Inhibition of Corrosion and Scale Formation in Oilfield Produced Water Recycling System

2013 ◽  
Vol 734-737 ◽  
pp. 2214-2217
Author(s):  
Jiang Wei Zhang ◽  
Gang Li ◽  
Yu Liu

Due to the characteristics of the oilfield produced water, there are serious problems of corrosion and scale formation in the water recycling process. A compound inhibitor consists of organophosphine inhibitors and zinc sulfate, was applied to prevent corrosion and scale formation. The corrosion rate and scale inhibition efficiency were studied in artificial supersaturated solutions through weight loss measurements and static jar tests at 95°C, respectively. The results showed that the compound inhibitor had lower corrosion rate (0.021 mm/a) and higher scale inhibition efficiency (97.34 %). The result of industrial pilot test verified the compound inhibitor has an excellent efficiency at oilfield. All results show that the compound inhibitor can solve corrosion and scale formation in oilfield produced water recycling system.

2021 ◽  
Vol 21 (4) ◽  
pp. 954
Author(s):  
Muhamad Jalil Baari ◽  
Bunbun Bundjali ◽  
Deana Wahyuningrum

The presence of salts and dissolved gas like CO2 that is carried with natural gas and crude oil along the pipeline is the main reason for corrosion and scale formation. These problems are usually resolved separately by corrosion inhibitors and scale inhibitors or acidification. Meanwhile, utilizing a compound to resolve both corrosion and scale formation has an advantage in the economic side and working time. N,O-carboxymethyl chitosan or N,O-CMCs is one of the chitosan's derivates. It is water-soluble and has different functional groups. Those properties support its capability as a complexing agent on corrosion and scale inhibitors. Synthesis of N,O-CMCs was carried out by chemical reactions between chitosan and chloroacetic acid under alkaline circumstances. N,O-CMCs product was characterized using FT-IR and 1H-NMR spectroscopy. The inhibition efficiency was analyzed by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization techniques. The measurements showed that the highest efficiency of corrosion inhibition reached 63.54% when the concentration and temperature were 30 ppm and 35 °C, respectively. N,O-CMCs was classified as a mixed-type inhibitor. The adsorption mechanism of the inhibitor followed Langmuir adsorption isotherm. The static scale inhibition test informed that the optimum inhibition efficiency of N,O-CMCs reached 60.00%.


2021 ◽  
Vol 6 (15) ◽  
pp. 3692-3701
Author(s):  
Lina Zhao ◽  
Yuming Zhou ◽  
Qingzhao Yao ◽  
Yanyun Wang ◽  
Sujuan Ge ◽  
...  

2019 ◽  
Vol 66 (1) ◽  
pp. 101-114 ◽  
Author(s):  
Luis Manuel Quej-Ake ◽  
Antonio Contreras ◽  
Hongbo Liu ◽  
Jorge L. Alamilla ◽  
Eliceo Sosa

PurposeThe purpose of this paper is to study the corrosion rate for X52, X60, X65, X70 and X80 steel immersed in Mexican oilfield produced water. For the electrochemical characterization of the five steels rotating disk electrodes, 20°C, 30°C and 45°C of experimental temperature and 0, 500, 1,000 and 2,000 rpm of rotation speed were taken into account. The temperature dependence was analyzed using Arrhenius law. Thus, Rct values obtained from EIS data in comparison with the corrosion rate obtained from polarization curves data were taken into account. Hydrodynamic effects were analyzed by Rct and corrosion rate data.Design/methodology/approachElectrochemical impedance spectroscopy and potentiodynamic polarization techniques were used to assess the electrochemical behavior for five pipe steels steel immersed in a natural solution.FindingsThe resistance and corrosion rate taken from electrochemical tests decreased as temperature and hydrodynamic condition also decreased. In addition, the Arrhenius parameter revealed that the natural solution increased the corrosion rate as the activation energy decreased. Typical branches related to reduction-oxidation reaction (dissolution-activation process or corrosion products dissolution) on steel surface were discussed. Optical images analysis shows that corrosion products for X65 steel exposed to oilfield produced water can be attributed to more susceptibility to corrosion damage for this steel grade (Quej-Ake et al., 2018), which is increased with the temperature and rotation speed of the working electrode.Originality/valueCorrosion process of the five steels exposed to oilfield produced water could be perceptive when Arrhenius analysis is taken into account. This is because oilfield produced water is the most aggressive condition (brine reservoir and sour water) for internal pipelines walls and storage tanks (brine tanks). Thus, stagnant condition was considered as a more extreme corrosive condition because produced water is stored in atmospheric stationary tanks as well as it is transported under laminar condition in zones where oilfield produced water is maintaining in the bottom of the pipe during the production, transporting and storing of the crude oil. In addition, a brief operational process for Reynolds number and the flowrate of the stock tank barrel per day (Q in STBD) using field and Reynolds number data is discussed.


2013 ◽  
Vol 295-298 ◽  
pp. 1144-1148
Author(s):  
Cheng Tun Qu ◽  
Xin Wang ◽  
Hong Guang Su ◽  
Jing Tian ◽  
Xue Yang

In this experiment the main corrosion factors of produced water in Changqing Oil Field concentrated treatment station was studied. In terms of ion component analysis, dissolved oxygen detection, bacteria content measurement, corrosion rate determination, as well as Gray Relational Analysis (GRA) method. And the corrosion products Scanning Electron Microscope Energy Dispersive X-ray analysis(SEM/EDX) were conducted. The results showed that the TGB content, pH value, S2-content, HCO3-, and dissolved oxygen content were the main corrosion factors. This study indicated that the corrosion rate of the system could be reduced from 0.0872mm/a to 0.0074mm by increasing pH value of oilfield produced water appropriately, strengthening the intensity of sulfur removal, controlling the bacterial content by adding fungicides etc.


2008 ◽  
Vol 62 (6) ◽  
pp. 700-703
Author(s):  
Makoto Matsushita ◽  
Yoshiharu Numata

2019 ◽  
Author(s):  
Chem Int

The corrosion inhibition characteristics of two medicinal molecules phenylalanine and rutin on mild steel in 1.0M Hydrochloric acid were evaluated using gravimetric method. Corrosion inhibition efficiency of 83.78 and 90.40 % was obtained respectively after seven days. However, phenylalanine showed weak accumulative higher corrosion inhibition efficiency. The presence of both molecules in the corrosive environment reduced the corrosion rate constant and increased the material half-life. Thermodynamic data calculated suggests a spontaneous adsorption of the molecules on the mild steel’s surface.


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