The Gas and Aerosol Phase Composition of Smoke Plumes From The 2019-2020 Black Summer Bushfires and Potential Implications For Human Health

The 2019-2020 Australian bushfire season was historically large, long, and intense. Smoke from fires burning in southeast Australia blanketed population centres for weeks to months. This study reports the chemical composition in the gas and aerosol phase of aged plumes measured near Wollongong, NSW in early 2020. Enhancement ratios to CO are presented for thirteen species. Plume composition is largely similar to that measured in fresh smoke during previous studies. It is hoped enhancement ratios reported here will assist in plume modelling of landscape scale fires and allow concentration estimates of infrequently measured atmospheric pollutants at monitoring stations. The relative toxicological contribution of species present in the plumes was determined for dilute plume exposure at the measurement site and for concentrated plumes at a heavily impacted population centre case study location. Similar results were determined for both sites. Respirable particles, formaldehyde and acrolein were found to contribute significantly to the toxicological loading, with respirable particles contributing approximately half of the loading. This is a reminder to consider not only the toxicological contributions of particles when studying health impacts of bushfire smoke exposure.

Exposure to Ultrafine Particles in the Ferroalloy Industry Using a Logbook Method

Background: It is difficult to assess workers’ exposure to ultrafine particles (UFP) due to the lack of personal sampling equipment available for this particle fraction. The logbook method has been proposed as a general method for exposure assessment. This method measures the time and concentration components of the time-weighted average concentration separately and could be suitable for investigation of UFP exposure. Objectives: In this study, we have assessed workers’ exposure to UFP in a ferrosilicon plant. The main tasks of the furnace workers were identified, and the logbook method was used in combination with stationary measurements of UFP taken as close to the identified task areas as possible. In order to verify the results, respirable particles were collected using stationary sampling in close proximity to the UFP measuring instrument, and personal full-shift sampling of respirable particles was performed simultaneously. Thus, exposure to respirable particles determined using the logbook method could be compared to the results of standard measurement. Methods: The particle number concentration of ultrafine particles was determined using a NanoScan SMPS. Respirable particle concentration and exposure were determined using a sampling train consisting of a pump, filter, filter cassettes, and SKC Cyclone for the respirable fraction. Attendance times for workers at each work location were registered via thorough observations made by the research team. Results: The logbook method for exposure estimation based on stationary sampling equipment made it possible to calculate UFP exposure for workers operating the furnaces at a ferrosilicon plant. The mid-size furnace and the large furnace were evaluated separately. The workers operating the largest furnace were exposed to 1.47 × 104 particles/cm3, while workers operating the mid-size furnace were exposed to 2.06 × 104 particles/cm3, with a mean of 1.74 × 104 particles/cm3. Substantial contributions from the casting area, ladle transport corridor, and both tapping areas were made. Exposure to respirable particles was 2.04 mg/m3 (logbook); 2.26 mg/m3 (personal sampling) for workers operating the large-sized furnace, 3.24 mg/m3 (logbook); 2.44 mg/m3 (personal sampling) for workers operating the medium-sized furnace, and 2.57 mg/m3 (logbook); 2.53 mg/m3(personal sampling) on average of all tappers. The average ratio of these two methods’ results was 1.02, which indicates that the logbook method could be used as a substitute for personal sampling when it is not possible to perform personal sampling, at least within this industry. Conclusions: The logbook method is a useful supplement for exposure assessment of UFP, able to identify the most polluted areas of the workplace and the contribution of different work tasks to the total exposure of workers, enabling companies to take action to reduce exposure.

Evaluation of Sub-micrometer-Sized Particles Generated from a Diesel Locomotive and Jackleg Drilling in an Underground Metal Mine

Concerns have been raised regarding small respirable particles, i.e. sub-micrometer-sized particles, associated with mining activities. This evaluation was designed to investigate the emissions from jackleg drilling and diesel engines and to characterize the nature of emitted particles using gravimetric analysis and number metrics. The mass concentration to which workers are potentially exposed was determined from a 4-h sampling in the vicinity of drilling activities in an underground metal mine; this concentration was found to be lower than 0.6 mg m−3 of total respirable dust. This mass concentration is low; however, the number concentrations of emitted particles from drilling exceeded 1 × 106 particles cm−3 in areas 7–9 m downwind from the drilling operation. Sub-micrometer-sized particles were also observed in aerosol samples collected using a specialized sampler, and various elements associated with drilling were found among these emitted particles. Finally, the particles in the diesel exhaust were collected, and the exhaust was found to contain nanometer-sized particles.

In vitro toxicity assessment of respirable solid surface composite sawing particles

Solid surface composites (SSCs) are a class of popular construction materials composed of aluminum trihydrate and acrylic polymers. Previous investigations have demonstrated that sawing SSC releases substantial airborne dusts, with a number-based geometric mean diameter of 1.05 µm. We reported that in mice, aspiration exposure to airborne SSC dusts induced symptoms of pulmonary inflammation at 24-h postexposure: neutrophilic influx, alveolitis, and increased lactate dehydrogenase (LDH) and pro-inflammatory cytokine levels in lavage fluid. The particles appeared to be poorly cleared, with 81% remaining at 14-day postexposure. The objective of this study was to determine the toxicity specifically of respirable particles on a model of human alveolar macrophages (THP-1). The relative toxicities of subfractions (0.07, 0.66, 1.58, 5.0, and 13.42 µm diameter) of the airborne particles were also determined. THP-1 macrophages were exposed for 24 h to respirable particles from sawing SSC (0, 12.5, 25, 50, or 100 µg/ml) or size-specific fractions (100 µg/ml). Exposure to respirable SSC particles induced THP-1 macrophage toxicity in a dose-dependent manner. Viability was decreased by 15% and 19% after exposure to 50 and 100 µg/ml SSC, respectively, which correlated with increased cell culture supernatant LDH activity by 40% and 70% when compared to control. Reactive oxygen species (ROS) production and inflammatory cytokines were increased in a dose-dependent manner. A size-dependent cytotoxic effect was observed in the cells exposed to subfractions of SSC particles. SSC particles of 0.07, 0.66, and 1.58 µm diameter killed 36%, 17%, and 22% of cells, respectively. These results indicate a potential for cytotoxicity of respirable SSC particles and a relationship between particle size and toxicity, with the smallest fractions appearing to exhibit the greatest toxicity.