Effect of Silica Fume on the Rheological Properties of Cement Paste with Ultra-Low Water Binder Ratio

The effect of silica fume on the rheological properties of a cement–silica fume–high range water reducer–water mixture with ultra-low water binder ratio (CSHWM) was studied. The results indicate that the W/B ratio and silica fume content have different effects on the rheological parameters, including the yield stress, plastic viscosity, and hysteresis loop area. The shear-thickening influence of CSHWM decreased with the increased silica fume content. When the silica fume content increased from 0% to 35%, the mixture with W/B ratio of 0.19 and 0.23 changed from a dilatant fluid to a Newtonian fluid, and then to a pseudoplastic fluid. When the silica fume content was less than 15%, the yield stress was close to 0. With the increase of silica fume content, the yield stress increased rapidly. The plastic viscosity and hysteresis loop area decreased slightly with the addition of a small amount of silica fume, but increased significantly with the continuous increase of silica fume. Compared with the Bingham and modified Bingham models, the Herschel–Buckley model is more applicable for this CSHWM.

Experimental Study of Hysteresis in Clayey Soils under Compression

The energy dissipation for one cycle of clay soil deformation over the area of ​​a hysteresis loop under conditions of one-dimensional deformation has been experimentally studied. Several series of trials were carried out under different conditions of soil density and moisture and different loading modes. It was established by the experiments that after several cycles of loading and unloading of the samples, the transient process of the closed loop formation ends and certain dependences of stress on deformations are established in the sections of the ascending and descending branches of the hysteresis loop. To determine these dependencies, rheological relations obtained directly from the hysteresis loop by approximating the arcs of its contour have been used. By integrating the approximating rheological dependences along the branches of the loop, the dissipated energy per deformation cycle has been obtained as a function of cyclic deformation amplitude, measured by the area of the hysteresis loop. Experiments on obtaining a hysteresis loop were carried out on a compression device with a cyclic sample. Samples with different states of density and moisture content were produced by consolidating a paste having yield point moisture under different pressures. Several series of experiments have been carried out. In the first series, soil absorption coefficients were derived for different states of density-moisture at different loading rates. In the second series, three types of clayish soil (clay, loam, sandy loam) were studied. Dissipation coefficients have been found out for the indicated soils. In the third series, three types of clay soil were tested under different conditions of density and moisture. The dissipation coefficients have been obtained. In the fourth series, the dependences of the absorption coefficient on the amplitude value of the cyclic stress for three types of clay soil were disclosed. It was found that a change in the loading rate within the range from 0.05 MPa to 0.2 MPa does not lead to the significant change in the absorption coefficient, the increase in the number of clay fractions in the sample leads to an increase in the absorption coefficient, a change in the amplitude of cyclic loading (in the indicated range of change) does not affect the absorption coefficient.

Influence of Cr-doping on structural, magnetic and dielectric properties of M-type hexaferrites synthesized using microwave digestion technique

M-type hexaferrite SrCrxFe12-xO19 compounds doped with Cr (x=0, 1, 2, 3 and 4 at.%) were prepared by microwave digestion system. X-ray diffraction was used to study the structure and crystallization of the samples. The samples are found to have a hexagonal phase, SrFe12O19, as a main phase at 2Θ ≈ 33.144° and 35.618° for x = 0 and 1 respectively, and 32.451° and 34.295° for x ≥ 2. The Rietveld refined parameters such as the lattice parameters (a=b, c), direct and indirect cell volume, crystallite size and microstrain were investigated. TEM and SEM results showed that the samples have hexagonal shape and grain sizes range from 126 nm to 379 nm. Magnetization, M, as a function of the applied magnetic field, H, was obtained from the hysteresis loop. The coercive field, HC , saturation, Ms and remnant, Mr , magnetization and squareness ration, Mr/Ms , were extracted from the hysteresis loop results. These results revealed that HC is inversely proportional with the grains size of the samples but directly proportional with Cr-doping values candidating these compounds to be used in computer hard disk memories applications. M values are inversely proportional with Cr-doping values. The variation of conductivity, σ, impedance, Z, dielectric constant, ε, dielectric loss factor, tan δ and dissipation factor as functions of both AC frequency, F(Hz) and Cr-doping, x, were investigated. The maximum value of the dissipation factor was at x=2 which equals 8.05x109 m/F when F = 2x105 Hz. The impedance of the samples behaved as a capacitor reactance that makes our compounds candidate for many crucial dielectric applications.

Development of Co-Rich Microwires with Graded Magnetic Anisotropy

In this paper, a gradual change in the hysteresis loop of Co-rich glass-coated microwire stress-annealed at variable temperature is observed. Such microwires annealed with a temperature gradient also present a variable squareness ratio and magnetic anisotropy field along the microwire’s length. The obtained graded anisotropy has been attributed to a gradual modification of the domain structure along the microwire originated by a counterbalance between shape, magnetoelastic, and induced magnetic anisotropies. Accordingly, we propose a rather simple route to design graded magnetic anisotropy in a magnetic microwire.

Asymmetric Interfacial Intermixing Associated Magnetic Coupling in LaMnO3/LaFeO3 Heterostructures

The structural and magnetic properties of LaMnO3/LaFeO3 (LMO/LFO) heterostructures are characterized using a combination of scanning transmission electron microscopy, electron energy-loss spectroscopy, bulk magnetometry, and resonant x-ray reflectivity. Unlike the relatively abrupt interface when LMO is deposited on top of LFO, the interface with reversed growth order shows significant cation intermixing of Mn3+ and Fe3+, spreading ∼8 unit cells across the interface. The asymmetric interfacial chemical profiles result in distinct magnetic properties. The bilayer with abrupt interface shows a single magnetic hysteresis loop with strongly enhanced coercivity, as compared to the LMO plain film. However, the bilayer with intermixed interface shows a step-like hysteresis loop, associated with the separate switching of the “clean” and intermixed LMO sublayers. Our study illustrates the key role of interfacial chemical profile in determining the functional properties of oxide heterostructures.

Synthesis, microstructure and effect of high pressures on transport properties of GdBaCo2O5,5

In polycrystalline samples of double layered cobaltite GdBaCo2O5.5 the structure and resistivity at the first order “insulator-metal” (I-M) phase transition were studied at normal and high pressures. The strong dependence of the shape of the temperature hysteresis loop on the rate of temperature change indicates an infra-slow thermal relaxation of conductivity. Baric studies have shown an increase in the transition temperature ТIM at increasing pressure P with baric coefficient dТIM/dP ≈ 10 K/GPa. The spin blockade model is used to explain the observed effects.

Hysteretic device characteristics indicate cardiac contractile state for guiding mechanical circulatory support device use

Background Acute heart failure and cardiogenic shock remain highly morbid conditions despite prompt medical therapy in critical care settings. Mechanical circulatory support (MCS) is a promising therapy for these patients, yet remains managed with open-loop control. Continuous measure of cardiac function would support and optimize MCS deployment and weaning. The nature of indwelling MCS provides a platform for attaining this information. This study investigates how hysteresis modeling derived from MCS device signals can be used to assess contractility changes to provide continuous indication of changing cardiac state. Load-dependent MCS devices vary their operation with cardiac state to yield a device–heart hysteretic interaction. Predicting and examining this hysteric relation provides insight into cardiac state and can be separated by cardiac cycle phases. Here, we demonstrate this by predicting hysteresis and using the systolic portion of the hysteresis loop to estimate changes in native contractility. This study quantified this measurement as the enclosed area of the systolic portion of the hysteresis loop and correlated it with other widely accepted contractility metrics in animal studies (n = 4) using acute interventions that alter inotropy, including a heart failure model. Clinical validation was performed in patients (n = 8) undergoing Impella support. Results Hysteresis is well estimated from device signals alone (r = 0.92, limits of agreement: − 0.18 to 0.18). Quantified systolic area was well correlated in animal studies with end-systolic pressure–volume relationship (r = 0.84), preload recruitable stroke work index (r = 0.77), and maximum slope of left ventricular pressure (dP/dtmax) (r = 0.95) across a range of inotropic conditions. Comparable results were seen in patients with dP/dtmax (r = 0.88). Diagnostic capability from ROC analysis yielded AUC measurements of 0.92 and 0.90 in animal and patients, respectively. Conclusions Mechanical circulatory support hysteretic behavior can be well modeled using device signals and used to estimate contractility changes. Contractility estimate is correlated with other accepted metrics, captures temporal trends that elucidate changing cardiac state, and is able to accurately indicate changes in inotropy. Inherently available during MCS deployment, this measure will guide titration and inform need for further intervention.