A Solar Cell Based on a Hybrid Film of P3HT and Magic Cubic-Like PbS

2012 ◽  
Vol 567 ◽  
pp. 236-239
Author(s):  
Peng Wang ◽  
An Mei Wang ◽  
Zhen Hua Zhang ◽  
Li Bo Fan ◽  
Yan Lei ◽  
...  

Lead sulfide (PbS) magic cubes were prepared by a simple hydrothermal method without any organic solvent. The product was characterized by X-ray diffraction (XRD), Scanning electron microscopy (SEM) and absorption spectrum. A solar cell, with a structure of Al/P3HT:PbS/PEDOT:PSS/ITO/Glass, was made. By a spin coating method, a hybrid film of poly(3-hexylthiophene) (P3HT) and PbS was prepared on the PEDOT:PSS layer. The solar cells are photosensitive in a large spectral range (visible and near infrared regions). The cells, with the area of 0.15 cm2 without any special treatment, have shown the values of open-circuit voltage (Voc) of 242 mV, short circuit current (Jsc) of 0.01 mA/cm2, energy conversion efficiency (η) of 0.01 % and fill factor (FF) of 0.31 under illumination intensity of 100 mW/cm2.

2012 ◽  
Vol 479-481 ◽  
pp. 166-169
Author(s):  
Peng Wang ◽  
Li Bo Fan ◽  
Zhen Hua Zhang ◽  
Yan Lei ◽  
Yan Ge Zhang ◽  
...  

Cubic-like lead sulfide (PbS) films were in situ fabricated on lead (Pb) foil on a large scale by solvothermal method. Ethanol and ethylenediamine were used as the solvent. The films were characterized by X-ray diffraction (XRD), Scanning electron microscopy (SEM), absorption and the Fourier transformation-infrared (FT-IR) spectra. A solar cell was made by the hybrid film of P3HT and cubic-like PbS. The solar cells are photosensitive in a large spectral range (visible and near infrared regions). The cell with the area of 0.20 cm2 without any special treatment has shown the values of open-circuit voltage (Voc) of 250 mV and short circuit current (Jsc) of 0.01 mA/cm2 with the efficiency of 0.01 % and the fill factor (FF) is 0.36 under illumination intensity of 100 mW/cm2.


2012 ◽  
Vol 569 ◽  
pp. 172-175
Author(s):  
Peng Wang ◽  
Li Bo Fan ◽  
Meng Yuan Yang ◽  
Zhen Hua Zhang ◽  
Xin Bing Zhu ◽  
...  

A new hybrid film solar cell was made with a structure of Glass/ITO/PbS/P3HT/Al. PbS film was prepared by a simple solid-solid reaction and poly(3-hexylthiophene) (P3HT) film was obtained by a spin coating method. The solar cells are photosensitive in a large spectral range (extending from near infrared to high energy side regions). Without any special treatment, the cell with an area of 0.15 cm2 has shown values of open-circuit voltage (Voc) of 85 mV and fill factor (FF) of 0.33 under an illumination intensity of 100 mW/cm2.


2012 ◽  
Vol 569 ◽  
pp. 176-179
Author(s):  
Peng Wang ◽  
Li Bo Fan ◽  
Li Juan Sun ◽  
Zhen Hua Zhang ◽  
Xin Bing Zhu ◽  
...  

A film solar cell was made with a structure of Glass/ITO/CdS/PbS/Al. CdS film was obtained by thermal evaporation. PbS film was prepared by a simple solid-solid reaction. The solar cells are photosensitive in a large spectral range (extending from near infrared to high energy side regions). The cell with the area of 0.15 cm2 without any special treatment has shown the values of open-circuit voltage (Voc) of 138 mV and short circuit current (Jsc) of 0.01 mA/cm2 with the efficiency of 0.33 % and the fill factor (FF) is 0.26 under illumination intensity of 100 mW/cm2.


2012 ◽  
Vol 05 (02) ◽  
pp. 1260004 ◽  
Author(s):  
GENTIAN YUE ◽  
JIHUAI WU ◽  
YUNFANG HUANG ◽  
YAOMING XIAOMING XIAO ◽  
ZHANG LAN

An iodine/iodide-free and polymer heterojunction-sensitized hybrid solar cell is fabricated by using 6,6-phenyl- C61 -butyric acid methyl ester (PCBM) as electronic acceptor, poly(3-hexylthiophene) (P3HT) as donor and TiO2 film as substrate. The PCBM–P3HT heterojunction can harvest ultraviolet-visible light, transport charge carriers, replacing the dyes and electrolytes in dye-sensitized solar cell. The cell with a PCBM/P3HT ratio of 1:2 shows a short circuit current of 5.47 mA⋅cm-2, an open circuit voltage of 0.849 V, a fill factor of 0.640 and a light-to-electric energy conversion efficiency of 2.97% under a simulated solar light irradiation of 100 mW⋅cm-2.


2016 ◽  
Vol 34 (3) ◽  
pp. 540-547 ◽  
Author(s):  
H. Sattarian ◽  
T. Tohidi ◽  
SH. Rahmatallahpur

AbstractIn this study, a solar cell with a glass/ITO/CdS/PbS/Al structure was constructed. Both window (CdS) and absorption (PbS) layers were deposited by chemical bath deposition (CBD) method. The CdS window layer was deposited on ITO-glass. The PbS nanocrystalline thin film was prepared with and without triethanolamine on CdS films at bath temperature of 25 °C. CdS and PbS nanocrystals were identified using XRD and SEM. The cells are photosensitive in a large spectral range (at visible and near infrared regions). The cell with absorbing layer obtained from the bath without TEA has higher efficiency with the following parameters: the open circuit voltage (Voc) is 275 mV, short circuit current (Jsc) is 12.24 mA/cm2, maximum voltage (Vmax) is 165 mV and maximum current (Jmax) is 7.11 mA/cm2 with the efficiency η = 1.31 %, fill factor FF is 32 % under the illumination intensity of 90 mW/cm2. The cells have an area of 0.15 cm2.


2014 ◽  
Vol 2014 ◽  
pp. 1-6 ◽  
Author(s):  
Hwen-Fen Hong ◽  
Tsung-Shiew Huang ◽  
Wu-Yih Uen ◽  
Yen-Yeh Chen

We performed accelerated tests on sealed and nonsealed InGaP/InGaAs/Ge triple-junction (TJ) solar cells in a complex high temperature and high humidity environment and investigated the electrical properties over time. The degradation of energy conversion efficiency in nonsealed cells was found to be more serious than that in sealed cells. The short-circuit current (ISC), open-circuit voltage (VOC), and fill factor (FF) of sealed cells changed very slightly, though the conversion efficiency decreased 3.6% over 500 h of exposure. This decrease of conversion efficiency was suggested to be due to the deterioration of silicone encapsulant. TheISC,VOC, and FF of nonsealed cells decreased with increasing exposure time. By EL and SEM analysis, the root causes of degradation can be attributed to the damage and cracks near the edge of cells induced by the moisture ingress. It resulted in shunt paths that lead to a deterioration of the conversion efficiency of solar cell by increasing the leakage current, as well as decreasing open-circuit voltage and fill factor of nonsealed solar cells.


2018 ◽  
Vol 6 (6) ◽  
Author(s):  
Hafeez Yusuf Hafeez ◽  
Bala Ismail Adam

In this analytical approach we fabricate and characterized a Titanium Dioxide Dye sensitized solar cell using Doctor-Blade Technique. The samples were given annealing treatment at various time of 20, 30 and 40 minutes respectivelyat constant annealing temperature of 450oC. The device under test (DUT) were tested using a Kiethley 2400, source meter under A.M 1.5 (1000W/m2) illumination from a Newport class A solar simulator.The results shows that at the miscellaneous annealing time, the open circuit voltagesVoc= 0.28V, 0.30V and 0.29V, the short circuit current density Jsc=95.5µAcm-2 , 104.1µAcm-2and 105µAcm-2, the fill factor FF= 0.411, 0.448 and 0.525 and the energy conversion efficiency, η = 0.011, 0.014 and 0.016 respectively.With best results of open circuit voltage Voc=0.30, short circuit current density Jsc= 105mAcm-2, fill factor FF= 0.525 and energy conversion efficiency η= 0.016 was achieved.It was observed that the power density, Fill Factor and efficiency increases with increasewith increase in annealing time.


2021 ◽  
Vol 2114 (1) ◽  
pp. 012075
Author(s):  
Ammar J. Aswad ◽  
Nadeem K. Hassan ◽  
Adnan R. Ahmed

Abstract A general equation to determine properties of penternary solar cell based on Cu (In, Ga) (Se, S) 2 (CIGSSe) with a double buffer layer ZnS/Zn0.8Mg0.2O(ZMO) were derived. Numerical analysis of a (CIGSSe) solar cell with a double buffer layer ZnS/ZMO, CdS free absorber layer, were investigated using the AFORS-HET software simulation. Taking into consideration the effect of thickness and doping concentration for the CIGSSe absorption layer, ZnS buffer layer and ZnO:B(BZO) window layer on the electron transport, short circuit current density (Jsc) and open circuit voltage (Voc); numerical simulation demonstrated that the changes in band structure characteristics occurred. The solar energy conversion efficiency is 28.34%, the filling factor is 85.59%, the open circuit voltage is 782.3 mV, the short circuit current is 42.32 mA. then we take the range of the gradient between the ratio of x and y for the absorption layer, and the best result of Voc, Jsc, FF, Eff equal (838.7 mV, 40.94 mA/cm2, 86.23%, 29.61%) respectively at x= 0, y= 0.26.


2013 ◽  
Vol 771 ◽  
pp. 159-168 ◽  
Author(s):  
I. Jinchu ◽  
A. Bharatkumar Sharma ◽  
C.O. Sreekala ◽  
K.S. Sreelatha ◽  
K. Achuthan

The efficiency of the best Dye sensitized solar cell is primarily depends on the good light harvesting property of the photo anode. Present study uses Lawsone (2 hydroxy [1, -naphthoquinone), the natural dye and compare the performance of photo anode in bare TiO2 and with nanoporous CaCO3 coated TiO2. As compared to bare TiO2, the surface area of nanoporous CaCO3-coated TiO2 increases, consequently, a better amount of dye adsorption occurs. The coating of CaCO3 increases the impedance at TiO2/dye/electrolyte interface and affect lifetime of the photoelectrons. Due to this reasons the short circuit current Jsc, open-circuit voltage (Voc), and fill factor (FF) increases. Thereby, the energy conversion efficiency of the solar cell is improved.


Energies ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1684
Author(s):  
Alessandro Romeo ◽  
Elisa Artegiani

CdTe is a very robust and chemically stable material and for this reason its related solar cell thin film photovoltaic technology is now the only thin film technology in the first 10 top producers in the world. CdTe has an optimum band gap for the Schockley-Queisser limit and could deliver very high efficiencies as single junction device of more than 32%, with an open circuit voltage of 1 V and a short circuit current density exceeding 30 mA/cm2. CdTe solar cells were introduced at the beginning of the 70s and they have been studied and implemented particularly in the last 30 years. The strong improvement in efficiency in the last 5 years was obtained by a new redesign of the CdTe solar cell device reaching a single solar cell efficiency of 22.1% and a module efficiency of 19%. In this paper we describe the fabrication process following the history of the solar cell as it was developed in the early years up to the latest development and changes. Moreover the paper also presents future possible alternative absorbers and discusses the only apparently controversial environmental impacts of this fantastic technology.


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