Ionic Conductivity and Dielectric Properties of Plasticized Polyacrylonitrile Based Solid Polymer Electrolyte Films

The conducting polymer electrolyte films composed of polyacrylonitrile (PAN) as the host polymer, LiCF3SO3 and NaCF3SO3 as inorganic salts and ethylene carbonate (EC) as plasticizer were prepared by the solution cast technique. The conductivities of the films were characterized by impedance spectroscopy. On addition of more than 14 wt% of salt, the NaCF3SO3-containing PAN films exhibited higher ionic conductivity than the LiCF3SO3-containing PAN films. The values of the dielectric constant, εr and dielectric loss, εi increase as frequency decreases at room temperature. The temperature dependence of the conductivity obeys Arrhenius relation in the temperature range of 303 K to 353 K.

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Increase of Solid Polymer Electrolyte Ionic Conductivity Using Nano-SiO2 Synthesized from Sugarcane Bagasse as Filler

Polymers ◽

10.3390/polym13234240 ◽

2021 ◽

Vol 13 (23) ◽

pp. 4240

Author(s):

Yatim Lailun Ni’mah ◽

Zakkiyyah Hidayatul Muhaiminah ◽

Suprapto Suprapto

Keyword(s):

Ionic Conductivity ◽

Polymer Electrolyte ◽

Sugarcane Bagasse ◽

Solid Polymer Electrolyte ◽

Sol Gel ◽

Solid Polymer ◽

Elongation At Break ◽

Nano Sio2 ◽

Solution Cast ◽

Cast Technique

The synthesize of solid polymer electrolyte (SPE) based on polyethylene oxide (PEO), NaClO4 and nano-SiO2 was carried out by solution cast technique. Nano-SiO2 was synthesized from sugarcane bagasse using sol-gel method. FTIR analysis was carried out to investigate the bonding between nano-SiO2 and PEO/NaClO4. The morphology of the SPE was characterized using SEM. XRD and DSC analysis showed that SPE crystallinity decreased as nano-SiO2 concentration was increased. Mechanical analyses were conducted to characterize the SPE tensile strength and elongation at break. EIS analysis was conducted to measure SPE ionic conductivity. The PEO/NaClO4 SPE with the addition of 5% nano-SiO2 from sugarcane bagasse at 60 °C produced SPE with the highest ionic conductivity, 1.18 × 10−6 S/cm. It was concluded that the addition of nano-SiO2 increased ionic conductivity and interface stability at the solid polymer electrolyte-PEO/NaClO4.

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Structural Study of Plasticized Carboxy Methylcellulose Based Solid Biopolymer Electrolyte

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.1107.242 ◽

2015 ◽

Vol 1107 ◽

pp. 242-246 ◽

Cited By ~ 5

Author(s):

M.N. Chai ◽

M.I.N. Isa

Keyword(s):

Solid Polymer Electrolyte ◽

Room Temperature ◽

Solid Polymer ◽

Biopolymer Electrolytes ◽

Infrared Studies ◽

Solution Cast ◽

Biopolymer Electrolyte ◽

Relationship Of ◽

Carboxyl Methylcellulose ◽

Cast Technique

Carboxyl methylcellulose (CMC) doped with oleic acid (OA) and plasticized with glycerol was able to be produced into solid biopolymer electrolytes using the solution cast technique. The CMC-OA-glycerol solid polymer electrolyte obtained the highest conductivity of 1.64 x 10-4 S cm-1 at room temperature for sample Gly 40 wt. %. Within the temperature range investigated, the conductivity– temperature relationship of the biopolymer electrolytes is characteristically Arrhenius behaviour, suggesting that the conductivity is thermally assisted. Fourier Transform Infrared studies was carried out to determine the dissociation of free protons (H+) from the carboxyl group (–COOH) of glycerol.

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Studies of Ionic Conductivity and Dielectric Behavior in Polyacrylonitrile Based Solid Polymer Electrolytes

Defect and Diffusion Forum ◽

10.4028/www.scientific.net/ddf.312-315.116 ◽

2011 ◽

Vol 312-315 ◽

pp. 116-121 ◽

Cited By ~ 1

Author(s):

Zurina Osman ◽

Khairul Bahiyah Md. Isa ◽

Lisani Othman ◽

Norlida Kamarulzaman

Keyword(s):

Ionic Conductivity ◽

Room Temperature ◽

Dielectric Behavior ◽

Solid Polymer Electrolytes ◽

Solid Polymer ◽

Ion Diffusion ◽

Lithium Triflate ◽

Different Temperatures ◽

Solution Cast ◽

Cast Technique

The solid polymer electrolyte films consisting of polyacrylonitrile (PAN) as the host polymer, lithium triflate (LiCF3SO3) and sodium triflate (NaCF3SO3) as dopant salts were prepared by the solution cast technique. The pure PAN film was prepared as a reference. The films were characterized using a.c. impedance spectroscopy. At room temperature, the highest conductivity for the sample from the (PAN+LiCF3SO3) system and the (PAN+NaCF3SO3) system is 3.04 x 10-4 Scm-1 and 7.13 x 10-4 Scm-1, respectively. The temperature dependence of ionic conductivity for the highest conducting film from both systems follows the Arrhenius equation in the temperature range of 303 K to 353 K. The frequency dependence of ionic conductivity, , complex permittivity, *, and complex electrical modulus, M* were studied at different temperatures. The ionic conductivity and the dielectric behavior are described in terms of ion diffusion and polarization.

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Analyses of ionic conductivity and dielectric behavior of solid polymer electrolyte based 2-hydroxyethyl cellulose doped ammonium nitrate plasticized with ethylene carbonate

10.1063/1.5002292 ◽

2017 ◽

Cited By ~ 4

Author(s):

M. N. Hafiza ◽

M. I. N. Isa

Keyword(s):

Ionic Conductivity ◽

Ammonium Nitrate ◽

Polymer Electrolyte ◽

Solid Polymer Electrolyte ◽

Ethylene Carbonate ◽

Dielectric Behavior ◽

Hydroxyethyl Cellulose ◽

Solid Polymer

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Tailoring the Structural, Morphological, Electrochemical, and Dielectric Properties of Solid Polymer Electrolyte

10.20944/preprints201807.0191.v1 ◽

2018 ◽

Author(s):

Anil Arya

Keyword(s):

Dielectric Properties ◽

Polymer Electrolyte ◽

Solid Polymer Electrolyte ◽

Interaction Mechanism ◽

Transference Number ◽

Dielectric Strength ◽

Solid Polymer ◽

Solution Cast ◽

Standard Solution ◽

Cast Technique

Herein, we present preparation of solid polymer electrolyte (SPE) comprising of PEO, NaPF6 and varying fraction of Succinonitrile (SN) by standard solution cast technique. The morphological features and structural properties were studied by the FESEM, XRD, respectively. FTIR was performed to study the interactions between polymer host, salt, and SN. Impedance spectroscopy, Transference number measurements, LSV and CV were used to examine the electrochemical properties. The complex permittivity/conductivity & modulus were studied to understand the dielectric properties by evaluating the dielectric strength, relaxation time, hopping frequency and dc conductivity. Based on the experimental results an interaction mechanism is presented.

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