<p>Groundwater dynamics and flow directions in the near-stream zone depend on groundwater gradients, are highly dynamic in space and time, and reflect the flowpaths between stream channel and groundwater. A wide variety of studies have addressed groundwater flow and changes of flow direction in the near-stream domain which, however, have obtained contrasting results on the drivers and hydrologic conditions of water exchange between stream channel and near-stream groundwater. Here, we investigate groundwater dynamics and flow direction in the stream corridor through a spatially dense groundwater monitoring network over a period of 18 months, addressing the following research questions:</p><ul><li>How and why does groundwater table response vary between precipitation events across different hydrological states in the near-stream domain?</li>
<li>How and why does groundwater flow direction in the near-stream domain change across different hydrological conditions?</li>
</ul><p>Our results show a large spatio-temporal variability in groundwater table dynamics. During the progression from dry to wet hydrologic conditions, we observe an increase in precipitation depths required to trigger groundwater response and an increase in the timing of groundwater response (i.e. the lag-time between the onset of a precipitation event and groundwater rise). This behaviour can be explained by the subsurface structure with solum, subsolum, and fractured bedrock showing decreasing storage capacity with depth. A Spearman rank (r<sub>s</sub>) correlation analysis reveals a lack of significant correlation between the observed minimum precipitation depth needed to trigger groundwater response with the local thickness of the subsurface layer, as well as with the distance from and the elevation above the stream channel. However, both the increase in groundwater level &#160;and the timing of the groundwater response are positively correlated with the thickness of the solum and subsolum layers and with the distance and the elevation from the stream channel, but only during wet conditions. These results suggest that during wet conditions the spatial differences in the groundwater dynamics are mostly controlled by the regolith depth above the fractured bedrock. However, during dry conditions, local changes in the storage capacities of the fractured bedrock or the presence of preferential flowpaths in the fractured schist matrix could control the spatially heterogeneous timing of groundwater response. In the winter months, the groundwater flow direction points mostly toward the stream channel also many days after an event, suggesting that the groundwater flow from upslope locations controls the near-stream groundwater movement toward the stream channel during wet hydrologic conditions. However, during dry-out or long recessions, the groundwater table at the footslopes decreases to the stream level or below. In these conditions, the groundwater fall lines point toward the footslopes both in the summer and in the winter and in different sections of the stream reach. This study highlights the effect of different initial conditions, precipitation characteristics, streamflow, and potential water inflow from hillslopes on groundwater dynamics and groundwater surface-water exchange in the near stream domain.</p>
Hydrogeochemical Evolution of an Aquifer Regulated by Pyrite Oxidation and Organic Sediments
