Electrochemical Potential Noise Analysis of 304 Stainless Steel Weld Zone Exposed to Alkaline Solutions by Different Parameters

2013 ◽  
Vol 331 ◽  
pp. 469-473 ◽  
Author(s):  
Ru Zhao ◽  
Shi Zhe Song

The electrochemical potential noise (EPN) of 304 stainless steel (SS) weld zone in boiling 50%NaOH solution were studied, in order to monitor stress corrosion cracking (SCC). Several EPN parameters were extracted from time domain, frequency domain and statistical analysis. The results showed its corrosion potential appears a downward trend during the experiment. When localized corrosion cracks initiation, amplitude was large and termination appeared. A high frequency plateau appeared using the Fast Fourier Transform (FFT) method in the power spectrum densities (PSD) s, and its standard deviation was larger, indicating the variation of corrosion state. Moreover, Visual records and frequency of events (fn) were discussed. Itsfncan distinguish the different state of specimens. EPN shows considerable promise for detecting localized corrosion. Further development work is expected to lead to a useful, for real time detection of localized corrosion.

1993 ◽  
Vol 34 (9) ◽  
pp. 1531-1540 ◽  
Author(s):  
J. Morales ◽  
P. Esparza ◽  
S. González ◽  
R. Salvarezza ◽  
M.P. Arévalo

2011 ◽  
Vol 480-481 ◽  
pp. 443-447
Author(s):  
Yan Hua Wang ◽  
Yuan Yuan Liu

The distributions of corrosion potential and galvanic current of 304 stainless steel under a NaCl droplet were studied by using the wire beam electrode (WBE). It was found that the distributions of the electrochemical parameters were heterogeneous with isolated anodic and cathodic zones appeared randomly. During the corrosion process, the polarity of some anodes changed with the evolution of time. The localized corrosion rate and heterogeneity increased firstly, and then decreased afterward with the increase of time, which can be attributed to the cooperative effects of the aggressive ions and the corrosion products.


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