Dielectric Dispersion and Ferroelectric P-E Hysteresis Loop of Lead-Free Ta-Substituted (Na$_{0.53}$K$_{0.47}$)(Nb$_{0.55}$Ta$_{0.45}$)O$_3$ Ceramics

2017 ◽  
Vol 67 (11) ◽  
pp. 1284-1290
Author(s):  
Jin Soo KIM ◽  
Hyo-Eun KIM ◽  
Ho Sueb LEE* ◽  
Kwang-Sei LEE
2014 ◽  
Vol 04 (02) ◽  
pp. 1450014 ◽  
Author(s):  
Venkata Sreenivas Puli ◽  
Dhiren K. Pradhan ◽  
Brian C. Riggs ◽  
Shiva Adireddy ◽  
Ram S. Katiyar ◽  
...  

Polycrystalline sample of lead-free 1/3( Ba 0.70 Sr 0.30 TiO 3) + 1/3( Ba 0.70 Ca 0.30 TiO 3) + 1/3( BaZr 0.20 Ti 0.80 O 3)( BST - BCT - BZT ) ceramic was synthesized by solid state reaction method. Phase purity and crystal structure of as-synthesized materials was confirmed by X-ray diffraction (XRD). Temperature-dependent dielectric permittivity studies demonstrated frequency-independent behavior, indicating that the studied sample has typical diffuse phase transition behavior with partial thermal hysteresis. A ferroelectric phase transition between cubic and tetragonal phase was noticed near room temperature (~ 330 K). Bulk P–E hysteresis loop showed a saturation polarization of 20.4 μC/cm2 and a coercive field of ~ 12.78 kV/cm at a maximum electric field of ~ 115 kV/cm. High dielectric constant (ε ~ 5773), low dielectric loss (tan δ ~ 0.03) were recorded at room temperature. Discharge energy density of 0.44 J/cm3 and charge energy density of 1.40 J/cm3 were calculated from nonlinear ferroelectric hysteresis loop at maximum electric field. Dielectric constant at variable temperatures and electric fields, ferroelectric to paraelectric phase transition and energy storage properties were thoroughly discussed.


Pramana ◽  
2009 ◽  
Vol 72 (6) ◽  
pp. 999-1009 ◽  
Author(s):  
M. Raghavender ◽  
G. S. Kumar ◽  
G. Prasad

2019 ◽  
Vol 114 (12) ◽  
pp. 122901 ◽  
Author(s):  
Jiaming Ye ◽  
Genshui Wang ◽  
Xuefeng Chen ◽  
Fei Cao ◽  
Xianlin Dong

2011 ◽  
Vol 25 (32) ◽  
pp. 4481-4488 ◽  
Author(s):  
YUN ZHOU ◽  
XINYAN WANG ◽  
LI LI ◽  
YULING SU ◽  
JINCANG ZHANG ◽  
...  

Nontoxic lead-free multiferroic composites are synthesized by incorporating the dispersed 0.3 CoFe 2 O 4 (CFO) ferromagnetic nanoparticles into 0.7( K 0.5 Na 0.5) NbO 3- LiSbO 3 (KNN-LS5.2) ferroelectric micromatrix. The multiferroicity of the composite can be verified by polarization-electric field hysteresis loop and magnetic hysteresis loop. The composite exhibits excellent magnetic properties. A dilution effect is observed in magnetic hysteresis loops. The field dependence of ME voltage coefficient is given as a function of magnetic field from -4 kOe to 4 kOe with a maximum magnetoelectric voltage coefficient of 10.7 mV ⋅ cm -1⋅ Oe -1 at the frequency of 1 kHz. It is a very high value in the lead-free magnetoelectric composites system for the potential use on multifunctional devices.


2019 ◽  
Author(s):  
Anita Verma ◽  
Arun Kumar Yadav ◽  
Nasima Khatun ◽  
Sunil Kumar ◽  
Somaditya Sen

2007 ◽  
Vol 90 (23) ◽  
pp. 232903 ◽  
Author(s):  
Dunmin Lin ◽  
K. W. Kwok ◽  
H. L. W. Chan

Author(s):  
Muhannad Mustafa ◽  
Zijie Cai ◽  
Jeffrey C. Suhling ◽  
Pradeep Lall

Solder joints in electronic assemblies are typically subjected to thermal cycling, either in actual application or in accelerated life testing used for qualification. Mismatches in the thermal expansion coefficients of the assembly materials leads to the solder joints being subjected to cyclic (positive/negative) mechanical strains and stresses. This cyclic loading leads to thermomechanical fatigue damage that involves damage accumulation, crack initiation, crack propagation, and failure. While the effects of aging on solder constitutive behavior (stress-strain and creep) have been examined in some detail, there have been no prior studies on the effects of aging on solder failure and fatigue behavior. In this investigation, we have examined the effects of aging on the cyclic stress-strain behavior of lead free solders. Uniaxial SAC lead free solder specimens were subjected to cyclic (tension/compression) mechanical loading. Samples were cyclically loaded under both strain control (constant positive and negative strain limits) and stress control (constant positive and negative stress limits). The hysteresis loop size (area) was calculated from the measured cyclic stress-strain curves for a given solder alloy and temperature. This area represents the strain energy density dissipated per cycle, which can be typically correlated to the damage accumulation in the joint. The tests in this investigation were performed with SAC105 solder alloy. Prior to cyclic loading, the specimens in this study were aged (preconditioned) at 125 °C for various aging times (0–6 months). From the recorded cyclic stress-strain curves, we have been able to characterize and empirically model the evolution of the solder hysteresis loops with aging. Similar to solder stress-strain and creep behaviors, there is a strong effect of aging on the hysteresis loop size (and thus the rate of damage accumulation) in the solder specimens. The observed degradations in the fatigue/cyclic behavior of the lead free solders are highly accelerated for lower silver content alloys (e.g., SAC105), and for aging and testing at higher temperatures. In our current work, we are also subjecting aged solder samples to cyclic loading until failure occurs. Our ultimate goal is to understand the effects of aging on the thermomechanical fatigue life.


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