scholarly journals Occurrence and Distribution of Polycyclic Aromatic Hydrocarbons in the Marine Surface Microlayer of an Industrialized Coastal Area in the Eastern Mediterranean

Water ◽  
2021 ◽  
Vol 13 (22) ◽  
pp. 3174
Author(s):  
Aikaterini Sakellari ◽  
Sotirios Karavoltsos ◽  
Ipek Moutafis ◽  
Konstantinos Koukoulakis ◽  
Manos Dassenakis ◽  
...  

Concentrations of dissolved and particulate polycyclic aromatic hydrocarbons (PAHs) were determined seasonally in sea surface microlayer (SML) and sub-surface water (SSW) within the Saronicos Gulf, Greece, close to a highly industrialized coastal zone. For the 16 US EPA priority PAHs, the sum of dissolved PAHs (∑dPAHs) concentrations ranged from 40.4 to 237 ng L−1 in SML, 22.8–180 ng L−1 in SSW0.2, whereas the corresponding concentrations in suspended particulate matter (∑pPAHs) were 30.8 to 177 ng L−1 and 36.8–171 ng L−1, respectively. The enrichment factor (EF) for dissolved ∑dPAHs varied from 0.9 to 2.1 with a mean value of 1.5 (n = 10) being statistically significantly greater than unity, whereas for particulate ∑pPAHs, no enrichment of the SML was reported. Enrichment factors of 5–6 ring PAHs were higher near the industrial zone. The possible sources, fate, and toxicity of PAHs are also discussed.

2012 ◽  
Vol 2012 ◽  
pp. 1-10 ◽  
Author(s):  
Anita Lakhani

16 US EPA priority polycyclic aromatic hydrocarbons (PAHs) were quantified in total suspended ambient particulate matter (TSPM) collected from an industrial site in Agra (India) using gas chromatography. The major industrial activities in Agra are foundries that previously used coal and coke as fuel in cupola furnaces. These foundries have now switched over to natural gas. In addition, use of compressed natural gas has also been promoted and encouraged in automobiles. This study attempts to apportion sources of PAH in the ambient air and the results reflect the advantages associated with the change of fuel. The predominant PAHs in TSPM include high molecular weight (HMW) congeners BghiP, DbA, IP, and BaP. The sum of 16 priority PAHs had a mean value of 72.7 ± 4.7 ng m−3. Potential sources of PAHs in aerosols were identified using diagnostic ratios and principal component analysis. The results reflect a blend of emissions from diesel and natural gas as the major sources of PAH in the city along with contribution from emission of coal, coke, and gasoline.


2012 ◽  
Vol 9 (12) ◽  
pp. 19165-19197 ◽  
Author(s):  
C. Theodosi ◽  
C. Parinos ◽  
A. Gogou ◽  
A. Kokotos ◽  
S. Stavrakakis ◽  
...  

Abstract. To assess sources and major processes controlling vertical transport of both anthropogenic and natural chemical species in deep basins of the Eastern Mediterranean Sea (SE Ionian Sea, Nestor site), we performed chemical characterization (elemental carbon, major and trace metals and polycyclic aromatic hydrocarbons) of marine sinking particles. Sediment traps were deployed at five successive depths, 700 m, 1200 m, 2000 m, 3200 m and 4300 m from the sea surface, during the period of May 2007 to October 2008. Fluxes of all measured species exhibited minimum values from January to March 2008 and maximum from April to September 2008, with an evident covariance revealing a common and rapid vertical transport mechanism from 700 m down to 4300 m depth. Crustal matter flux from atmospheric deposition plays an important role in the temporal variability of particulate matter with significant contribution from biogenic constituents namely the seasonal succession in the export of planktonic biomass, expressed by particulate organic carbon (POC), carbonates and biogenic Si fluxes (Stavrakakis et al., 2012). Tracers (elemental carbon, retene) of the devastating forest fires occurred in August 2007 in southern Greece, were detected at sediment trap material in all depths with a delay of 15 days at 4300 m, indicating a rapid and well-coupled transport of sinking particulate material between the sea-surface and deep layers of the Eastern Mediterranean Sea. Lateral inputs of pollutants at the deepest trap (4300 m) are probably of importance, due to the influence of deep Adriatic water at the study site.


2007 ◽  
Vol 54 (2) ◽  
pp. 186-194 ◽  
Author(s):  
Carlos Guitart ◽  
Nuria García-Flor ◽  
Josep M. Bayona ◽  
Joan Albaigés

Microbiology ◽  
2020 ◽  
Vol 89 (5) ◽  
pp. 609-615
Author(s):  
A. D. Galachyants ◽  
M. Yu. Suslova ◽  
I. I. Marinayte ◽  
O. N. Izosimova ◽  
A. Yu. Krasnopeev ◽  
...  

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