Synthesis of Tetragonal BaTiO3 Powders via Alkoxide Method Assisted by Diethanolamine

2013 ◽  
Vol 442 ◽  
pp. 88-93
Author(s):  
Yu Tao Li ◽  
Ke Hui Qiu ◽  
Yu Chong Qiu ◽  
Hui Zhong ◽  
Ning Jia Fu

The BaTiO3 precursor was prepared by alkoxide method, in which barium hydroxide octahydrate and butyl titanate were chosen as the Ba and Ti sources, and diethanolamine (DEA) as the polymerizing agent respectively. In order to determine the synthesis parameters of the target product, the phase transition process of the precursor with temperature increasing was investigated by TG-DTA. The effect of calcination temperature, the dosage of DEA and calcination time on the phase compositions and crystal structure of the synthesized samples were investigated by XRD. The results indicate that DEA can promote the formation of tetragonal BaTiO3 effectively, and the high-purity tetragonal BaTiO3 was obtained by heat treatment of the precursor at 1100°C for 3h with 1mL DEA dosage.

2018 ◽  
Vol 427 ◽  
pp. 304-311 ◽  
Author(s):  
Yifan Meng ◽  
Kang Huang ◽  
Zhou Tang ◽  
Xiaofeng Xu ◽  
Zhiyong Tan ◽  
...  

Langmuir ◽  
2016 ◽  
Vol 32 (26) ◽  
pp. 6691-6700 ◽  
Author(s):  
Zhangxin Ye ◽  
Youcheng Li ◽  
Zesheng An ◽  
Peiyi Wu

Author(s):  
Longjian Li ◽  
Jianbang Zeng ◽  
Quan Liao ◽  
Wenzhi Cui

A new lattice Boltzmann model, which is based on Shan-Chen (SC) model, is proposed to describe liquid-vapor phase transitions. The new model is validated through simulation of the one-component phase transition process. Compared with the simulation results of van der Waals fluid and the Maxwell equal-area construction, the results of new model are closer to the analytical solutions than those of SC model and Zhang model. Since the range of temperature and the maximum density ratio are increased, and the value of maximum spurious current is between those of SC and Zhang models, it is believed that this new model has better stability than SC and Zhang models. Therefore, the application scope of this new model is expanded. According to the principle of corresponding states in Engineering Thermodynamics, the simulations of water and ammonia phase transition process are implemented by using this new model with different equations of state. Compared to the experimental data of water and ammonia, the results show that the Peng-Robinson equation of state is more suitable to describe the water, ammonia and other substances phase transition process. Therefore, these simulation results have great significance for the real engineering applications.


2002 ◽  
Vol 16 (27) ◽  
pp. 1021-1026 ◽  
Author(s):  
ARANYABHUTI BHATTACHERJEE ◽  
MAN MOHAN

Crossover from individual Rabi dynamics to collective Josephson dynamics in two-coupled Bose–Einstein condensates is studied as a phase transition process. We obtain the critical value of the parameter Λ (ratio of the mean field energy to the tunneling matrix element) for the π-phase oscillations from the non-linear perturbation expansion of small oscillations around the saddle point of the first-order Euclidean (imaginary time) differential equations for polar and azimuthal angles θ and ϕ without approximation.


2009 ◽  
Vol 54 (24) ◽  
pp. 4596-4603 ◽  
Author(s):  
JianBang Zeng ◽  
LongJian Li ◽  
Quan Liao ◽  
WenZhi Cui ◽  
QingHua Chen ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (101) ◽  
pp. 83139-83143 ◽  
Author(s):  
Huafang Zhang ◽  
Quanjun Li ◽  
Pengfei Shen ◽  
Qing Dong ◽  
Bo Liu ◽  
...  

Micro-sized rods show a lower phase transition temperature than nano-sized rods, and this is interpreted on the basis of nucleating defects.


2006 ◽  
Vol 89 (2) ◽  
pp. 021904 ◽  
Author(s):  
X. P. Wang ◽  
D. Li ◽  
Q. F. Fang ◽  
Z. J. Cheng ◽  
G. Corbel ◽  
...  

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