Conductivity Studies of ENR Based Proton Conducting Polymer Electrolytes

The present study focuses on preparation of ENR-50/PEMA-NH4CF3SO3 proton conducting polymer electrolytes by solution casting technique. Conductivity increases with NH4CF3SO3 concentration up to 40 wt.% but decreases with further increase in salt content. The temperature dependent conductivity study shows that the conductivity-temperature behaviour of ENR-50/PEMA-NH4CF3SO3 electrolytes follows the VTF rule. DSC studies show that the Tg increases with increase in salt content. This means that the increase in conductivity of ENR-50/PEMA-NH4CF3SO3 is incorrelated to the increase of the segmental motion of the host polymer chains but may be attributed to the increase in the concentration and migration rate of charge carriers.

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Characterization of Plasticized PMMA-LiClO4 Solid Polymer Electrolytes

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.585.185 ◽

2012 ◽

Vol 585 ◽

pp. 185-189 ◽

Cited By ~ 3

Author(s):

Rajni Sharma ◽

Anjan Sil ◽

Subrata Ray

Keyword(s):

Ionic Conductivity ◽

Polymer Electrolytes ◽

Thermal Analyses ◽

Impedance Analysis ◽

Solid Polymer Electrolytes ◽

Solid Polymer ◽

Casting Technique ◽

Ac Impedance Analysis ◽

Solution Casting Technique

In the present work, the effect of Li salt i.e. LiClO4 contained in composite plasticizer (PC+DEC) with three different concentrations on ionic transport and other electrochemical properties of PMMA based gel polymer electrolytes synthesized has been investigated. The electrolytes have been synthesized by solution casting technique by varying the wt (%) of salt and plasticizer. The formation of polymer-salt complexes and their structural characterization have been carried out by FTIR spectroscopic and XRD analyses. The room temperature ionic conductivity of the electrolyte composition 0.6PMMA-0.125(PC+DEC)-0.15LiClO4 (wt %) has been found to be maximum whose magnitude is 0.40×10-5 S/cm as determined by ac impedance analysis. The temperature dependent ionic conductivity of electrolyte sample0.6PMMA-0.125(PC+DEC)-0.15LiClO4 has further been investigated. Thermal analyses of electrolyte samples of all three compositions have also been done.

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Ionic Conductivity, Morphology and Transport Number of Lithium Ions in PMMA Based Gel Polymer Electrolytes

Defect and Diffusion Forum ◽

10.4028/www.scientific.net/ddf.334-335.137 ◽

2013 ◽

Vol 334-335 ◽

pp. 137-142 ◽

Cited By ~ 3

Author(s):

Lisani Othman ◽

Khairul Bahiyah Md. Isa ◽

Zurina Osman ◽

Rosiyah Yahya

Keyword(s):

Ionic Conductivity ◽

Salt Concentration ◽

Polymer Electrolytes ◽

Ethylene Carbonate ◽

Transference Number ◽

Gel Polymer Electrolytes ◽

Casting Technique ◽

Ionic Transference Number ◽

Temperature Dependence Of Conductivity ◽

Solution Casting Technique

The gel polymer electrolytes (GPEs) composed of polymethylmethacrylate (PMMA) with lithium trifluoromethanesulfonate (LiCF3SO3) salt dissolved in a binary mixture of ethylene carbonate (EC) and propylene carbonate (PC) organic solvents have been prepared by the solution casting technique. The samples are prepared by varying the salt concentrations from 5 wt.% to 30 wt.%. Impedance spectroscopy measurement has been carried out to determine the ionic conductivity of the samples. The sample containing 25 wt.% of LiCF3SO3salt exhibits the highest room temperature ionic conductivity of 2.56 x 10-3S cm-1. The conductivity of the GPEs has been found to depend on the salt concentration added to the sample, while at higher salt concentration reveals a decrease in the ionic conductivity due to ions association. The temperature dependence of conductivity from 303 K to 373 K is found to obey the Arrhenius law. The ionic transference number,tiof GPEs has been estimated by the DC polarization method and the value is found to be 0.98, 0.93, and 0.97 for the sample containing 25 wt.%, 5 wt.% and 30 wt.% respectively. This result is consistent with the conductivity studies.

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Communication—Phosphoric Acid Based Proton Conducting Polymer Electrolytes for Organic Field Effect Transistor Gate Dielectrics

ECS Journal of Solid State Science and Technology ◽

10.1149/2162-8777/abfa86 ◽

2021 ◽

Vol 10 (5) ◽

pp. 055003

Author(s):

Kevin Ton ◽

Asia Vighi ◽

Keryn Lian ◽

Ta-Ya Chu ◽

Ye Tao

Keyword(s):

Phosphoric Acid ◽

Conducting Polymer ◽

Polymer Electrolytes ◽

Field Effect ◽

Field Effect Transistor ◽

Gate Dielectrics ◽

Organic Field Effect Transistor ◽

Proton Conducting ◽

Effect Transistor

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Proton Conducting Polymer Electrolytes for Electrochemical Capacitors

ECS Transactions ◽

10.1149/1.3490684 ◽

2019 ◽

Vol 28 (8) ◽

pp. 77-82 ◽

Cited By ~ 2

Author(s):

Han Gao ◽

Qifeng Tian ◽

Keryn K. Lian

Keyword(s):

Conducting Polymer ◽

Polymer Electrolytes ◽

Electrochemical Capacitors ◽

Proton Conducting

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ELECTRICAL CONDUCTIVITY STUDIES ON PROTON CONDUCTING POLYMER ELECTROLYTES BASED ON POLY (VINYL ACETATE)

Solid State Ionics ◽

10.1142/9789812773104_0067 ◽

2006 ◽

Author(s):

D. ARUN KUMAR ◽

T. SAVITHA ◽

S. SELVASEKARAPANDIAN ◽

R. BASKARAN

Keyword(s):

Electrical Conductivity ◽

Vinyl Acetate ◽

Conducting Polymer ◽

Polymer Electrolytes ◽

Proton Conducting

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Electrochemical Impedance study of Proton Conducting Polymer Electrolytes based on PVC Doped with Thiocyanate and Plasticized with Glycerol

International Journal of Electrochemical Science ◽

10.20964/2020.05.34 ◽

2020 ◽

pp. 4671-4683 ◽

Cited By ~ 11

Author(s):

Jihad M. Hadi ◽

Keyword(s):

Conducting Polymer ◽

Polymer Electrolytes ◽

Electrochemical Impedance ◽

Proton Conducting ◽

Impedance Study

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Study on ammonium acetate salt-added polyvinyl alcohol-based solid proton-conducting polymer electrolytes

Ionics ◽

10.1007/s11581-013-0899-9 ◽

2013 ◽

Vol 19 (11) ◽

pp. 1619-1626 ◽

Cited By ~ 9

Author(s):

A. P. Khandale ◽

S. S. Bhoga ◽

S. K. Gedam

Keyword(s):

Polyvinyl Alcohol ◽

Conducting Polymer ◽

Polymer Electrolytes ◽

Ammonium Acetate ◽

Proton Conducting ◽

Acetate Salt

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Proton-conducting polymer electrolytes based on phosphoric acid

Solid State Ionics ◽

10.1016/s0167-2738(99)00179-4 ◽

1999 ◽

Vol 125 (1-4) ◽

pp. 225-233 ◽

Cited By ~ 81

Author(s):

A. Bozkurt ◽

M. Ise ◽

K.D. Kreuer ◽

W.H. Meyer ◽

G. Wegner

Keyword(s):

Phosphoric Acid ◽

Conducting Polymer ◽

Polymer Electrolytes ◽

Proton Conducting

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Studies on Sodium Ion Conducting Gel Polymer Electrolytes

Key Engineering Materials ◽

10.4028/www.scientific.net/kem.594-595.786 ◽

2013 ◽

Vol 594-595 ◽

pp. 786-792 ◽

Cited By ~ 3

Author(s):

Khairul Bahiyah Md Isa ◽

Lisani Othman ◽

Nurul Husna Zainol ◽

Siti Mariam Samin ◽

Woon Gie Chong ◽

...

Keyword(s):

Polymer Electrolytes ◽

Room Temperature ◽

Ethylene Carbonate ◽

Gel Polymer Electrolyte ◽

Sodium Ion ◽

Casting Technique ◽

Ionic Salt ◽

Temperature Dependence Of Conductivity ◽

Solution Casting Technique ◽

Ion Conducting

Sodium ion conducting gel polymer electrolyte (GPE) films consisting of polyvinylidenefluoride-co-hexafluoropropylene (PVdF-HFP) as a polymer host were prepared using the solution casting technique. Sodium trifluoromethane-sulfonate (NaCF3SO3) was used as an ionic salt and the mixture of ethylene carbonate (EC) and propylene carbonate (PC) as the solvent plasticizer. The GPE films were found to be stable up to temperature of 145 °C as shown by TGA analysis. The AC impedance study show that the optimum conductivity of 2.50 x 10-3 S cm-1 at room temperature is achieved for the film containing 20 wt.% of NaCF3SO3 salt. The temperature dependence of conductivity obeys VTF relation in the temperature range of 303 K to 373 K.

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