Occurrence and Treatment of Micropollutants in Landfill Leachate

2020 ◽  
pp. 1492-1508
Author(s):  
Muhammad Umar

Micropollutants have emerged as a new challenge to the scientific community over the past decade. This chapter discusses the occurrence of various micropollutants in landfill leachate. Phthalic acid esters (PAEs) are one of the most investigated compounds in landfill leachate and are therefore given special focus in this chapter. The potential treatment options for these micropollutants are discussed with relevance to the estrogenicity potential of micropollutants. The potential of leaching of micropollutants from landfill sites is discussed to emphasize on the requirements of appropriate liners to avoid such exposure to the surrounding environment. Biological treatment in particular membrane bioreactors have been successfully used to remove some of the micropollutants. Advanced oxidation processes such Fenton and photo-Fenton have limited application reported in literature whereas other physic-chemical processes such as coagulation and adsorption have been demonstrated to be effective in the removal of micropollutants.

Author(s):  
Muhammad Umar

Micropollutants have emerged as a new challenge to the scientific community over the past decade. This chapter discusses the occurrence of various micropollutants in landfill leachate. Phthalic acid esters (PAEs) are one of the most investigated compounds in landfill leachate and are therefore given special focus in this chapter. The potential treatment options for these micropollutants are discussed with relevance to the estrogenicity potential of micropollutants. The potential of leaching of micropollutants from landfill sites is discussed to emphasize on the requirements of appropriate liners to avoid such exposure to the surrounding environment. Biological treatment in particular membrane bioreactors have been successfully used to remove some of the micropollutants. Advanced oxidation processes such Fenton and photo-Fenton have limited application reported in literature whereas other physic-chemical processes such as coagulation and adsorption have been demonstrated to be effective in the removal of micropollutants.


2013 ◽  
Vol 30 (7) ◽  
pp. 647-653 ◽  
Author(s):  
Ying LAI ◽  
Zongping HUANG ◽  
Xiuxiu GE ◽  
Rui LIN ◽  
Hexiu CHEN

1998 ◽  
Vol 38 (2) ◽  
pp. 185-192 ◽  
Author(s):  
M. J. Bauer ◽  
R. Herrmann ◽  
A. Martin ◽  
H. Zellmann

Large amounts of phthalic acid esters (PAEs) are leached from plastics dumped at municipal landfills. This leachate transports PAEs either adsorbed on particulate matter or in dissolved phase. Dissolved organic macromolecules, mainly humic-like substances, enhance the solubility of PAEs. In the biochemical environments of municipal landfills short chain PAEs can be degraded by base-catalyzed hydrolysis or by microorganisms which enzymatically split the side chains. However, there is no cleavage of the aromatic ring. Long chain PAEs like di-(2-ethylhexyl) phthalate are neither degraded abiotically nor by microorganisms. Hence, these PAEs can be leached and washed out of leaky landfills into the groundwater and thus continue to be a threat to the aquatic environment. Only a combined UV radiation/ozonation treatment is capable of fully destroying PAEs.


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