The Mobility and Rheological Properties of Phenyl Silicone Rubber

2012 ◽  
Vol 624 ◽  
pp. 256-259 ◽  
Author(s):  
Zhen Wu ◽  
Ying Qiang Zhang ◽  
Qing Guo
Keyword(s):  
Temperature Dependence ◽  
Rheological Properties ◽  
Silicone Rubber ◽  
Molar Mass ◽  
High Molar Mass

In this paper the mobility and factots affecting mobility of phenyl silicone rubber is studied. The results showed that the crystallinity of phenyl silicone rubber was declined because of the presence of phenyl and the higher the phenyl content, the lower the crystallinity when the phenyl content was low. The viscosity of the phenyl silicone rubber was rised as molar mass and phenyl content of the rubber was increased but the changes was not uniform. The viscosity of the phenyl silicone rubber was declined as temperature was increased and viscosity-temperature dependence of the high molar mass phenyl silicone rubber was larger. The influence of shearing on the viscosity and mobility of the phenyl silicone rubber were evident.

High molar mass silicone rubber reinforced with montmorillonite clay masterbatches: Morphology and mechanical properties

2010 ◽  
Vol 46 (5) ◽  
pp. 881-890 ◽  
Author(s):  
Manuela L.Q.A. Kaneko ◽  
Rafaelle Bonzanini Romero ◽  
Maria do Carmo Gonçalves ◽  
Inez V.P. Yoshida
Keyword(s):  
Mechanical Properties ◽  
Silicone Rubber ◽  
Molar Mass ◽  
Montmorillonite Clay ◽  
High Molar Mass ◽  
Morphology And Mechanical Properties

Molar mass and temperature dependence of rheological properties of polymethylmethacrylate melt

2018 ◽  
Vol 221 ◽  
pp. 62-65 ◽  
Author(s):  
Zhili Lu ◽  
Yamin Pan ◽  
Xianhu Liu ◽  
Guoqiang Zheng ◽  
Dirk W Schubert ◽  
...  
Keyword(s):  
Temperature Dependence ◽  
Rheological Properties ◽  
Molar Mass

Effect of layered silicates on rheological and mechanical properties and thermal stability of high-molar mass polydimethylsiloxane matrix

e-Polymers ◽  
2011 ◽  
Vol 11 (1) ◽  
Author(s):  
Veronika Rabova ◽  
Petr Hron
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Tensile Strength ◽  
Silicone Rubber ◽  
Molar Mass ◽  
Strength Increase ◽  
Weight Decay ◽  
High Molar Mass ◽  
Surface Modified ◽  
Thermal Stability Of

AbstractThe effect of surface modified fillers based on montmorillonite on rheological and mechanical properties and thermal stability of high-molar mass polydimethylsiloxane matrix was evaluated. Silicone rubber/clay composites were prepared via homogenisation on open two roll-mill followed by torque measurement at two different temperatures. At 30 °C and 100 °C the torque did not extremely differ excepting the mixtures containing Cloisite 15A where it achieved the maximum at 3 phr montmorillonite content, but the tensile strength reached the similar values in all mixtures. Thermogravimetric analysis was utilized to find out the differences in weight decay of composites in silicone rubber/montmorillonite mixtures and in unfilled silicone rubber. Synergism of fillers was also studied and led to tensile strength increase.

Paper Chemistry: Interactions of thermo mechanical pulp fractions with high molar mass cationic polyacrylamides: Part 2. Flocculation

2010 ◽  
Vol 25 (3) ◽  
pp. 310-318 ◽  
Author(s):  
Tero Taipale ◽  
Janne Laine ◽  
Susanna Holappa ◽  
Jonni Ahlgren ◽  
Juan Cecchini
Keyword(s):  
Molar Mass ◽  
High Molar Mass ◽  
Mechanical Pulp ◽  
Paper Chemistry

scholarly journals Highly Efficient MOF Catalyst Systems for CO2 Conversion to Bis-Cyclic Carbonates as Building Blocks for NIPHUs (Non-Isocyanate Polyhydroxyurethanes) Synthesis

Catalysts ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 628
Author(s):  
Adolfo Benedito ◽  
Eider Acarreta ◽  
Enrique Giménez
Keyword(s):  
Molar Mass ◽  
Cycloaddition Reaction ◽  
Building Blocks ◽  
Catalyst System ◽  
Cyclic Carbonate ◽  
Ammonium Bromide ◽  
Cyclic Carbonates ◽  
High Molar Mass ◽  
Highly Efficient ◽  
Free Process

The present paper describes a greener sustainable route toward the synthesis of NIPHUs. We report a highly efficient solvent-free process to produce [4,4′-bi(1,3-dioxolane)]-2,2′-dione (BDC), involving CO2, as renewable feedstock, and bis-epoxide (1,3-butadiendiepoxide) using only metal–organic frameworks (MOFs) as catalysts and cetyltrimethyl-ammonium bromide (CTAB) as a co-catalyst. This synthetic procedure is evaluated in the context of reducing global emissions of waste CO2 and converting CO2 into useful chemical feedstocks. The reaction was carried out in a pressurized reactor at pressures of 30 bars and controlled temperatures of around 120–130 °C. This study examines how reaction parameters such as catalyst used, temperature, or reaction time can influence the molar mass, yield, or reactivity of BDC. High BDC reactivity is essential for producing high molar mass linear non-isocyanate polyhydroxyurethane (NIPHU) via melt-phase polyaddition with aliphatic diamines. The optimized Al-OH-fumarate catalyst system described in this paper exhibited a 78% GC-MS conversion for the desired cyclic carbonates, in the absence of a solvent and a 50 wt % chemically fixed CO2. The cycloaddition reaction could also be carried out in the absence of CTAB, although lower cyclic carbonate yields were observed.

scholarly journals High Molar Mass Polycarbonate via Dynamic Solution Transcarbonation Using Bis(methyl salicyl) Carbonate, an Activated Carbonate

2021 ◽  
pp. 2100186
Author(s):  
Annelore Aerts ◽  
Camiel Kroonen ◽  
Jan Henk Kamps ◽  
Rint P. Sijbesma ◽  
Johan P. A. Heuts
Keyword(s):  
Molar Mass ◽  
High Molar Mass ◽  
Dynamic Solution

Synthesis of high molar mass poly(12-hydroxydodecanoic acid) in brønsted acid ionic liquids

Polymer ◽  
2010 ◽  
Vol 51 (6) ◽  
pp. 1218-1221 ◽  
Author(s):  
Elise-Marie Dukuzeyezu ◽  
Hervé Lefebvre ◽  
Martine Tessier ◽  
Alain Fradet
Keyword(s):  
Ionic Liquids ◽  
Molar Mass ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
High Molar Mass ◽  
Brönsted Acid
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