Sheet Polymeric Iron (III) Porphyrin Complexes Catalytic Oxidation of Styrene with Molecular Oxygen
2014 ◽
Vol 496-500
◽
pp. 88-91
The sheet polymrtic iron (III) porphyrin complex [PFe (III)TPP] was prepared and charactrtized by FT-IR, TG-DTA and DTG, SEM and XPS. It was applied to catalytic oxidation of styrene with molecular oxygen and exhibited excellent catalytic activity. The results showed that the conversion reached to 50.5% in mild concitions, the major products of benzaldhyde (65.2% at 90°C) were obtained, and the catalyst could be efficiently reused five times.