Spectral Characteristics in the Degradation Process of Colored Dissolved Organic Matter from Large Filamentous Algae Sources in Saltwater Lake

2011 ◽  
Vol 356-360 ◽  
pp. 2536-2541 ◽  
Author(s):  
Li Min Zou ◽  
Jian Hua Li ◽  
De Gang Jiang ◽  
Yu Lai Wang

The indoor experimental study was on a large common species of filamentous green algae in the North Lake beach of Chongming Island - bristles algae liquid produced by algae growth during the photodegradation of colored dissolved organic matter (CDOM) spectral characteristics change. Absorption coefficient a (355) in the degradation experiment was reduced 27.44% , however , in the control experiment , a (355) was only 1.61% lower. In the photodegradation process of degradation experiments and control experiments, the values of M and S were increased to the different extent and the increased value of the former was higher than the latter. By using three-dimensional fluorescence spectroscopy (EEMS), the detected peak value of protein-and humic fluorescence in control experiments was little changed, while significantly increased in the degradation experiments. By the analysis of parallel factor model (PARAFAC) combined with three-dimensional fluorescence excitation - emission matrix data (EEMS), the three-component CDOM: C1, C2, C3, respectively were relative to humic fluorescence peaks A, C, and protein-like fluorescence B. In the degradation experiments, small changes were in the components of C1, however the components of C2, C3 compared with those in the control group were increased by nearly 2 times. All results showed that the photodegradation process of bristles algae liquid can cause changes of the CDOM in the structure and content, easier to produce small molecules and weak aromatic CDOM.

Water ◽  
2021 ◽  
Vol 13 (24) ◽  
pp. 3574
Author(s):  
Renkai Zhang ◽  
Ziqi Liu ◽  
Kangning Xiong ◽  
Xiaoxi Lyu ◽  
Chenpeng Hu ◽  
...  

Groups in dissolved organic matter (DOM) emit fluorescence information at characteristic wavelengths when irradiated by excitation waves, which can reveal the geochemical behavior of dissolved organic matter in the environment and its sources, but there are few relevant studies in cave groundwater systems. In order to investigate the relationship between drip hydrochemistry characteristics and DOM in cave systems after subsurface leakage, in this study, from the perspective of dissolved organic matter in the karst cave water system, the groundwater in the dry season of Daxiao Cave was selected as the research object. Five drip points and one water pool (DX-1, DX-2, DX-3, DX-4, DX-5, and DX-C) in Daxiao Cave were monitored and consecutively sampled for four months. The parallel factor analysis method (PARAFAC), three-dimensional (3D) fluorescence parameters, and excitation-emission matrix fluorescence spectroscopy (EEM), combined with the hydrochemistry characteristics of the drip water and correlation analysis, were used to analyze the 3D fluorescence spectral characteristics of the DOM of the drip water of Daxiao Cave and their influencing factors. The results show that (1) the hydrochemistry type of the drip water in Daxiao Cave was within the Ca–Mg–HCO3 type, and Ca2+, Mg2+, and HCO3- were the dominant ions in Daxiao Cave; (2) the fluorescence fractions of drip water in dry season caves were dominated by C1 (humus-like), C2 (tryptophan-like), and C3 (tyrosine-like), and the fluorescence fractions of drip water DOM were controlled by protein fluorophores; (3) the DOM in the drip water of Daxiao Cave in the dry season was controlled in part by subsurface leakage and was largely the result of microbial degradation; and (4) the DOM of the drip water may be influenced by the chemical composition of the water, but the exact process is not clear.


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