Comparative Study between Imprinted Polymer Technology and Economic Adsorption Methodologies for the Removal of Arsenic Species from Water

Among the various arsenic sources in the environment, water may pose the greatest threat to human health. Arsenic and its compounds are known to have adverse health effects on humans, including skin cancer, bladder cancer, kidney cancer, and lung cancer, as well as vascular diseases of the legs and feet. There are a few separation methods that have been studied to remove arsenic species from water. Methods to remove arsenic species such as adsorption and ion exchange, coagulation and flocculation and membrane filtration have been developed to remove arsenic species from water. However, certain separation methods require a sophisticated equipment and are too expensive. From the different possible methods, this review is based in adsorption studies using imprinted polymer technology and economic sorbents as a media to remove arsenic from water. The details of adsorption processes for imprinted polymer technology have been discussed briefly and the comparative properties for arsenic species removal using different types of sorbents has been addressed significantly for being a user-friendly, highly extended and inexpensive methodology. However, a few drawbacks for each sorbent have been determined and the details was included in this review.

Utilization of Moringa oleifera as Natural Coagulant for Water Purification

The plant-based natural coagulant has the potential to substitute the chemical coagulant in the water treatment process. In this work, the potential of plant-based natural coagulants in the ability of turbidity removal was identified. The Moringa oleifera seed was selected for the batch analysis test such as pH, contact time, agitation, and dosage. The high alkaline water decreases the effectiveness of plant-based natural coagulants. The agitation and contact time show the importance of the coagulation process. The optimum turbidity removal rate in pH is 4, the contact time is 60 seconds and 3000 seconds for coagulation and flocculation, respectively, the agitation is 300 RPM and 30 RPM for coagulation and flocculation, and lastly, the dosage is 10 g of Moringa oleifera seed. Finally, the plant-based natural coagulants demonstrated the ability to remove turbidity and could be used in place of chemical coagulants.

River water turbidity removal using new natural coagulant aids: case study of Euphrates River, Iraq

For turbidity removal, most of drinking water treatment plants are using coagulants due to the presence of suspended and colloidal materials at the coagulation and flocculation units. Aluminium and sulphates salts are the widely used coagulants, such as Aluminium sulphate (Alum) and ferric chloride. However, several researches have linked Alzheimer's disease to the use of Aluminium sulphate. Hence, scholars have conducted several researches on the possibility to reduce the amount of Aluminium sulphate by using natural material/plants base as coagulant aids. In this study, Mallow's Leaves Extracts (MLE) and Carob's Pods Extracts (CPE) were used as an alternative coagulant aid. Couples of coagulation tests were implemented to find the optimal dosage of Aluminium Sulphates were used as coagulants. The results displayed that the maximum turbidity removal efficiency by adding 100% of each coagulant (i.e., Alum, MLE and CPE) were (61.16%, 51.175% and 37.12%), respectively. In addition, the minimum residual turbidity and maximum turbidity removal efficiency were 4.56 NTU and 97.72% by adding 22.5 Alum and 7.5 MLE presenting 30 mg/l dosing. Further, the minimum residual turbidity and maximum turbidity removal efficiency were 15.4 NTU and 92.3% by adding 22.5 Alum and 7.5 CPE presenting 30 mg/l dosing.

Coagulation performance evaluation of alginate as a natural coagulant for the treatment of turbid water

Alginates are quite abundant in nature as they occur both as a structural component in marine brown algae (Phaeophyceae) comprising up to 40% of dry matter and as capsular polysaccharides in soil bacteria. Alginic acid is the only polysaccharide, which naturally contains carboxyl groups in each constituent residue, and possesses various abilities for functional materials. Experiments were carried out for the water of turbidity 300 NTU. Alginate as such doesn't act as a coagulant instead it should be converted to calcium alginate by adding calcium ions. Calcium chloride was used for imparting calcium ions necessary for the reaction. The dosage of calcium was fixed as 50 mg/L, 75 mg/L, 100 mg/L, 150 mg/L, 200 mg/L, and alginate doses between 2 to 10 mg/L. Calcium dosage below 50 mg/L was not sufficient enough for the formation of egg-box structure which is responsible for the coagulation and flocculation process. For the mechanism of charge neutralization to take place effectively, calcium should be added first followed by alginate. pH and conductivity of the sample remain constant before and after the treatment. The dosage of alginate required for the treatment is less so the cost of treatment also will be very less, thus alginate can replace the usage of chemical coagulants like alum.

Choosing the chemicals and advanced filter media for enhancing the process of mine water purification

В настоящее время строительство сооружений для очистки шахтных вод является одним из важных мероприятий, направленных на сохранение поверхностных водотоков и водоемов. Количество сбрасываемых шахтных вод в поверхностные водоемы может быть сокращено в результате их использования для комплексного обеспыливания в шахтах, технического водоснабжения и других наиболее водоемких технологических процессов. Одним из эффективных способов очистки шахтных вод от взвешенных веществ и тяжелых металлов является реагентная обработка высокомолекулярными флокулянтами, использование которых позволяет уменьшить расход неорганических коагулянтов и интенсифицировать процесс осаждения взвешенных веществ и тяжелых металлов. Предварительная обработка шахтной воды перед контактными осветлителями позволяет значительно увеличить пропускную способность действующих очистных сооружений, стабилизировать их работу при колебании качественного состава и температуры шахтной воды, снизить нагрузку на последующие стадии очистки на скорых фильтрах. Представлены результаты экспериментальных лабораторных исследований пробной коагуляции и флокуляции с последующим фильтрованием на скорых фильтрах с применением каталитической фильтрующей загрузки Orefilter В, сорбента АС и сорбционной загрузки Extrasorb, а также удаления (отдувки) аммиака из шахтной воды. Currently, the construction of facilities for the purification of mine waters is one of the important measures aimed at preserving surface watercourses and water reservoirs. The amount of mine water discharged into surface water bodies can be reduced by reusing it for complex dedusting in mines, process water supply and other most water-intensive technological processes. One of the effective ways of removing suspended solids and heavy metals from mine water is chemical treatment with high-molecular flocculants that provide for reducing the consumption of inorganic coagulants and enhancing the process of suspended solids and heavy metals precipitation. Pretreatment of mine water upstream contact clarifiers can significantly increase the capacity of existing treatment facilities, stabilize their operation in case of fluctuations in the quality composition and temperature of mine water, and reduce the load on the subsequent stages of filtration in rapid filters. The results of experimental laboratory studies of trial coagulation and flocculation with subsequent filtration in rapid filters using Orefilter B catalytic filtering media, AS sorbent and Extrasorb sorption media, as well as removing (stripping) ammonia from mine water are presented.

Treatment of poultry slaughterhouse wastewater using electrocoagulation: a review

Poultry slaughterhouses are generally large consumers of fresh water, which is exhausted as wastewater characterized by a high concentration of biological oxygen demand (BOD), chemical oxygen demand COD, and fats, oil, and grease (FOG). Cost-effective methods are required for the treatment of poultry slaughterhouse wastewater, with the aim of attaining a high quality effluent that can be reused in industrial processes to promote sustainability. As compared to conventional treatment methods, electrocoagulation is an efficient and low-cost system. Electrocoagulation is environmentally friendly, treating wastewater without the need of chemicals, thus limiting secondary pollution. The metal anodes initiate electrochemical reactions for coagulation and flocculation. Its distinct advantages include compact installation, and simple operation. This paper offers a comprehensive review of recent literature that has been dedicated to utilizing electrocoagulation for poultry slaughterhouse wastewater treatment. This paper also examines aspects such as theory, potential applications, current applications, as well as economical assessment of the technique.

KOMBINASI PROSES KOAGULASI-FLOKULASI DENGAN SEQUENCHING BATCH REACTOR UNTUK MENURUNKAN KANDUNGAN ORGANIK PADA LIMBAH BATIK

Limbah batik memiliki kandungan organik dan warna, yang sulit untuk digredasi. Tujuan penelitian ini mengembangkan teknologi Sequenching Batch Reactor (SBR) yang dimodifikasi dengan adsorben dari tempurung kelapa dan bamboo. Konsentrasi limbah batik awal, untuk COD sebesar 1965 mg/L, warna 1603 mg/L, TSS 1140 mg/L. Pelaksanaan penelitian terbagi menjadi dua tahap, yaitu tahap pertama limbah diolah menggunakan proses koagulasi dan flokulasi, selanjutnya tahap dua menggunakan Sequencing Batch Reactor. Pada tahap koagulasi-flokulasi, menggunakan koagulan PAC (Poly Aluminium Chloride). Sedangkan pada tahap dua yang menggunakan SBR, diatur Hydraulic Retention Time (HRT) dan berat adsorben (tempurung kelapa, bamboo dan zeolite). Hasil penelitian, didapatkan proses koagulasi dan flokulasi mampu menurunkan kandungan organic (BOD5 dan COD) pada kisaran 80%, Total Suspended Solid (TSS )26% dan warna 55%. Sedangkan pada SBR, didapatkan bahwa penambahan adsorben mengoptimalkan pendegradasian kandungan organic. Didapatkan pada HRT optimal 48 jam, jenis adsorben tempurung kelapa optimal menurunkan kandungan BOD5 sebesar 93%, COD 93.7% sebesar , TSS 81% mg/L dan warna 81% mg/L. Kata kunci: kandungan organic dan warna, koagulasi dan flokulasi, sequencing batch reactor (SBR). The organic content and color of batik wastewater make it difficult to grade. The goal of this research was to create a modified Sequenching Batch Reactor (SBR) using adsorbents made from coconut shells and bamboo. The initial concentrations of COD, color, and TSS in batik wastewater were 1965 mg/L for COD, 1603 mg/L for color, and 1140 mg/L for TSS. The research was divided into two stages, with the first stage involving the use of coagulation and flocculation processes, and the second stage involving the use of a Sequencing Batch Reactor. PAC (Poly Aluminum Chloride) coagulant was used for the coagulation-flocculation stage. Meanwhile, the Hydraulic Retention Time (HRT) and the weight of the adsorbent (coconut shell, bamboo, and zeolite) were set in the second stage using SBR. The coagulation and flocculation processes reduced organic content (BOD5 and COD) by 80 %, total suspended solids (TSS) by 26 %, and color by 55 %, according to the results. In SBR, it was discovered that adding an adsorbent improves the decomposition of organic material. The optimal type of coconut shell adsorbent reduced the level of BOD5 by 93 %, COD by 93.7 %, TSS by 81 % mg/L, and color by 81 % mg/L at an optimal HRT of 48 hours. Keywords: Organic material and color, coagulation and flocculation, sequencing batch reactor (SBR).