learning approach is performing better than regional CTM simulations in predicting surface NO2 concentrations. We also performed a sensitivity analysis for each input parameter of the neural network model. The validated neural network model is then used to estimate surface NO2 concentrations over Germany from 2018 to 2020. Estimated surface NO2 concentrations are used to investigate the spatio-temporal characteristics, such as seasonal and weekly variations of NO2 in Germany. The estimated surface NO2 concentrations provide comprehensive information of NO2 spatial distribution which is very useful for exposure estimation. We estimated the annual average NO2 exposure for 2018, 2019 and 2020 is 15.53, 15.24 and 13.27 µµg/m3, respectively. While the annual average NO2 concentration of 2018, 2019 and 2020 is only 12.79, 12.60 and 11.15 µµg/m3. In addition, we used the surface NO2 data set to investigate the impacts of the coronavirus disease 2019 (COVID-19) pandemic on ambient NO2 levels in Germany. In general, 10–30% lower surface NO2 concentrations are observed in 2020 compared to 2018 and 2019, indicating the significant impacts of a series of restriction measures to reduce the spread of the virus.


2019 ◽  
Vol 11 (6) ◽  
pp. 617 ◽  
Author(s):  
Sidrah Hafeez ◽  
Man Wong ◽  
Hung Ho ◽  
Majid Nazeer ◽  
Janet Nichol ◽  
...  

Anthropogenic activities in coastal regions are endangering marine ecosystems. Coastal waters classified as case-II waters are especially complex due to the presence of different constituents. Recent advances in remote sensing technology have enabled to capture the spatiotemporal variability of the constituents in coastal waters. The present study evaluates the potential of remote sensing using machine learning techniques, for improving water quality estimation over the coastal waters of Hong Kong. Concentrations of suspended solids (SS), chlorophyll-a (Chl-a), and turbidity were estimated with several machine learning techniques including Artificial Neural Network (ANN), Random Forest (RF), Cubist regression (CB), and Support Vector Regression (SVR). Landsat (5,7,8) reflectance data were compared with in situ reflectance data to evaluate the performance of machine learning models. The highest accuracies of the water quality indicators were achieved by ANN for both, in situ reflectance data (89%-Chl-a, 93%-SS, and 82%-turbidity) and satellite data (91%-Chl-a, 92%-SS, and 85%-turbidity. The water quality parameters retrieved by the ANN model was further compared to those retrieved by “standard Case-2 Regional/Coast Colour” (C2RCC) processing chain model C2RCC-Nets. The root mean square errors (RMSEs) for estimating SS and Chl-a were 3.3 mg/L and 2.7 µg/L, respectively, using ANN, whereas RMSEs were 12.7 mg/L and 12.9 µg/L for suspended particulate matter (SPM) and Chl-a concentrations, respectively, when C2RCC was applied on Landsat-8 data. Relative variable importance was also conducted to investigate the consistency between in situ reflectance data and satellite data, and results show that both datasets are similar. The red band (wavelength ≈ 0.665 µm) and the product of red and green band (wavelength ≈ 0.560 µm) were influential inputs in both reflectance data sets for estimating SS and turbidity, and the ratio between red and blue band (wavelength ≈ 0.490 µm) as well as the ratio between infrared (wavelength ≈ 0.865 µm) and blue band and green band proved to be more useful for the estimation of Chl-a concentration, due to their sensitivity to high turbidity in the coastal waters. The results indicate that the NN based machine learning approaches perform better and, thus, can be used for improved water quality monitoring with satellite data in optically complex coastal waters.


Electronics ◽  
2021 ◽  
Vol 10 (23) ◽  
pp. 3004
Author(s):  
Antonia Ivanda ◽  
Ljiljana Šerić ◽  
Marin Bugarić ◽  
Maja Braović

In this paper, we describe a method for the prediction of concentration of chlorophyll-a (Chl-a) from satellite data in the coastal waters of Kaštela Bay and the Brač Channel (our case study areas) in the Republic of Croatia. Chl-a is one of the parameters that indicates water quality and that can be measured by in situ measurements or approximated as an optical parameter with remote sensing. Remote sensing products for monitoring Chl-a are mostly based on the ocean and open sea monitoring and are not accurate for coastal waters. In this paper, we propose a method for remote sensing monitoring that is locally tailored to suit the focused area. This method is based on a data set constructed by merging Sentinel 2 Level-2A satellite data with in situ Chl-a measurements. We augmented the data set horizontally by transforming the original feature set, and vertically by adding synthesized zero measurements for locations without Chl-a. By transforming features, we were able to achieve a sophisticated model that predicts Chl-a from combinations of features representing transformed bands. Multiple Linear Regression equation was derived to calculate Chl-a concentration and evaluated quantitatively and qualitatively. Quantitative evaluation resulted in R2 scores 0.685 and 0.659 for train and test part of data set, respectively. A map of Chl-a of the case study area was generated with our model for the dates of the known incidents of algae blooms. The results that we obtained are discussed in this paper.


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