Reaction Mechanism on the Modification of PLA by Melamine via DMP
2013 ◽
Vol 781-784
◽
pp. 495-498
Keyword(s):
When poly (lactic acid-co-melamine) [P(LA-co-MA)] is synthesized via direct melt polycondensation (DMP), with the more MA in the feed content, the copolymer with a three-MA-core structure linked by the ether bond is formed. Increasing the molar feed ration(LA)/n(MA), the structure of the copolymers is gradually changed from multi-core structure into SPLA structure only containing one MA core, and a peak value of Mwexists as expected. The aromatic cores with different functional groups have an important influence on the Mwpeak value, and the internal factors are the conjugate effect and the nucleophilicity caused by the different functional groups themselves.
Synthesis of a Biodegradable Material Poly(lactic acid-co-melamine) via Direct Melt Polycondensation
2013 ◽
Vol 781-784
◽
pp. 503-506
2011 ◽
Vol 311-313
◽
pp. 1106-1109
◽
Keyword(s):
2013 ◽
Vol 131
(10)
◽
pp. n/a-n/a
◽
2011 ◽
Vol 121
(6)
◽
pp. 3662-3668
◽
2005 ◽
Vol 99
(1)
◽
pp. 244-252
◽
2011 ◽
Vol 18
(6)
◽
pp. 2093-2102
◽
2012 ◽
Vol 125
(S2)
◽
pp. E339-E346
◽