Preparation and Application of CA/BaSO4 -CR Composite Gel Ball in Cationic Dye Wastewater Treatment

2014 ◽  
Vol 955-959 ◽  
pp. 38-46
Author(s):  
Da Mei Yu ◽  
Yun Lin ◽  
Yi Min Zhang ◽  
Wen Juan Zhou ◽  
Dan Hua Zhao ◽  
...  

A new hybrid adsorbent of calcium-alginate encapsulated BaSO4-CR (CABSC) has been prepared. The adsorption selectivity and mechanism were studied by investigating the adsorption performance of two anionic and two cationic dyes. The adsorption of two cationic dyes (EV and MB) from aqueous solutions was examined using a batch sorption technique. The effects of time, pH, temperature and ionic strength on the adsorption were examined. Besides, this material was applied in the treatment of two practical cationic dye wastewaters. Our study shows that the sorbent could be a potential candidate for utilization in dye wastewater treatment processes.

Author(s):  
Shan Cao ◽  
Xudong Xu ◽  
Deyi Zhu ◽  
Changhua Jiang ◽  
Tianping Yu ◽  
...  

The dye effluent is usually difficult to be degraded by conventional wastewater treatment in leather industry. In order to develop efficient and cost-effective treatment methods, we evaluate the effect of white-rot fungus immobilization for dye decolorisation in this paper. The Phanerochaete chrysosporium BKM-F-1767 was used for immobilization. This research found that the white-rot fungus immobilization had an obviously decolorisation effect in dye wastewater treatment, and plant carriers such as sorghum stalk and corn cob were helpful to the growth of Phanerochaete chrysosporium in white-rot fungus immobilization. Due to the stability and recyclability, the white-rot fungus co-immobilization was considered as the most suitable treatment for decolorisation of dye effluent which enjoyed the advantages of both adsorption immobilization and entrapment immobilization. Furthermore, the dye decolorisation evaluation was carried out to find the most suitable carrier for co-immobilization, and it found that sorghum stalk - calcium-alginate gel spherical particle (SS-CGPB) has better decolorisation effect than corn cobs - calcium-alginate gel spherical particle (CC-CGPB), and the dye decolorisation rate was 86.77%. After 5 cycles, the dye decolorisation rate was 85.87% which indicated the SS-CGPB preserved functional integrity successfully. By further analyzing the biodegradation process with white-rot fungus immobilization, the intermediate products were observed and the degradation pathway of acid golden yellow dye molecular was proposed. The results showed that the C-N single bonds attached to the central benzene in the dye molecule were attacked and destroyed in white-rot fungus co-immobilization treatment, thus the structure of dye molecule could be successfully degraded into small molecules which would be more easily treated by conventional treatment methods. Therefore, the white rot fungus co-immobilization might be appropriate for pre-treatment as an important biotechnology for the advanced treatment of dye effluent.


RSC Advances ◽  
2016 ◽  
Vol 6 (85) ◽  
pp. 81622-81630 ◽  
Author(s):  
Ting-Ting Zhu ◽  
Zhi-Ming Zhang ◽  
Wei-Lin Chen ◽  
Zhu-Jun Liu ◽  
En-Bo Wang

H3PW12O40 was incorporated into cages of harmless MIL-101(Fe). The composite material exhibited excellent adsorption performance for the cationic dyes MB and RhB, can be utilized in the selective capture and separation of organic dyes in water and is reusable and stable.


2013 ◽  
Vol 652-654 ◽  
pp. 1571-1579
Author(s):  
Dan Hua Zhao ◽  
Xiu Lian Zhang ◽  
Wei Yin ◽  
Xiao Jun Liu

CaF2/AG25 (CFA) hybrid sorbent formed by hybrid reaction with activated calcium fluoride of low cost and anionic dye wastewater-Acid Green 25 (AG25) was used for the treatment of cationic dye wastewater. The adsorption of two cationic dyes methyl violet (MV) and Neutral Red (NR) from aqueous solutions was examined using a batch sorption technique. The effects of time, pH, ionic strength and temperature on the adsorption were also examined. It exhibited a faster adsorption to cationic dyes and hardly affected in pH over 3.5, ionic strength low 0.04 mol/L and temperature between 20 oC and 60 oC. The adsorption behavior of the NR and MV on CFA is in good agreement with the Langmiur isotherms model with the correlation coefficients of R 0.9948 for NR and 0.9992 for MV and the maximum adsorption capacity of NR (39.22 mg/g) and MV (48.78 mg/g). Finally, this sorbent was used in treatment of two practical cationic dye wastewaters with satisfactory results.


2006 ◽  
Vol 5 (4) ◽  
pp. 685-692
Author(s):  
Elisabeta Chirila ◽  
Ionela Carazeanu Popovici ◽  
Techin Ibadula ◽  
Alice Iordache

Author(s):  
N. Zaletova ◽  
S. Zaletov

Биологический метод очистки сточных вод представляет собой сложный многокомпонентный процесс, ключевой составляющей которого является работа ферментной системы. Известно, что одним из важнейших ферментов, обеспечивающих биологический процесс, являются дегидрогеназы. Полностью сложнейший механизм действия ферментов до конца пока не раскрыт, однако в практике контроля процессов биологической очистки используется показатель дегидрогеназной активности ила. Результаты исследований позволили дополнить имеющуюся информацию фактическими данными о взаимообусловленности уровня дегидрогеназной активности ила и показателей отдельных технологических параметров биологической очистки. Показано, что режим работы аэротенков (нагрузка на ил, доза активного ила и др.) и величина показателей исходной дегидрогеназной активности и дегидрогеназной активности этого же образца ила со слабо концентрированным раствором (ДАИН2О) связаны между собой и зависят от нагрузки на ил по органическим веществам. Полученные результаты исследования могут быть использованы для контроля биологического процесса очистки сточных вод.The biological method of wastewater treatment is a comprehensive multicomponent process the activities of the enzyme system being the key component of it. It is known that dehydrogenases have been one of the most important enzymes the ensure the biological process. The complicated mechanism of the action of enzymes has not been fully described so far however, in the practice of monitoring biological treatment processes, an indicator of the dehydrogenase activity of sludge is used. The research results provided for supplementing the available information with actual data on the interdependence of the level of dehydrogenase activity of sludge and indicators of individual process parameters of biological treatment. It was shown that the mode of operation of aeration tanks (organic matter load on sludge, dose of activated sludge, etc.) and the values of the initial dehydrogenase activity and dehydrogenase activity of the same sludge sample with weakly concentrated solution (DASН2О) are interconnected and depend on the organic load on sludge. The results of the study can be used to control the biological process of wastewater treatment.The biological method of wastewater treatment is a comprehensive multicomponent process the activities of the enzyme system being the key component of it. It is known that dehydrogenases have been one of the most important enzymes the ensure the biological process. The complicated mechanism of the action of enzymes has not been fully described so far however, in the practice of monitoring biological treatment processes, an indicator of the dehydrogenase activity of sludge is used. The research results provided for supplementing the available information with actual data on the interdependence of the level of dehydrogenase activity of sludge and indicators of individual process parameters of biological treatment. It was shown that the mode of operation of aeration tanks (organic matter load on sludge, dose of activated sludge, etc.) and the values of the initial dehydrogenase activity and dehydrogenase activity of the same sludge sample with weakly concentrated solution (DASН2О) are interconnected and depend on the organic load on sludge. The results of the study can be used to control the biological process of wastewater treatment.


1989 ◽  
Vol 21 (8-9) ◽  
pp. 805-814 ◽  
Author(s):  
F. R. Christensen ◽  
G. Holm Kristensen ◽  
J. la Cour Jansen

Experimental investigations on the kinetics of wastewater treatment processes in biofilms were performed in a laboratory reactor. Parallel with the kinetic experiments, the influence of the biofilm kinetics on the biofilm structure was studied at macroscopic and microscopic levels. The close interrelationship between biofilm kinetics and structural changes caused by the kinetics is illustrated by several examples. From the study, it is evident that the traditional modelling of wastewater treatment processes in biofilm reactors based on substrate removal kinetics alone will fail in many cases, due to the inevitable changes in the biofilm structure not taken into consideration. Therefore design rules for substrate removal in biofilms used for wastewater treatment must include correlations between the removal kinetics and the structure and development of the biological film.


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