scholarly journals A procedure of Arrhenius activation energy determination for salt flotation of particles in the vicinity of one molar salt aqueous solutions

Author(s):  
Tomasz Ratajczak ◽  
Szymon Kurkiewicz ◽  
Jan Drzymała
Entropy ◽  
2020 ◽  
Vol 22 (12) ◽  
pp. 1337
Author(s):  
Xiangfeng Tian ◽  
Lemeng Wang ◽  
Pan Zhang ◽  
Dong Fu

The surface tension and viscosity values of N-methyldiethanolamine (MDEA) aqueous solutions promoted by tetramethylammonium arginate ([N1111][Arg]) were measured and modeled. The experimental temperatures were 303.2 to 323.2 K. The mass fractions of MDEA (wMDEA) and [N1111][Arg] (w[N1111][Arg]) were 0.300 to 0.500 and 0.025 to 0.075, respectively. The measured surface tension and viscosity values were satisfactorily fitted to thermodynamic models. With the aid of experimentally viscosity data, the activation energy (Ea) and H2S diffusion coefficient (DH2S) of MDEA-[N1111][Arg] aqueous solution were deduced. The surface entropy and surface enthalpy of the solutions were calculated using the fitted model of the surface tension. The quantitative relationship between the calculated values (surface tension, surface entropy, surface enthalpy, viscosity, activation energy, and H2S diffusion coefficient) and the operation conditions (mass fraction and temperature) was demonstrated.


2020 ◽  
Vol 24 (2 Part B) ◽  
pp. 1143-1155
Author(s):  
Salman Ahmad ◽  
Khan Ijaz ◽  
Ahmed Waleed ◽  
Tufail Khan ◽  
Tasawar Hayat ◽  
...  

The computational investigations on mixed convection stagnation point flow of Jeffrey nanofluid over a stretched surface is presented herein. The sheet is placed vertical over which nanomaterials flowing upward direction. Arrhenius activation energy and binary chemical reaction are accounted. Non-linear radiative heat flux, MHD, viscous dissipation, heat source/sink, and Joule heating are considered. Initially the non-linear flow expressions are converted to ordinary one and then tackled for series solutions by homotopy analysis method. Consider flow problem are discussed for velocity, temperature and concentration through various flow variables. Furthermore, skin friction coefficient, Sherwood number, and heat transfer rate are computed graphically.


1954 ◽  
Vol 32 (2) ◽  
pp. 71-78 ◽  
Author(s):  
C. J. Krauss ◽  
J. W. T. Spinks

Coefficients of self-diffusion have been measured for aqueous solutions of sodium dihydrogen phosphates from 1 molar to 10−4 molar and at temperatures of 15, 25, 35, and 45 °C. The activation energy of self-diffusion has been calculated for various concentrations. It decreases from 5.4 kcal./mole at 0.9 M to 4.3 kcal./mole. at infinite dilution.


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