Thermal Schock Criteria of Refractory Ceramics: Limitations of Conventional Analyses and Some Numerical Approaches to Improve the Prediction of the Resistance to Thermal Schock

2010 ◽  
Vol 70 ◽  
pp. 160-166
Author(s):  
Nicolas Schmitt

Significant advances in the mechanical design of ceramic parts were realized since the pioneer works of Kingery and Hasselman to define thermal shock resistance. But for high heterogeneous refractories and contrasted local phase properties the use of these criteria is not always convincing because the assumptions made are too simplicist. First, we underline how thermal shock resistance parameters helped to improve the global performance of ceramics and make some comments on their limitations for refractory materials. Then we show how numerical tools are useful for the design of refractory structures at high temperatures through several approaches we have developed for refractory structures: prediction of macroscopic thermal shock resistance of heterogeneous refractories using multi-scale analysis, finite element methods applied to a specific structure considering either a two-scale approach to describe the thermo-elastic quasi brittle behavior of heterogeneous materials, at the macroscopic scale approach considering homogeneous microstructure.

2007 ◽  
Vol 22 (2) ◽  
pp. 180-186 ◽  
Author(s):  
W. O. Soboyejo ◽  
E. T. Akpan ◽  
I. B. Bashir ◽  
J. Zimba ◽  
N. Hosannah ◽  
...  

Minerals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 835
Author(s):  
Martin Nguyen ◽  
Radomír Sokolář

This article examines the process for the synthesis of forsterite–spinel (2MgO·SiO2/MgO·Al2O3) refractory ceramics from fly ash and alumina as sources of aluminum oxide. Raw materials were milled, mixed in different ratios and sintered at 1500 °C for 2 h. Sintered samples were characterized by XRD, thermal analyses and SEM. Porosity, water absorption, bulk density, refractoriness, refractoriness under load and thermal shock resistance were also investigated. The impact of fly ash as a raw material was investigated in accordance with the resulting properties and microstructure of samples with fly ash and alumina as the raw materials. Due to the positive effect of flux oxides (iron oxides and alkalis) on sintering, the mullite contained in fly ash completely decomposed into silica and alumina, which, together with magnesium oxide, formed spinel. This led to improved microstructural and mechanical properties and thermal shock resistance. In particular, mixtures with 10 wt.% and 20 wt.% of fly ash had the most promising results compared to alumina mixtures. Both modulus of rupture and thermal shock resistance were improved, while the impact on refractory properties was minimal. The novelty of this research lies in the recycling of fly ash, a by-product from coal-burning power plants, into a raw material for the production of forsterite–spinel refractory ceramics.


2021 ◽  
Vol 866 ◽  
pp. 158985
Author(s):  
Xiaojia Su ◽  
Yiwang Bao ◽  
Detian Wan ◽  
Haibin Zhang ◽  
Ludi Xu ◽  
...  

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