scholarly journals Effect of the Recycling Process on Drinking Water Treatment: Evaluation Based on Fluorescence EEM Analysis Using the Peak-Picking Technique and Self-Organizing Map

Water ◽  
2021 ◽  
Vol 13 (23) ◽  
pp. 3456
Author(s):  
Hudori Hudori ◽  
Maulana Yusup Rosadi ◽  
Toshiro Yamada ◽  
Sartaj Ahmad Bhat ◽  
Fusheng Li
Keyword(s):  
Humic Acid ◽  
Water Treatment ◽  
Fulvic Acid ◽  
Drinking Water Treatment ◽  
Self Organizing Map ◽  
Peak Picking ◽  
Recycling Process ◽  
Fluorescence Excitation ◽  
Flocculation Process ◽  
Self Organizing

The recycling process is applied in many water treatment plants (WTPs), although this process can lead to adverse effects. The effect of the recycling process on the characteristics of dissolved organic matter was evaluated based on a fluorescence excitation-emission matrix using the peak-picking technique and self-organizing map (SOM). In this study, an evaluation of two WTPs, one with and one without a recycling system, was carried out. Both WTPs show moderate efficiency during the coagulation–flocculation process in removing DOC, fulvic acid-like, humic acid-like, and tryptophan-like substances. The recycling process causes increased values of fulvic acid-like, humic acid-like, and tryptophan-like substances and specific ultraviolet absorbance (SUVA) after the filtration process of about 31.0%, 35.7%, 22.2%, and 6%, respectively. Meanwhile, the WTP without recycling showed a reduction in the level of fulvic acid-like, humic acid-like, and tryptophan-like substances and SUVA by 23.3%, 52.9%, 27.8%, and 21.1%, respectively. Moreover, SOM analysis based on the peak-picking technique can determine differences in sample clusters due to the recycling process.

scholarly journals Fouling analysis of polysulfone ultrafiltration membranes used for drinking water treatment

2011 ◽  
Vol 11 (6) ◽  
pp. 668-674 ◽  
Author(s):  
B. Q. Zhao ◽  
C. P. Huang ◽  
S. Y. Chen ◽  
D. S. Wang ◽  
T. Li ◽  
...  
Keyword(s):  
Drinking Water ◽  
Organic Matter ◽  
Water Treatment ◽  
Fulvic Acid ◽  
Humic Substances ◽  
Natural Organic Matter ◽  
Drinking Water Treatment ◽  
Ultrafiltration Membranes ◽  
Fluorescence Excitation ◽  
Hydrophobic Fraction

Natural organic matter (NOM) plays a significant role in the fouling of ultrafiltration membranes in drinking water treatment processes. For a better understanding of the interaction between fractional components of NOM and polysulfone (PS) ultrafiltration membranes used for drinking water treatment, fouling and especially the physically irreversible fouling of natural organic matter were investigated. Resin fractionation, fluorescence excitation–emission matrix (EEM) spectroscopy, fourier transform infrared spectroscopy (FTIR), contact angle and a scanning electron microscope (SEM) were employed to identify the potential foulants. The results showed that humic acid and fulvic acid of small size were likely to permeate the membrane, while the hydrophobic fraction of humic and fulvic acid and aromatic proteins tended to be rejected and retained. Organic compounds such as proteins, humic substances, and polysaccharide-like materials, were all detected in the fouling layer. The physically irreversible fouling of the PS membrane seemed to be mainly attributed to the hydrophobic fraction of humic substances.

Identification of humic acid-like and fulvic acid-like natural organic matter in river water using fluorescence spectroscopy

2011 ◽  
Vol 63 (10) ◽  
pp. 2427-2433 ◽  
Author(s):  
R. H. Peiris ◽  
H. Budman ◽  
C. Moresoli ◽  
R. L. Legge
Keyword(s):  
Organic Matter ◽  
Humic Acid ◽  
Water Sample ◽  
Fulvic Acid ◽  
River Water ◽  
Natural Organic Matter ◽  
Drinking Water Treatment ◽  
Fluorescence Analysis ◽  
Product Formation ◽  
Fluorescence Excitation

Identifying the extent of humic acid (HA)-like and fulvic acid (FA)-like natural organic matter (NOM) present in natural water is important to assess disinfection by-product formation and fouling potential during drinking water treatment applications. However, the unique fluorescence properties related to HA-like NOM is masked by the fluorescence signals of the more abundant FA-like NOM. For this reason, it is not possible to accurately characterize HA-like and FA-like NOM components in a single water sample using direct fluorescence EEM analysis. A relatively simple approach is described here that demonstrates the feasibility of using a fluorescence excitation-emission matrix (EEM) approach for identifying HA-like and FA-like NOM fractions in water when used in combination with a series of pH adjustments and filtration steps. It is demonstrated that the fluorescence EEMs of HA-like and FA-like NOM fractions from the river water sample possessed different spectral properties. Fractionation of HA-like and FA-like NOM prior to fluorescence analysis is therefore proposed as a more reasonable approach.

Characterization of NOM in a drinking water treatment process train with no disinfectant residual

2009 ◽  
Vol 9 (4) ◽  
pp. 379-386 ◽  
Author(s):  
S. A. Baghoth ◽  
M. Dignum ◽  
A. Grefte ◽  
J. Kroesbergen ◽  
G. L. Amy
Keyword(s):  
Drinking Water ◽  
Water Treatment ◽  
Organic Carbon ◽  
Distribution System ◽  
Chemical Properties ◽  
Drinking Water Treatment ◽  
Building Blocks ◽  
Fluorescence Excitation ◽  
Water Treatment Process ◽  
Water Treatment Plants

For drinking water treatment plants that do not use disinfectant residual in the distribution system, it is important to limit availability of easily biodegradable natural organic matter (NOM) fractions which could enhance bacterial regrowth in the distribution system. This can be achieved by optimising the removal of those fractions of interest during treatment; however, this requires a better understanding of the physical and chemical properties of these NOM components. Fluorescence excitation-emission matrix (EEM) and liquid chromatography with online organic carbon detection (LC-OCD) were used to characterize NOM in water samples from one of the two water treatment plants serving Amsterdam, The Netherlands. No disinfectant residual is applied in the distribution system. Fluorescence EEM and LC-OCD were used to track NOM fractions. Whereas fluorescence EEM shows the reduction of humic-like as well as protein-like fluorescence signatures, LC-OCD was able to quantify the changes in dissolved organic carbon (DOC) concentrations of five NOM fractions: humic substances, building blocks (hydrolysates of humics), biopolymers, low molecular weight acids and neutrals.

scholarly journals Mechanism of Coagulation Using Chitosan from Mytilus Virdis Linneaus Shells in Water Treatment

2018 ◽  
Author(s):  
sinardi ◽  
Prayatni Soewondo ◽  
Suprihanto Notodarmojo ◽  
cynthia radiman
Keyword(s):  
Water Treatment ◽  
Inorganic Compounds ◽  
Drinking Water Treatment ◽  
Turbid Water ◽  
Degree Of Deacetylation ◽  
Green Mussel ◽  
Environment And Health ◽  
Residual Aluminum ◽  
Mussel Shells ◽  
Flocculation Process

Green mussel (Mytilus viridis Linnaeus) is one of the shells from marine source that can be used as chitosan. On the other side of drinking water treatment using synthetic coagulant such us aluminum sulphate (Al2 (SO4)3) concerns about the residual aluminum in the water that contains inorganic compounds are carcinogenic so it is necessary to do research about potential use of chitosan as a coagulant. This study conducted on laboratory-scale use of chitosan from green mussel shells as a coagulant in coagulation-flocculation process using turbid water from Tirtawening in Bandung City, Indonesia. The purpose of this study was to determine the mechanism of coagulation-flocculation process based on the characteristics of chitosan. Preparation of chitosan with deproteination process done using a solution of NaOH 3.5% 10: 1 (v: w), stirring 2 hours 65oC. Demineralization process using a solution of HCl 1 N 15: 1 (v: w), stirring 30 minutes 50 °C. Deacetylation process using a solution NaOH 60% 20:1 (v: w) stirred 60 minutes 120oC produce chitosan with degree of deacetylation about 77.8% and molecular mass about 4,26x104 g / mol. The degree of deacetylation of chitosan effect ability formation of flock and the molecules of mass of chitosan effect in binding colloids in turbid water into one and form a flock large. The results concluded that chitosan from green mussel shells can be used as a coagulant for turbidity removal in water treatment and use it safe for the environment and health because from natural compounds and biodegradable.

Estradiol Uptake in a Combined Magnetic Ion Exchange - Ultrafiltration (MIEX-UF) Process During Water Treatment

2017 ◽  
Vol 23 (2) ◽  
pp. 328-337 ◽  
Author(s):  
Alessandra Imbrogno ◽  
Jennifer Biscarat ◽  
Andrea Iris Schafer
Keyword(s):  
Drinking Water ◽  
Humic Acid ◽  
Water Treatment ◽  
Surface Water ◽  
Ion Exchange ◽  
Acid Concentration ◽  
Drinking Water Treatment ◽  
Polymeric Materials ◽  
Aquatic Life ◽  
Magnetic Ion

Background: Estrogens and their synthetic analogues are widely used as pharmaceuticals. Upon oral administration these drugs are eventually excreted via urine. The persistence of these pharmaceuticals and inefficient removal by water treatment lead to accumulation in surface water and effluents with negative effects for aquatic life and human health. Methods: In this study, the uptake of estradiol by a combined magnetic ion exchange resin - ultrafiltration process (MIEX-UF) was investigated. This is a relatively common process used in drinking water treatment for the removal of natural organic matter. However, uptake of micropollutants, such as steroidal pharmaceuticals, may occur as a side effect of water treatment due to the high affinity for polymeric materials. To elucidate the mechanism governing estradiol partitioning between water, resin and membrane, the influence of different parameters, such as pH, humic acid concentration and membrane molecular-weight-cut-off (MWCO) was studied. Results: Humic acid concentration and pH affected estradiol uptake most. At pH 11 the most significant increase of estradiol uptake was observed for MIEX-UF process (30 ng/g corresponding to 80%) compared with individual UF (17 ng/g corresponding to 12%). The presence of humic acid slightly reduced estradiol uptake at pH 11 (about 55%) due to competition for the ion exchange binding sites. Conclusion: Results demonstrated that the uptake of estradiol, which is amongst the most potent EDCs detected in surface water, in the MIEX-UF process can reach significant quantities (30 ng/g of resin) leading to uncontrolled accumulation of this micropollutant during drinking water treatment. This study gives a novel contribution in the understanding the mechanism of the unanticipated accumulation of pharmaceuticals, such as estradiol, in the drinking water treatment process.

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